The hbar Expansion in Quantum Field Theory

We show how expansions in powers of Planck's constant hbar = h/2\pi can give new insights into perturbative and nonperturbative properties of quantum field theories. Since hbar is a fundamental parameter, exact Lorentz invariance and gauge invariance are maintained at each order of the expansion. The physics of the hbar expansion depends on the scheme; i.e., different expansions are obtained depending on which quantities (momenta, couplings and masses) are assumed to be independent of hbar. We show that if the coupling and mass parameters appearing in the Lagrangian density are taken to be independent of hbar, then each loop in perturbation theory brings a factor of hbar. In the case of quantum electrodynamics, this scheme implies that the classical charge e, as well as the fine structure constant are linear in hbar. The connection between the number of loops and factors of hbar is more subtle for bound states since the binding energies and bound-state momenta themselves scale with hbar. The hbar expansion allows one to identify equal-time relativistic bound states in QED and QCD which are of lowest order in hbar and transform dynamically under Lorentz boosts. The possibility to use retarded propagators at the Born level gives valence-like wave-functions which implicitly describe the sea constituents of the bound states normally present in its Fock state representation.Comment: 8 pages, 1 figure. Version to be published in Phys. Rev.

Many-Body Dynamics and Exciton Formation Studied by Time-Resolved Photoluminescence

The dynamics of exciton and electron-hole plasma populations is studied via time-resolved photoluminescence after nonresonant excitation. By comparing the peak emission at the exciton resonance with the emission of the continuum, it is possible to experimentally identify regimes where the emission originates predominantly from exciton and/or plasma populations. The results are supported by a microscopic theory which allows one to extract the fraction of bright excitons as a function of time.Comment: 11 pages, 5 figure

Photoluminescence and Terahertz Emission from Femtosecond Laser-Induced Plasma Channels

Luminescence as a mechanism for terahertz emission from femtosecond laser-induced plasmas is studied. By using a fully microscopic theory, Coulomb scattering between electrons and ions is shown to lead to luminescence even for a spatially homogeneous plasma. The spectral features introduced by the rod geometry of laser-induced plasma channels in air are discussed on the basis of a generalized mode-function analysis.Comment: 4 pages with 2 figures

Excitonic Photoluminescence in Semiconductor Quantum Wells: Plasma versus Excitons

Time-resolved photoluminescence spectra after nonresonant excitation show a distinct 1s resonance, independent of the existence of bound excitons. A microscopic analysis identifies excitonic and electron-hole plasma contributions. For low temperatures and low densities the excitonic emission is extremely sensitive to even minute optically active exciton populations making it possible to extract a phase diagram for incoherent excitonic populations.Comment: 9 pages, 4 figure

Vibration-enhanced quantum transport

In this paper, we study the role of collective vibrational motion in the phenomenon of electronic energy transfer (EET) along a chain of coupled electronic dipoles with varying excitation frequencies. Previous experimental work on EET in conjugated polymer samples has suggested that the common structural framework of the macromolecule introduces correlations in the energy gap fluctuations which cause coherent EET. Inspired by these results, we present a simple model in which a driven nanomechanical resonator mode modulates the excitation energy of coupled quantum dots and find that this can indeed lead to an enhancement in the transport of excitations across the quantum network. Disorder of the on-site energies is a key requirement for this to occur. We also show that in this solid state system phase information is partially retained in the transfer process, as experimentally demonstrated in conjugated polymer samples. Consequently, this mechanism of vibration enhanced quantum transport might find applications in quantum information transfer of qubit states or entanglement.Comment: 7 pages, 6 figures, new material, included references, final published versio

Influence of Coulomb and Phonon Interaction on the Exciton Formation Dynamics in Semiconductor Heterostructures

A microscopic theory is developed to analyze the dynamics of exciton formation out of incoherent carriers in semiconductor heterostructures. The carrier Coulomb and phonon interaction is included consistently. A cluster expansion method is used to systematically truncate the hierarchy problem. By including all correlations up to the four-point (i.e. two-particle) level, the fundamental fermionic substructure of excitons is fully included. The analysis shows that the exciton formation is an intricate process where Coulomb correlations rapidly build up on a picosecond time scale while phonon dynamics leads to true exciton formation on a slow nanosecond time scale.Comment: 18 pages, 7 figure

