Lanthanides in granulometric fractions of Mediterranean soils. Can they be used as fingerprints of provenance?

Highlights Are lanthanides from fine sand and clay genetically related to the geological materials? Lanthanide concentrations of fine sand and clay fit chronofunctions Pearson's r of lanthanide couples decreases when separation increases in the periodic table Free forms of clay are scavengers of lanthanides and concentrate HREE and ceriumSample preparation and chemical analysis were conducted by Emma Humphreys-Williams and Stanislav Strekopytov (Imaging and Analysis Centre, Natural History Museum, London, UK). This work was supported by a grant from Ministerio de Economía, Industria y Competitividad de España (‘Tipologías de Suelos Mediterráneos versus Cuarzo. En la frontera del conocimiento edafogenético’; Ref. CGL2016-80308-P). The authors thank Professor Margaret A. Oliver, an anonymous editor and two anonymous reviewers for helpful comments and suggestions that improved the final manuscript. We also thank Robert Abrahams (Bsc) for revising the English language.There is geochemical interest in the lanthanides because they behave like a group that is closely related to the parent materials during surface processes, although they also undergo fractionation as a result of supergene dynamics. We analysed lanthanide concentrations (ICPms) in the granulometric fractions fine sand, clay and free forms of clay (FFclay‐CDB and FFclay‐Ox: extracted with citrate‐dithionite‐sodium bicarbonate and with ammonium oxalate, respectively) from a soil chronosequence of Mediterranean soils. There was a relative enrichment of heavy rare earth elements (HREE) in the clay fraction and its free forms with respect to fine sand. The clay free forms behaved as scavengers of lanthanides, and oxidative scavenging of cerium (Ce) in FFclay‐CDB was also detected. Lanthanide concentrations (lanthanum to gadolinium in fine sand; terbium to lutetium in clay) varied with soil age, and chronofunctions were established. There was a strong positive collinearity between most of the lanthanide concentrations. Furthermore, the value of the correlation index (Pearson's r ) of the concentrations between couples of lanthanides (r CLC) decreased significantly with increasing separation between the elements in the periodic table; this has never been described in soils. Several geochemical properties and indices in the fine sand and clay soil fractions and in the geological materials of the Guadalquivir catchment showed, on the one hand, a genetic relation between them all, enabling the lanthanides to be used as fingerprints of provenance; on the other hand, fractionation between fine sand and clay showed these are actively involved in soil lanthanide dynamics.Secretaría de Estado de Investigación, Desarrollo e Innovación. Grant Number: CGL2016‐80308‐

Time resolved scattering relaxation mechanisms of microcavity polaritons

We study the polariton relaxation dynamics for different scattering mechanisms as: Phonon and electron scattering procesess. The relaxation polariton is obtained at very short times by solving the Boltzman equation. Instead of the well-known relaxation process by phonons, we show that the bottleneck effect relaxes to the ground state more efficiently at low pump power intensity when the electron relaxation process is included. In this way, we clearly demonstrate that different relaxation times exist, for which any of these two mechanism is more efficient to relax the polariton population to the ground state.Comment: 10 eps figure

Free Energy of a Dilute Bose Gas: Lower Bound

A lower bound is derived on the free energy (per unit volume) of a homogeneous Bose gas at density $\rho$ and temperature $T$. In the dilute regime, i.e., when $a^3\rho \ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, our bound differs to leading order from the expression for non-interacting particles by the term $4\pi a (2\rho^2 - [\rho-\rho_c]_+^2)$. Here, $\rho_c(T)$ denotes the critical density for Bose-Einstein condensation (for the non-interacting gas), and $[ ]_+$ denotes the positive part. Our bound is uniform in the temperature up to temperatures of the order of the critical temperature, i.e., $T \sim \rho^{2/3}$ or smaller. One of the key ingredients in the proof is the use of coherent states to extend the method introduced in [arXiv:math-ph/0601051] for estimating correlations to temperatures below the critical one.Comment: LaTeX2e, 53 page

On the microstructure and mechanical properties of an Fe-10Ni-7Mn martensitic steel processed by high-pressure torsion.

High-pressure torsion (HPT) processing was applied to an Fe-10Ni-7Mn (wt.%) martensitic steel at room temperature and the grain size was reduced from an initial value of ~5.5 μm to an ultrafine value of ~185 nm for the ferritic phase and around 30 nm for the austenitic phase after 20 HPT turns. The microstructure and mechanical properties of the as-processed material were evaluated using X-ray diffraction (XRD), electron backscatter diffraction (EBSD), field emission scanning electron microscopy (FESEM), microhardness measurements and tensile testing. In addition, annealing of an as-processed specimen was analyzed by differential scanning calorimetry (DSC). The results show that HPT processing increases the hardness and ultimate tensile strength to ~690 Hv and ~2230 MPa, respectively, but the ductility is decreased from ~16.5% initially to ~6.4% and ~3.1% after 10 and 20 turns, respectively. The hardness distributions and EBSD images show that a reasonably homogeneous microstructure is formed when applying a sufficient level of pressure and torsional strain. The DSC results demonstrate that processing by HPT reduces the start and finish temperatures of the reverse transformation of martensite to austenite and there is continuous re-crystallization after the recovery process

