Temperature effects on the 15-85-micron spectra of olivines and pyroxenes

Far-infrared spectra of laboratory silicates are normally obtained at room temperature even though the grains responsible for astronomical silicate emission bands seen at wavelengths >20 micron are likely to be at temperatures below ~150 K. In order to investigate the effect of temperature on silicate spectra, we have obtained absorption spectra of powdered forsterite and olivine, along with two orthoenstatites and diopside clinopyroxene, at 3.5+-0.5 K and at room temperature (295+-2K). To determine the changes in the spectra the resolution must be increased from 1 to 0.25 cm^-1 at both temperatures since a reduction in temperature reduces the phonon density, thereby reducing the width of the infrared peaks. Several bands observed at 295 K split at 3.5 K. At 3.5 K the widths of isolated single bands in olivine, enstatites and diopside are ~ 90% of their 295 K-widths. However, in forsterite the 3.5-K-widths of the 31-, 49- and 69-micron bands are, respectively, 90%, 45% and 31% of their 295 K widths. Due to an increase in phonon energy as the lattice contracts, 3.5-K-singlet peaks occur at shorter wavelengths than do the corresponding 295-K peaks; the magnitude of the wavelength shift increases from \~ 0-0.2 micron at 25 micron to ~0.9 micron at 80 micron. Changes in the relative absorbances of spectral peaks are also observed. The temperature dependence of lambda_pk and bandwidth shows promise as a means to deduce characteristic temperatures of mineralogically distinct grain populations. In addition, the observed changes in band strength with temperature will affect estimates of grain masses and relative mineral abundances inferred using room-temperature laboratory data.Comment: 11 pages, 7 figures including figures 3a and 3b. includes latex and eps files. Accepted by MNRAS on 15th March 200

Infrared Spectra of Pyroxenes (Crystalline Chain Silicates) at Room Temperature

Pyroxene crystals are common in meteorites but few compositions have been recognized in astronomical environments. We present quantitative room-temperature spectra of 17 Mg-- Fe-- and Ca--bearing ortho- and clinopyroxenes, and a Ca-pyroxenoid in order to discern trends indicative of crystal structure and a wide range of composition. Data are produced using a Diamond Anvil Cell: our band strengths are up to 6 times higher than those measured in KBr or polyethylene dispersions, which include variations in path length (from grain size) and surface reflections that are not addressed in data processing. Pyroxenes have varied spectra: only two bands, at 10.22~$\mu$m and 15.34~$\mu$m in enstatite (En$_{99}$), are common to all. Peak-wavelengths generally increase as Mg is replaced by Ca or Fe. However, two bands in MgFe-pyroxenes shift to shorter wavelengths as the Fe component increases from 0 to 60 per cent. A high-intensity band shifts from 11.6~$\mu$m to 11.2~$\mu$m and remains at 11.2~$\mu$m as Fe increases to 100~per~cent; it resembles an astronomical feature normally identified with olivine or forsterite. The distinctive pyroxene bands between 13~ and 16~$\mu$m show promise for their identification in MIRI spectra obtained with JWST. The many pyroxene bands between 40 and 80~$\mu$m could be diagnositic of silicate mineralogy if data were obtained with the proposed SPICA telescope. Our data indicate that comparison between room-temperature laboratory bands for enstatite and cold $\sim 10-K$ astronomical dust features at wavelengths $\gtrsim 28~\mu$m can result in the identification of (Mg,Fe)- pyroxenes that contain 7--15 % less Fe-- than their true values because some temperature shifts mimic some compositional shifts. Therefore some astronomical silicates may contain more Fe, and less Mg, than previously thought.Comment: 16 pages, 10 figures.accepted in MNRA

Sakurai's Object revisited: new laboratory data for carbonates and melilites suggest the carrier of 6.9-?m excess absorption is a carbonate

We present new room-temperature 1100–1800-cm−1 spectra of melilite silicates and 600–2000-cm−1 spectra of three randomly orientated fine-grained carbonates to determine the possible carrier(s) of a 6.9-μm absorption feature observed in a variety of dense astronomical environments, including young stellar objects and molecular clouds. We focus on the low-mass post-asymptotic giant branch star Sakurai’s Object, which has been forming substantial quantities of carbonaceous dust since an eruptive event in the 1990s. Large melilite grains cannot be responsible for the 6.9-μm absorption feature because the similarly shaped feature in the laboratory spectrum was produced by very low (0.1 per cent by mass) carbonate contamination, which was not detected at other wavelengths. Due to the high band strength of the 6.9-μm feature in carbonates, we conclude that carbonates carry the astronomical 6.9-μm feature. Replacement of melilite with carbonates in models of Sakurai’s Object improves fits to the 6–7-μm Spitzer spectra without significantly altering other conclusions of Bowey’s previous models except that there is no link between the feature and the abundance of melilite in meteorites. With magnesite (MgCO3), the abundance of 25-μm-sized SiC grains is increased by 10–50 per cent and better constrained. The mass of carbonate dust is similar to the mass of polycyclic aromatic hydrocarbon dust. Existing experiments suggest that carbonates are stable below 700 K; however, it is difficult to ascertain the applicability of these experiments to astronomical environments, and more studies are required

