Thermodynamic stability of H2 + tetrahydrofuran mixed gas hydrate in nonstoichiometric aqueous solutions

Phase equilibria (pressure - temperature relations) of the H2 + tetrahydrofuran mixed gas hydrate system have been measured for various concentrations of tetrahydrofuran aqueous solutions. The three-phase equilibrium lines obtained in the present study are shifted to the low-temperature or high-pressure side from that of the stoichiometric THF solution. Each three-phase equilibrium line of H2 + tetrahydrofuran hydrate converges at the three-phase equilibrium line of the pure tetrahydrofuran hydrate. At the cross point on the lines, the tetrahydrofuran concentration of mother aqueous solution agrees with each other. The Raman spectra of H 2 and tetrahydrofuran for the H2 + tetrahydrofuran mixed gas hydrate do not change with the variation of tetrahydrofuran mole fraction from 0.010 to 0.130 in the aqueous solution. © 2007 American Chemical Society.Shunsuke Hashimoto, Takeshi Sugahara, Hiroshi Sato et al. Thermodynamic Stability of H2 + Tetrahydrofuran Mixed Gas Hydrate in Nonstoichiometric Aqueous Solutions. Journal of Chemical & Engineering Data, 52 (1), 517-520, March 1, © 2007 American Chemical Society. https://doi.org/10.1021/je060436

Relativistic Hartree approach with exact treatment of vacuum polarization for finite nuclei

We study the relativistic Hartree approach with the exact treatment of the vacuum polarization in the Walecka sigma-omega model. The contribution from the vacuum polarization of nucleon-antinucleon field to the source term of the meson fields is evaluated by performing the energy integrals of the Dirac Green function along the imaginary axis. With the present method of the vacuum polarization in finite system, the total binding energies and charge radii of 16O and 40Ca can be reproduced. On the other hand, the level-splittings in the single-particle level, in particular the spin-orbit splittings, are not described nicely because the inclusion of vacuum effect provides a large effective mass with small meson fields. We also show that the derivative expansion of the effective action which has been used to calculate the vacuum contribution for finite nuclei gives a fairly good approximation.Comment: 15 pages, 8 figure

SPR METHOD : REHABILITATION TECHNOLOGIES TO REVIVE DECREPIT PIPELINES

Abstract In the SPR (Sewage Pipe Renewal) method, a rigid PVC liner is formed inside an existing pipe by using a specially designed winding machine that is placed inside the existing pipe. A rigid PVC profile strip is fed through a manhole entrance above ground, and the winding machine is used to wind and interlock the profiles together to form a liner. Rehabilitation technologies are needed that can cope with various existing installation site conditions; i.e. long or curved pipelines, with round, square or horseshoe shaped crossections. Under such circumstances, we have developed a new technology to form the PVC liner in which self running winding machenes travel around a frame that is set inside the existing pipeline, and which is made to conform to the interior cross sectional shape of the pipe

Exploring the Interplay between Mythology and ‘Beyond the Horizon’: A Memorandum

application/pdfdepartmental bulletin pape

Identification of amino acid residues of mammalian mitochondrial phosphate carrier important for its functional expression in yeast cells, as achieved by PCR-mediated random mutation and gap-repair cloning

The mitochondrial phosphate carrier (PiC) of mammals, but not the yeast one, is synthesized with a presequence. The deletion of this presequence of the mammalian PiC was reported to facilitate the import of the carrier into yeast mitochondria, but the question as to whether or not mammalian PiC could be functionally expressed in yeast mitochondria was not addressed. In the present study, we first examined whether the defective growth on a glycerol plate of yeast cells lacking the yeast PiC gene could be reversed by the introduction of expression vectors of rat PiCs. The introduction of expression vectors encoding full-length rat PiC (rPiC) or rPiC lacking the presequence (ΔNrPiC) was ineffective in restoring growth on the glycerol plates. When we examined the expression levels of individual rPiCs in yeast mitochondria, ΔNrPiC was expressed at a level similar to that of yeast PiC, but that of rPiC was very low. These results indicated that ΔNrPiC expressed in yeast mitochondria is inert. Next, we sought to isolate “revertants” viable on the glycerol plate by expressing randomly mutated ΔNrPiC, and obtained two clones. These clones carried either of two mutations, F267S or F282S; and these mutations restored the transport function of ΔNrPiC in yeast mitochondria. These two Phe residues were conserved in human carrier (hPiC), and the transport function of ΔNhPiC expressed in yeast mitochondria was also markedly improved by their substitutions. Thus, substitution of F267S or F282S was concluded to be important for functional expression of mammalian PiCs in yeast mitochondria

Big Three Dragons: A [N II] 122 μ\mum Constraint and New Dust-continuum Detection of A z=7.15z = 7.15 Bright Lyman Break Galaxy with ALMA