CP violation in Bd,s→l+l−B_{d,s} \to l^+l^- in the model III 2HDM

We have calculated the Wilson coefficients $C_{10}, C_{Q_i}$ (i=1,2) in the $\bar{MS}$ renormalization scheme in the model III 2HDM. Using the obtained Wilson coefficients, we have analyzed the CP violation in decays $B^0_q\to l^+l^-$ (q=d,s) in the model. The CP asymmetry, $A_{CP}$, depends on the parameters of models and $A_{CP}$ in $B_d\to l^+l^-$ can be as large as 40% and 35% for $l=\tau$ and $l=\mu$ respectively. It can reach 4% for $B^0_s$ decays. Because in SM CP violation is smaller than or equal to O($10^{-3}$) which is unobservably small, an observation of CP asymmetry in the decays $B^0_q \to l^+l^- (q=d,s)$ would unambiguously signal the existence of new physics.Comment: revtex4, 16 pages, 7 figure

Longitudinal polarization asymmetry of leptons in the pure leptonic B decays

Longitudinal lepton polarization asymmetry in B_q -> l l (q = d, s$ and l = e, mu, tau) decays is investigated. The analysis is done in a general manner by using the effective operators approach. It is shown that the longitudinal lepton polarization asymmetry would provide a direct search for the scalar and pseudoscalar type interactions, which are induced in all variants of Higgs-doublet models.Comment: 7 page

Determination of the η\eta and η′\eta' Mixing Angle from the Pseudoscalar Transition Form Factors

The possible range of $\eta-\eta'$ mixing angle is determined from the transition form factors $F_{\eta \gamma}(Q^2)$ and $F_{\eta' \gamma}(Q^2)$ with the help of the present experimental data. For such purpose, the quark-flavor mixing scheme is adopted and the pseudoscalar transition form factors are calculated under the light-cone pQCD framework, where the transverse momentum corrections and the contributions beyond the leading Fock state have been carefully taken into consideration. We construct a phenomenological expression to estimate the contributions to the form factors beyond the leading Fock state based on their asymptotic behavior at $Q^2\to 0$ and $Q^2\to\infty$. By taking the quark-flavor mixing scheme, our results lead to $\phi= 38.0^{\circ}\pm 1.0^{\circ}\pm 2.0^{\circ}$, where the first error coming from experimental uncertainty and the second error coming from the uncertainties of the wavefunction parameters. The possible intrinsic charm component in $\eta$ and $\eta'$ is discussed and our present analysis also disfavors a large portion of intrinsic charm component in $\eta$ and $\eta'$, e.g. $|f^c_{\eta'}|\le 50 {\rm MeV}$.Comment: 18 Pages, 3 figures. Several references added. To be published in EPJ

Light localization in quasi-periodic nano-photonics carpets

In this work we show the formation of quasi-periodic field carpets and strong localization of light in the proximity of a planar quasi-crystal array of nano-holes in metallic screen

Bounded version vectors

Version vectors play a central role in update tracking under optimistic distributed systems, allowing the detection of obsolete or inconsistent versions of replicated data. Version vectors do not have a bounded representation; they are based on integer counters that grow indefinitely as updates occur. Existing approaches to this problem are scarce; the mechanisms proposed are either unbounded or operate only under specific settings. This paper examines version vectors as a mechanism for data causality tracking and clarifies their role with respect to vector clocks. Then, it introduces bounded stamps and proves them to be a correct alternative to integer counters in version vectors. The resulting mechanism, bounded version vectors, represents the first bounded solution to data causality tracking between replicas subject to local updates and pairwise symmetrical synchronization.FCT project POSI/ICHS/44304/2002, FCT under grant BSAB/390/2003

Interpretation of computational thinking evaluation results for enrollment prediction

During two generations (2016 and 2017) the computational thinking evaluation has been carried out in order to establish learning scenarios for new students, such interventions have been made in the Programming methodology course, it belonging to the career of Information Technology at the Technological University of Puebla in México. The results have led a personalized education for students, recognizing previous skills as well as trying to correct those missing, so that it acquires the competences respective, credit the course and improve the retention percentage of the first quarter. In this sense, when detecting possible skill gaps, is it possible to predict what will be the impact to maintain or decrease enrollment during and the end of quarter? The present work aims to answer the question by the results interpretation obtained from the computational thinking evaluation to 242 new students, generation 2018. Initially, it was stablished which would be the student's situation during and the end of four months from September to December based on the correct assessment reagents; three categories were determined: 1. Sure desertion, 2. Safe permanence, 3. Variable permanence. Later, 50 students who enrolled the next quarter (January-April 2019) were revised if they had been predicted properly; using a survey, the familiarity of key concepts of the subject Programming methodology was obtained with the aim of determining a correspondence with the evaluation of computational thinking skills, as well as the established situation, consequently, establishing the validity of predicting the enrollment