Two-temperature coronal flow above a thin disk

We extended the disk corona model (Meyer & Meyer-Hofmeister 1994; Meyer, Liu, & Meyer-Hofmeister 2000a) to the inner region of galactic nuclei by including different temperatures in ions and electrons as well as Compton cooling. We found that the mass evaporation rate and hence the fraction of accretion energy released in the corona depend strongly on the rate of incoming mass flow from outer edge of the disk, a larger rate leading to more Compton cooling, less efficient evaporation and a weaker corona. We also found a strong dependence on the viscosity, higher viscosity leading to an enhanced mass flow in the corona and therefore more evaporation of gas from the disk below. If we take accretion rates in units of the Eddington rate our results become independent on the mass of the central black hole. The model predicts weaker contributions to the hard X-rays for objects with higher accretion rate like narrow-line Seyfert 1 galaxies (NLS1s), in agreement with observations. For luminous active galactic nuclei (AGN) strong Compton cooling in the innermost corona is so efficient that a large amount of additional heating is required to maintain the corona above the thin disk.Comment: 17 pages, 6 figures. ApJ accepte

Infrared spectra of pyroxenes (crystalline chain silicates) at room temperature

Crystals of pyroxene are common in meteorites but few compositions have been recognized in astronomical environments due to the limited chemistries included in laboratory studies. We present quantitative room-temperature spectra of 17 Mg-, Fe-, and Ca-bearing ortho- and clinopyroxenes, and a Ca-pyroxenoid in order to discern trends indicative of crystal structure and a wide range of composition. Data are produced using a diamond anvil cell: our band strengths are up to six times higher than those measured in KBr or polyethylene dispersions, which include variations in path length (from grain size) and surface reflections that are not addressed in data processing. Pyroxenes have varied spectra: only two bands, at 10.22 and 15.34 μm in enstatite (En99), are common to all. Peak wavelengths generally increase as Mg is replaced by Ca or Fe. However, two bands in MgFe-pyroxenes shift to shorter wavelengths as the Fe component increases from 0 to 60 per cent. A high-intensity band shifts from 11.6 to 11.2 μm and remains at 11.2 μm as Fe increases to 100 per cent; it resembles an astronomical feature normally identified with olivine or forsterite. The distinctive pyroxene bands between 13 and 16 μm show promise for their identification in Mid-Infrared-Instrumentspectra obtained with the James Webb Space Telescope. The many pyroxene bands between 40 and 80 μm could be diagnositic of silicate mineralogy if data were obtained with the proposed Space Infrared Telescope for Cosmology and Astrophysics. Our data indicate that comparison between room-temperature laboratory bands for enstatite and cold ∼10 − K astronomical dust features at wavelengths ≳28 μm can result in the identification of (Mg,Fe)- pyroxenes that contain 7–15 per cent less Fe– than their true values because some temperature shifts mimic some compositional shifts. Therefore some astronomical silicates may contain more Fe, and less Mg, than previously thought

Closed-Loop Process Control for Electron Beam Freeform Fabrication and Deposition Processes

A closed-loop control method for an electron beam freeform fabrication (EBF(sup 3)) process includes detecting a feature of interest during the process using a sensor(s), continuously evaluating the feature of interest to determine, in real time, a change occurring therein, and automatically modifying control parameters to control the EBF(sup 3) process. An apparatus provides closed-loop control method of the process, and includes an electron gun for generating an electron beam, a wire feeder for feeding a wire toward a substrate, wherein the wire is melted and progressively deposited in layers onto the substrate, a sensor(s), and a host machine. The sensor(s) measure the feature of interest during the process, and the host machine continuously evaluates the feature of interest to determine, in real time, a change occurring therein. The host machine automatically modifies control parameters to the EBF(sup 3) apparatus to control the EBF(sup 3) process in a closed-loop manner

A Long, Hard Look at the Low-Hard State in Accreting Black Holes

We present the first results of coordinated multi-wavelength observations of the Galactic black hole GX 339-4 in a canonical low-hard state, obtained during its 2004 outburst. XMM-Newton observed the source for 2 revolutions, or approximately 280 ksec; RXTE monitored the source throughout this long stare. The resulting data offer the best view yet obtained of the inner accretion flow geometry in the low-hard state, which is thought to be analogous to the geometry in low-luminosity active galactic nuclei. The XMM-Newton spectra clearly reveal the presence of a cool accretion disk component, and a relativistic Fe K emission line. The results of fits made to both components strongly suggest that a standard thin disk remains at or near to the innermost stable circular orbit, at least in bright phases of the low-hard state. These findings indicate that potential links between the inner disk radius and the onset of a steady compact jet, and the paradigm of a radially-recessed disk in the low-hard state, do not hold universally. The results of our observations can best be explained if a standard thin accretion disk fuels a corona which is closely related to, or consistent with, the base of a compact jet. In a brief examination of archival data, we show that Cygnus X-1 supports this picture of the low/hard state. We discuss our results within the context of disk-jet connections and prevailing models for accretion onto black holes.Comment: 13 pages, 10 figures (6 in color), ApJ, in pres

On hydrogen bond correlations at high pressures

In situ high pressure neutron diffraction measured lengths of O H and H O pairs in hydrogen bonds in substances are shown to follow the correlation between them established from 0.1 MPa data on different chemical compounds. In particular, the conclusion by Nelmes et al that their high pressure data on ice VIII differ from it is not supported. For compounds in which the O H stretching frequencies red shift under pressure, it is shown that wherever structural data is available, they follow the stretching frequency versus H O (or O O) distance correlation. For compounds displaying blue shifts with pressure an analogy appears to exist with improper hydrogen bonds.Comment: 12 pages,4 figure