We present new Atacama Large Millimeter/submillimeter Array Band 7 observational results of a Lyman break galaxy at $z=7.15$, B14-65666 ("Big Three Dragons"), which is an object detected in [OIII] 88 $\rm{\mu m}$, [CII] 158 $\rm{\mu m}$, and dust-continuum emission during the epoch of reionization. Our targets are the [NII] 122 $\rm{\mu m}$ fine-structure emission line and underlying 120 $\rm{\mu m}$ dust continuum. The dust continuum is detected with a $\sim$19$\sigma$ significance. From far-infrared spectral energy distribution sampled at 90, 120, and 160 $\rm{\mu m}$, we obtaine a best-fit dust temperature of $40$ K ($79$ K) and an infrared luminosity of $\log_{10}(L_{\rm IR}/{\rm L}_\odot)=11.6$ ($12.1$) at the emissivity index $\beta = 2.0$ (1.0). The [NII] 122 $\rm{\mu m}$ line is not detected. The 3$\sigma$ upper limit of the [NII] luminosity is $8.1 \times 10^7\ {\rm L}_\odot$. From the [NII], [OIII], and [CII] line luminosities, we use the Cloudy photoionization code to estimate nebular parameters as functions of metallicity. If the metallicity of the galaxy is high ($Z > 0.4\ {\rm Z}_\odot$), the ionization parameter and hydrogen density are $\log_{10} U \simeq -2.7\pm0.1$ and $n_\text{H} \simeq 50$-$250\ {\rm cm}^{-3}$, respectively, which are comparable to those measured in low-redshift galaxies. The nitrogen-to-oxygen abundance ratio, $\rm{N/O}$, is constrained to be sub-solar. At $Z < 0.4\ {\rm Z}_\odot$, the allowed $U$ drastically increases as the assumed metallicity decreases. For high ionization parameters, the $\rm{N/O}$ constraint becomes weak. Finally, our Cloudy models predict the location of B14-65666 on the BPT diagram, thereby allowing a comparison with low-redshift galaxies.Comment: 17 pages, 13 figures, 2 tables. accepted for publication in Ap

Comprehensive Analysis of Inflammatory Immune Mediators in Vitreoretinal Diseases

Inflammation affects the formation and the progression of various vitreoretinal diseases. We performed a comprehensive analysis of inflammatory immune mediators in the vitreous fluids from total of 345 patients with diabetic macular edema (DME, n = 92), proliferative diabetic retinopathy (PDR, n = 147), branch retinal vein occlusion (BRVO, n = 30), central retinal vein occlusion (CRVO, n = 13) and rhegmatogenous retinal detachment (RRD, n = 63). As a control, we selected a total of 83 patients with either idiopathic macular hole (MH) or idiopathic epiretinal membrane (ERM) that were free of major pathogenic intraocular changes, such as ischemic retina and proliferative membranes. The concentrations of 20 soluble factors (nine cytokines, six chemokines, and five growth factors) were measured simultaneously by multiplex bead analysis system. Out of 20 soluble factors, three factors: interleukin-6 (IL-6), interleukin-8 (IL-8), and monocyte chemoattractant protein-1 (MCP-1) were significantly elevated in all groups of vitreoretinal diseases (DME, PDR, BRVO, CRVO, and RRD) compared with control group. According to the correlation analysis in the individual patient's level, these three factors that were simultaneously increased, did not show any independent upregulation in all the examined diseases. Vascular endothelial growth factor (VEGF) was significantly elevated in patients with PDR and CRVO. In PDR patients, the elevation of VEGF was significantly correlated with the three factors: IL-6, IL-8, and MCP-1, while no significant correlation was observed in CRVO patients. In conclusion, multiplex bead system enabled a comprehensive soluble factor analysis in vitreous fluid derived from variety of patients. Major three factors: IL-6, IL-8, and MCP-1 were strongly correlated with each other indicating a common pathway involved in inflammation process in vitreoretinal diseases

Large Population of ALMA Galaxies at z>6 with Very High [OIII]88um to [CII]158um Flux Ratios: Evidence of Extremely High Ionization Parameter or PDR Deficit?

We present our new ALMA observations targeting [OIII]88um, [CII]158um, [NII]122um, and dust continuum emission for three Lyman break galaxies at z=6.0293-6.2037 identified in the Subaru/Hyper Suprime-Cam survey. We clearly detect [OIII] and [CII] lines from all of the galaxies at 4.3-11.8sigma levels, and identify multi-band dust continuum emission in two of the three galaxies, allowing us to estimate infrared luminosities and dust temperatures simultaneously. In conjunction with previous ALMA observations for six galaxies at z>6, we confirm that all the nine z=6-9 galaxies have high [OIII]/[CII] ratios of L[OIII]/L[CII]~3-20, ~10 times higher than z~0 galaxies. We also find a positive correlation between the [OIII]/[CII] ratio and the Lya equivalent width (EW) at the ~90% confidence level. We carefully investigate physical origins of the high [OIII]/[CII] ratios at z=6-9 using Cloudy, and find that high density of the interstellar medium, low C/O abundance ratio, and the cosmic microwave background attenuation are responsible to only a part of the z=6-9 galaxies. Instead, the observed high [OIII]/[CII] ratios are explained by 10-100 times higher ionization parameters or low photodissociation region (PDR) covering fractions of 0-10%, both of which are consistent with our [NII] observations. The latter scenario can be reproduced with a density bounded nebula with PDR deficit, which would enhance the Lya, Lyman continuum, and C+ ionizing photons escape from galaxies, consistent with the [OIII]/[CII]-Lya EW correlation we find.Comment: 20 pages, 18 figures, Accepted for publication in Ap

Charge- and parity-projected Hartree-Fock method for the strong tensor correlation and its application to the alpha particle

We propose a new mean-field-type framework which can treat the strong correlation induced by the tensor force. To treat the tensor correlation we break the charge and parity symmetries of a single-particle state and restore these symmetries of the total system by the projection method. We perform the charge and parity projections before variation and obtain a Hartree-Fock-like equation, which is solved self-consistently. We apply the Hartree-Fock-like equation to the alpha particle and find that by breaking the parity and charge symmetries, the correlation induced by the tensor force is obtained in the projected mean-field framework. We emphasize that the projection before the variation is important to pick up the tensor correlation in the present framework.Comment: 21 pages, 2 figure