A qualitative exploration of consumers’ perceived impacts, behavioural reactions, and future reflections of the EU Tobacco Products Directive (2017) as applied to electronic cigarettes

Background: Electronic cigarette regulations included in the Tobacco Products Directive (TPD), Article 20, implemented in Europe by May 2017, aimed to improve safety for e-cigarette consumers, and prevent uptake among non-smokers, particularly young people. Before implementation, there were significant concerns from consumers, industry, and some in the scientific community about the potential negative impact of the TPD on people using e-cigarettes to stay stopped from smoking. To date, there is limited evidence on how the TPD has affected consumers. This study aimed to add insight into how consumers perceived and experienced the regulations. Methods: Qualitative data, collected between March 2018 and March 2019, relating to participant views of the TPD were extracted from 160 interviews/extended surveys of e-cigarette consumers as part of a wider study into e-cigarette use trajectories (ECtra study). Data were thematically analysed. Results: Awareness of the TPD amongst consumers was not universal. Participants’ smoking behaviour did not appear to be influenced by the legislation. Participants were reassured by manufacturing regulations and requirements for ingredients labels. Participants responded negatively to changes perceived to cause inconvenience and extra plastic waste. The product restrictions prompted some participants to purchase non-compliant products illegally, potentially putting their safety at risk. Conclusions: E-cigarette regulation should focus on ensuring product safety. Raising awareness of the TPD amongst consumers and smokers could be beneficial

Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect?

The gauche conformation of the 1,2-difluoroethane motif is known to involve stabilising hyperconjugative interactions between donor (bonding, σC-H) and acceptor (antibonding, σ*C-F) orbitals. This model rationalises the generic conformational preference of F-Cβ-Cα-X systems (φFCCX ≈ 60°), where X is an electron deficient substituent containing a Period 2 atom. Little is known about the corresponding Period 3 systems, such as sulfur and phosphorus, where multiple oxidation states are possible. Conformational analyses of β-fluorosulfides, -sulfoxides and -sulfones are disclosed here, thus extending the scope of the fluorine gauche effect to the 3rd Period (F-C-C-S(O) n ; φFCCS ≈ 60°). Synergy between experiment and computation has revealed that the gauche effect is only pronounced in structures bearing an electropositive vicinal sulfur atom (S+-O-, SO2)

Implications of Lorentz covariance for the guidance equation in two-slit quantum interference

It is known that Lorentz covariance fixes uniquely the current and the associated guidance law in the trajectory interpretation of quantum mechanics for spin particles. In the non-relativistic domain this implies a guidance law for the electron which differs by an additional spin-dependent term from that originally proposed by de Broglie and Bohm. In this paper we explore some of the implications of the modified guidance law. We bring out a property of mutual dependence in the particle coordinates that arises in product states, and show that the quantum potential has scalar and vector components which implies the particle is subject to a Lorentz-like force. The conditions for the classical limit and the limit of negligible spin are given, and the empirical sufficiency of the model is demonstrated. We then present a series of calculations of the trajectories based on two-dimensional Gaussian wave packets which illustrate how the additional spin-dependent term plays a significant role in structuring both the individual trajectories and the ensemble. The single packet corresponds to quantum inertial motion. The distinct features encountered when the wavefunction is a product or a superposition are explored, and the trajectories that model the two-slit experiment are given. The latter paths exhibit several new characteristics compared with the original de Broglie-Bohm ones, such as crossing of the axis of symmetry.Comment: 27 pages including 6 pages of figure

Error analysis of Dobson spectrophotometer measurements of the total ozone content

A study of techniques for measuring atmospheric ozone is reported. This study represents the second phase of a program designed to improve techniques for the measurement of atmospheric ozone. This phase of the program studied the sensitivity of Dobson direct sun measurements and the ozone amounts inferred from those measurements to variation in the atmospheric temperature profile. The study used the plane - parallel Monte-Carlo model developed and tested under the initial phase of this program, and a series of standard model atmospheres

Condition matters: pupil voices on the design and condition of secondary schools

This research was produced by Sheffield Hallam University. The project aimed to inform the creation of a national schools Facilities Management network and an ongoing programme to research and benchmark the impact of school condition and design on pupils

Entangled-state cryptographic protocol that remains secure even if nonlocal hidden variables exist and can be measured with arbitrary precision

Standard quantum cryptographic protocols are not secure if one assumes that nonlocal hidden variables exist and can be measured with arbitrary precision. The security can be restored if one of the communicating parties randomly switches between two standard protocols.Comment: Shortened version, accepted in Phys. Rev.

Analysis of SPAR 8 single-axis levitation experiment

The melting and resolidification of SPAR 8 payload melting and resolidification of a glass specimen from the in a containerless condition and the retrieval and examination of the specimen from the. The absence of container contact was assured by use of a single-axis acoustic levitation system. However, the sample contacted a wire cage after being held without container contact by the acoustic field for only approximately 87 seconds. At this time, the sample was still molten and, therefore, flowed aroung the wire and continued to adhere to it. An analysis of why the sample did not remain levitated free of container contact is presented. The experiment is described, and experimental observations are discussed and analyzed

Classical and quantum massive cosmology for the open FRW universe

In an open Friedmann-Robertson-Walker (FRW) space background, we study the classical and quantum cosmological models in the framework of the recently proposed nonlinear massive gravity theory. Although the constraints which are present in this theory prevent it from admitting the flat and closed FRW models as its cosmological solutions, for the open FRW universe, it is not the case. We have shown that, either in the absence of matter or in the presence of a perfect fluid, the classical field equations of such a theory adopt physical solutions for the open FRW model, in which the mass term shows itself as a cosmological constant. These classical solutions consist of two distinguishable branches: One is a contacting universe which tends to a future singularity with zero size, while another is an expanding universe having a past singularity from which it begins its evolution. A classically forbidden region separates these two branches from each other. We then employ the familiar canonical quantization procedure in the given cosmological setting to find the cosmological wave functions. We use the resulting wave function to investigate the possibility of the avoidance of classical singularities due to quantum effects. It is shown that the quantum expectation values of the scale factor, although they have either contracting or expanding phases like their classical counterparts, are not disconnected from each other. Indeed, the classically forbidden region may be replaced by a bouncing period in which the scale factor bounces from the contraction to its expansion eras. Using the Bohmian approach of quantum mechanics, we also compute the Bohmian trajectory and the quantum potential related to the system, which their analysis shows are the direct effects of the mass term on the dynamics of the universe.Comment: 18 pages, 7 figures, typos corrected, refs. adde

Unraveling quantum dissipation in the frequency domain

We present a quantum Monte Carlo method for solving the evolution of an open quantum system. In our approach, the density operator evolution is unraveled in the frequency domain. Significant advantages of this approach arise when the frequency of each dissipative event conveys information about the state of the system.Comment: 4 pages, 4 Postscript figures, uses RevTe

The role of the Initial Teacher Training Coordinator in the school based element of partnership: to what extent does the Co-ordinator undertake supervision of aspects of quality assurance?

Over the last 14 years, Universities and colleges have organised school placements and award qualifications whilst teachers, acting as mentors take the lead in guiding, supervising and assessing students on lengthy teaching placements. Partnership developed quickly in response to legislation and Sheffield Hallam University was among the first of the Universities to 'sign up' to the new partnership model in 1992. The Partnership Survey 2006 reported on in this paper has focussed on the Senior Liaison Tutor with a view to finding out their views on their role, and perceived contributions to the quality assurance of the partnership. The survey focussed on some of the key issues identified in previous studies and meetings of the Partnership Management Board.</p