4,357 research outputs found
Analytical solutions for the isobaric evaporation of pure cryogens in storage tanks
New analytical solutions have been derived for the isobaric evaporation of a pure liquid cryogen. In particular, expressions have been provided for the liquid volume, evaporation rate, Boil-off-Gas (BOG) rate, vapour temperature and vapour to liquid heat transfer rate as a function of time. Both equilibrium and non-equilibrium scenarios have been considered. In the former, the vapour and liquid cryogen are assumed to be in thermal equilibrium, while in the latter the vapour is treated as superheated with respect to the liquid and acts as an additional heat source. The derived solutions for two scenarios were validated against the numerical results for the evaporation of liquid methane and of liquid nitrogen in small, medium sized and large storage tanks that are used in industry. For the equilibrium model, the analytical solutions are exact. For the non-equilibrium model, the analytical solutions are valid for the whole duration of evaporation, except for a short transient period at the beginning of the evaporation. For physical quantities of industrial interest, they provide accurate estimates of liquid volume, BOG rate and BOG temperature, with the maximum deviations not exceeding 1%, 2% and 4.5%, respectively. The vapour to liquid heat transfer rate is also well predicted to within a maximum deviation of 5%
New ALE applications in non-linear fast-transient solid dynamics
The arbitrary Lagrangian—Eulerian (ALE) formulation, which is already well established in the hydrodynamics and fluid-structure interaction fields, is extended to materials with memory, namely, non- linear path-dependent materials. Previous attempts to treat non- linear solid mechanics with the ALE description have, in common, the implicit interpolation technique employed. Obviously, this implies a numerical burden which may be uneconomical and may induce to give up this formulation, particularly in fast-transient dynamics where explicit algorithms are usually employed. Here, several applications are presented to show that if adequate stress updating techniques are implemented, the ALE formulation could be much more competitive than classical Lagrangian computations when large deformations are present. Moreover, if the ALE technique is interpreted as a simple interpolation enrichment, adequate—in opposition to distorted or locally coarse—meshes are employed. Notice also that impossible computations (or at least very involved numerically) with a Lagrangian code are easily implementable in an ALE analysis. Finally, it is important to observe that the numerical examples shown range from a purely academic test to real engineering simulations. They show the effective applicability of this formulation to non-linear solid mechanics and, in particular, to impact, coining or forming analysis
Predicting the viscosity of liquid mixtures consisting of n-alkane, alkylbenzene and cycloalkane species based on molecular description
1-component Extended Hard-Sphere (1-cEHS) model has been developed recently to predict the viscosity of liquid, n-alkane mixtures. It represents a mixture by a single pseudo-component characterized by an appropriate molecular weight and calculates the viscosity by means of the modified, extended hard-sphere model (EHS) that makes use of a universal function relating reduced viscosity to reduced volume. In this work we have extended the model to also predict the viscosity of mixtures containing alkylbenzene and cycloalkane species. Furthermore, we have developed a new 3-component Extended Hard-Sphere (3-cEHS) model which requires only a knowledge of the overall composition of n-alkane, alkylbenzene and cycloalkane species. Extensive comparison with the available experimental data indicates that both models (1-cEHS and 3-cEHS) predict the viscosity of binary and multicomponent mixtures containing n-alkane, alkylbenzene and cycloalkane species with uncertainty of 5–10%. The proposed models are a precursor of a new family of models that do not require a knowledge of the detailed composition of the mixture, but still take advantage of the underlying molecular description
A realistic vapour phase heat transfer model for the weathering of LNG stored in large tanks
A new non-equilibrium model relevant to LNG weathering in large storage tanks under constant pressure has been developed. It treats the heat influx from the surroundings into the vapour and liquid phases separately and allows for heat transfer between the two phases. The main heat transfer mechanisms in the vapour phase are assumed to be advection, due to upward flow of evaporated LNG, and conduction. It has been observed that the vapour temperature increases monotonically as a function of the height, in agreement with recent experimental results. In all the simulations performed the vapour to liquid heat transfer was small, also in line with recent experimental findings, and is estimated to contribute less than 0.3% to boil-off gas rates. The results of this work indicate that the heat transfer by the advective upward flow dominates the energy transfer within the vapour, while the natural convection, in the body of the vapour, can be neglected. The initial liquid filling has a pronounced effect on all the relevant variables, leading to a decrease in vapour temperature and boil-off gas temperature and an increase in boil-off rates. A rule of thumb for estimating the boil-off gas temperature in industrial storage tanks is provided
Second-best tax policy in a growing economy with externalities
This paper investigates the exploitation of environmental resources in a growing economy within a second-best scal policy framework. Agents derive utility from two types of consumption goods one which relies on an environmental input and one which does not as well as from leisure and from environmental amenity values. Property rights for the environmental resource are potentially incomplete. We connect second best policy to essential components of utility by considering the elasticity of substitution among each of the four utility arguments. The results illustrate potentially important relationships between environmental amentity values and leisure. When amenity values are complementary with leisure, for instance when environmental amenities are used for recreation, taxes on extractive goods generally increase over time. On the other hand, optimal taxes on extractive goods generally decrease over time when leisure and environmental amenity values are substitutes. Unders some parameterizations, complex dynamics leading to nonmonotonic time paths for the state variables can emerge.elasticity of substitution, second-best policy, growth and the environment
Condensation in an Economic Model with Brand Competition
We present a linear agent based model on brand competition. Each agent
belongs to one of the two brands and interacts with its nearest neighbors. In
the process the agent can decide to change to the other brand if the move is
beneficial. The numerical simulations show that the systems always condenses
into a state when all agents belong to a single brand. We study the
condensation times for different parameters of the model and the influence of
different mechanisms to avoid condensation, like anti monopoly rules and brand
fidelity.Comment: Accepted in: International Journal of Modern Physics
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