101 research outputs found
The electronic structure of LaSrMnO thin films and its dependence as studied by angle-resolved photoemission
We present angle-resolved photoemission spectroscopy results for thin films
of the three-dimensional manganese perovskite LaSrMnO. We
show that the transition temperature () from the paramagnetic insulating
to ferromagnetic metallic state is closely related to details of the electronic
structure, particularly to the spectral weight at the -point, where
the sharpest step at the Fermi level was observed. We found that this -point is the same for all the samples, despite their different . The
change of is discussed in terms of kinetic energy optimization. Our ARPES
results suggest that the change of the electronic structure for the samples
having different transition temperatures is different from the rigid band
shift.Comment: Accepted by Journal of Physics: Condensed Matte
Momentum resolved spin dynamics of bulk and surface excited states in the topological insulator
The prospective of optically inducing a spin polarized current for spintronic
devices has generated a vast interest in the out-of-equilibrium electronic and
spin structure of topological insulators (TIs). In this Letter we prove that
only by measuring the spin intensity signal over several order of magnitude in
spin, time and angle resolved photoemission spectroscopy (STAR-PES) experiments
is it possible to comprehensively describe the optically excited electronic
states in TIs materials. The experiments performed on
reveal the existence of a Surface-Resonance-State in the 2nd bulk band gap
interpreted on the basis of fully relativistic ab-initio spin resolved
photoemission calculations. Remarkably, the spin dependent relaxation of the
hot carriers is well reproduced by a spin dynamics model considering two
non-interacting electronic systems, derived from the excited surface and bulk
states, with different electronic temperatures.Comment: 5 pages and 4 figure
First-Principles Studies of Hydrogenated Si(111)--77
The relaxed geometries and electronic properties of the hydrogenated phases
of the Si(111)-77 surface are studied using first-principles molecular
dynamics. A monohydride phase, with one H per dangling bond adsorbed on the
bare surface is found to be energetically favorable. Another phase where 43
hydrogens saturate the dangling bonds created by the removal of the adatoms
from the clean surface is found to be nearly equivalent energetically.
Experimental STM and differential reflectance characteristics of the
hydrogenated surfaces agree well with the calculated features.Comment: REVTEX manuscript with 3 postscript figures, all included in uu file.
Also available at http://www.phy.ohiou.edu/~ulloa/ulloa.htm
Electronic properties and Fermi surface of Ag(111) films deposited onto H-passivated Si(111)-(1x1) surfaces
Silver films were deposited at room temperature onto H-passivated Si(111)
surfaces. Their electronic properties have been analyzed by angle-resolved
photoelectron spectroscopy. Submonolayer films were semiconducting and the
onset of metallization was found at a Ag coverage of 0.6 monolayers. Two
surface states were observed at -point in the metallic films,
with binding energies of 0.1 and 0.35 eV. By measurements of photoelectron
angular distribution at the Fermi level in these films, a cross-sectional cut
of the Fermi surface was obtained. The Fermi vector determined along different
symmetry directions and the photoelectron lifetime of states at the Fermi level
are quite close to those expected for Ag single crystal. In spite of this
concordance, the Fermi surface reflects a sixfold symmetry rather than the
threefold symmetry of Ag single crystal. This behavior was attributed to the
fact that these Ag films are composed by two domains rotated 60.Comment: 9 pages, 8 figures, submitted to Physical Review
Glycosaminoglycans: What Remains To Be Deciphered?
Glycosaminoglycans (GAGs) are complex polysaccharides exhibiting a vast structural diversity and fulfilling various functions mediated by thousands of interactions in the extracellular matrix, at the cell surface, and within the cells where they have been detected in the nucleus. It is known that the chemical groups attached to GAGs and GAG conformations comprise “glycocodes” that are not yet fully deciphered. The molecular context also matters for GAG structures and functions, and the influence of the structure and functions of the proteoglycan core proteins on sulfated GAGs and vice versa warrants further investigation. The lack of dedicated bioinformatic tools for mining GAG data sets contributes to a partial characterization of the structural and functional landscape and interactions of GAGs. These pending issues will benefit from the development of new approaches reviewed here, namely (i) the synthesis of GAG oligosaccharides to build large and diverse GAG libraries, (ii) GAG analysis and sequencing by mass spectrometry (e.g., ion mobility-mass spectrometry), gas-phase infrared spectroscopy, recognition tunnelling nanopores, and molecular modeling to identify bioactive GAG sequences, biophysical methods to investigate binding interfaces, and to expand our knowledge and understanding of glycocodes governing GAG molecular recognition, and (iii) artificial intelligence for in-depth investigation of GAGomic data sets and their integration with proteomics
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