Structural characterization of copper(II) binding to α-Synuclein: Insights into the bioinorganic chemistry of Parkinson's disease

The aggregation of α -synuclein (AS) is characteristic of Parkinson’s disease and other neurodegenerative synucleinopathies. We demonstrate here that Cu(II) ions are effective in accelerating AS aggregation at physiologically relevant concentrations without altering the resultant fibrillar structures. By using numerous spectroscopic techniques (absorption, CD, EPR, and NMR), we have located the primary binding for Cu(II) to a specific site in the N terminus, involving His-50 as the anchoring residue and other nitrogen oxygen donor atoms in a square planar or distorted tetragonal geometry. The carboxylate-rich C terminus, originally thought to drive copper binding, is able to coordinate a second Cu(II) equivalent, albeit with a 300-fold reduced affinity. The NMR analysis of AS–Cu(II) complexes reveals the existence of conformational restrictions in the native state of the protein. The metallobiology of Cu(II) in Parkinson’s disease is discussed by a comparative analysis with other Cu(II)-binding proteins involved in neurodegenerative disorders

Correlated errors in Hipparcos parallaxes towards the Pleiades and the Hyades

We show that the errors in the Hipparcos parallaxes towards the Pleiades and the Hyades open clusters are spatially correlated over angular scales of 2 to 3 deg, with an amplitude of up to 2 mas. This correlation is stronger than expected based on the analysis of the Hipparcos catalog. We predict the parallaxes of individual cluster members, pi_pm, from their Hipparcos proper motions, assuming that all cluster members have the same space velocity. We compare pi_pm with their Hipparcos parallaxes, pi_Hip, and find that there are significant spatial correlations in pi_Hip. We derive a distance modulus to the Pleiades of 5.58 +- 0.18 mag using the radial-velocity gradient method. This value, agrees very well with the distance modulus of 5.60 +- 0.04 mag determined using the main-sequence fitting technique, compared with the value of 5.33 +- 0.06 inferred from the average of the Hipparcos parallaxes of the Pleiades members. We show that the difference between the main-sequence fitting distance and the Hipparcos parallax distance can arise from spatially correlated errors in the Hipparcos parallaxes of individual Pleiades members. Although the Hipparcos parallax errors towards the Hyades are spatially correlated in a manner similar to those of the Pleiades, the center of the Hyades is located on a node of this spatial structure. Therefore, the parallax errors cancel out when the average distance is estimated, leading to a mean Hyades distance modulus that agrees with the pre-Hipparcos value. We speculate that these spatial correlations are also responsible for the discrepant distances that are inferred using the mean Hipparcos parallaxes to some open clusters. Finally, we note that our conclusions are based on a purely geometric method and do not rely on any models of stellar isochrones.Comment: 33 pages including 10 Figures, revised version accepted for publication in Ap

Composition Dependence of the Structure and Electronic Properties of Liquid Ga-Se Alloys Studied by Ab Initio Molecular Dynamics Simulation

Ab initio molecular dynamics simulation is used to study the structure and electronic properties of the liquid Ga-Se system at the three compositions Ga$_2$Se, GaSe and Ga$_2$Se$_3$, and of the GaSe and Ga$_2$Se$_3$ crystals. The calculated equilibrium structure of GaSe crystal agrees well with available experimental data. The neutron-weighted liquid structure factors calculated from the simulations are in reasonable agreement with recent neutron diffraction measurements. Simulation results for the partial radial distribution functions show that the liquid structure is closely related to that of the crystals. A close similarity between solid and liquid is also found for the electronic density of states and charge density. The calculated electronic conductivity decreases strongly with increasing Se content, in accord with experimental measurements.Comment: REVTeX, 8 pages and 12 uuencoded PostScript figures, submitted to Phys. Rev. B. corresponding author: [email protected]