The Osmotic Coefficient of Rod-like Polyelectrolytes: Computer Simulation, Analytical Theory, and Experiment

The osmotic coefficient of solutions of rod-like polyelectrolytes is considered by comparing current theoretical treatments and simulations to recent experimental data. The discussion is restricted to the case of monovalent counterions and dilute, salt-free solutions. The classical Poisson-Boltzmann solution of the cell model correctly predicts a strong decrease in the osmotic coefficient, but upon closer look systematically overestimates its value. The contribution of ion-ion-correlations are quantitatively studied by MD simulations and the recently proposed DHHC theory. However, our comparison with experimental data obtained on synthetic, stiff-chain polyelectrolytes shows that correlation effects can only partly explain the discrepancy. A quantitative understanding thus requires theoretical efforts beyond the restricted primitive model of electrolytes.Comment: 16 pages, 2 figure

New variational and multisymplectic formulations of the Euler-Poincar\'e equation on the Virasoro-Bott group using the inverse map

We derive a new variational principle, leading to a new momentum map and a new multisymplectic formulation for a family of Euler--Poincar\'e equations defined on the Virasoro-Bott group, by using the inverse map (also called `back-to-labels' map). This family contains as special cases the well-known Korteweg-de Vries, Camassa-Holm, and Hunter-Saxton soliton equations. In the conclusion section, we sketch opportunities for future work that would apply the new Clebsch momentum map with $2$-cocycles derived here to investigate a new type of interplay among nonlinearity, dispersion and noise.Comment: 19 page

On a unified formulation of completely integrable systems

The purpose of this article is to show that a $\mathcal{C}^1$ differential system on $\R^n$ which admits a set of $n-1$ independent $\mathcal{C}^2$ conservation laws defined on an open subset $\Omega\subseteq \R^n$, is essentially $\mathcal{C}^1$ equivalent on an open and dense subset of $\Omega$, with the linear differential system $u^\prime_1=u_1, \ u^\prime_2=u_2,..., \ u^\prime_n=u_n$. The main results are illustrated in the case of two concrete dynamical systems, namely the three dimensional Lotka-Volterra system, and respectively the Euler equations from the free rigid body dynamics.Comment: 11 page

Effect of grass–clover forage and whole-wheat feeding on the sensory quality of eggs

BACKGROUND: A sensory panel evaluated the sensory profile of eggs from hens from three experimental systems: (1) an indoor system × normal layer diet (InL), (2) a grass–clover forage system × normal layer diet (GrL), and (3) a grass–clover forage system × whole wheat and oyster shells (GrW). RESULTS: The taste of the albumen was significantly more ‘watery’ and the yolks a darker yellow/orange in the eggs from the GrL and GrW groups. The yolk was darkest from the GrW group. The yolks from the InL and GrW groups had a significantly more ‘fresh’, less ‘animal’, ‘cardboard’, and ‘intense’ aroma than the GrL group. The taste of the yolks from the InL and GrW groups was significantlymore ‘fresh’ and less ‘cardboard’-like compared to the GrL group. The yolks tasted significantly less ‘sulfurous’ in the GrW group than in the GrL group. CONCLUSION: The combination of a high feed intake from a grass–clover pasture and the type of feed allocated is an important factor in relation to the sensory quality of eggs. Thus, a less favourable sensory profile of eggs was found from hens on a grass–clover pasture and fed a normal layer diet

The free rigid body dynamics: generalized versus classic

In this paper we analyze the normal forms of a general quadratic Hamiltonian system defined on the dual of the Lie algebra $\mathfrak{o}(K)$ of real $K$ - skew - symmetric matrices, where $K$ is an arbitrary $3\times 3$ real symmetric matrix. A consequence of the main results is that any first-order autonomous three-dimensional differential equation possessing two independent quadratic constants of motion which admits a positive/negative definite linear combination, is affinely equivalent to the classical "relaxed" free rigid body dynamics with linear controls.Comment: 12 page

Higher dimensional Reidemeister torsion invariants for cusped hyperbolic 3-manifolds

For an oriented finite volume hyperbolic 3-manifold M with a fixed spin structure \eta, we consider a sequence of invariants {\tau_n(M; \eta)}. Roughly speaking, {\tau_n(M; \eta)} is the Reidemeister torsion of M with respect to the representation given by the composition of the lift of the holonomy representation defined by \eta, and the n-dimensional, irreducible, complex representation of SL(2,C). In the present work, we focus on two aspects of this invariant: its asymptotic behavior and its relationship with the complex-length spectrum of the manifold. Concerning the former, we prove that for suitable spin structures, log(\tau_n(M; \eta)) grows as -n^2 Vol(M)/4\pi, extending thus the result obtained by W. Mueller for the compact case. Concerning the latter, we prove that the sequence {\tau_n(M; \eta)} determines the complex-length spectrum of the manifold up to complex conjugation

Kinetic and ion pairing contributions in the dielectric spectra of electrolyte aqueous solutions

Understanding dielectric spectra can reveal important information about the dynamics of solvents and solutes from the dipolar relaxation times down to electronic ones. In the late 1970s, Hubbard and Onsager predicted that adding salt ions to a polar solution would result in a reduced dielectric permittivity that arises from the unexpected tendency of solvent dipoles to align opposite to the applied field. So far, this effect has escaped an experimental verification, mainly because of the concomitant appearance of dielectric saturation from which the Hubbard-Onsager decrement cannot be easily separated. Here we develop a novel non-equilibrium molecular dynamics simulation approach to determine this decrement accurately for the first time. Using a thermodynamic consistent all-atom force field we show that for an aqueous solution containing sodium chloride around 4.8 Mol/l, this effect accounts for 12\% of the total dielectric permittivity. The dielectric decrement can be strikingly different if a less accurate force field for the ions is used. Using the widespread GROMOS parameters, we observe in fact an {\it increment} of the dielectric permittivity rather than a decrement. We can show that this increment is caused by ion pairing, introduced by a too low dispersion force, and clarify the microscopic connection between long-living ion pairs and the appearance of specific features in the dielectric spectrum of the solution