Crystallization Behavior And Micromorphology Of Sol-gel Derived Mesoporous Nano-particles Titania

CRYSTALLIZATION BEHAVIOR AND MICROMORPHOLOGY OF SOL-GEL DERIVED MESOPOROUS NANO-PARTICLES TITANIA. In this work, effects of drying methods on the micro-morphology ofinesoporpous TiO2 prepared by the sol-gel method has been studied using transmission electron microscopy (TEM), X-ray diffraction analysis (XRD) and N2 gas adsorption. Mesoporous TiO2 consists of anatase nano-particles, about 5nm in diameter, have been obtained by hydrolysis of titanium alkoxide in a methanol solution and supercritical extraction in CO2 at 60°C and 22Mpa. XRD peaks ofrutile have been found after annealing at 600°C. The particle sizes of anatase and rutile are about 13 and 25nm in diameter, respectively. The surface morphology of Ti02 nano-particles has been discussed with the surface fractal dimensions estimated from the N2 gas adsorption isotherms

Electromagnetic Response of a kx±ikyk_x\pm ik_y Superconductor: Effect of Order Parameter Collective Modes

Effects of order parameter collective modes on electromagnetic response are studied for a clean spin-triplet superconductor with $k_x\pm ik_y$ orbital symmetry, which has been proposed as a candidate pairing symmetry for Sr$_2$RuO$_4$. It is shown that the $k_x \pm ik_y$ superconductor has characteristic massive collective modes analogous to the clapping mode in the A-phase of superfluid $^3$He. We discuss the contribution from the collective modes to ultrasound attenuation and electromagnetic absorption. We show that in the electromagnetic absorption spectrum the clapping mode gives rise to a resonance peak well below the pair breaking frequency, while the ultrasound attenuation is hardly influenced by the collective excitations.Comment: 4 pages RevTex, 1 eps figur

Leading Temperature Corrections to Fermi Liquid Theory in Two Dimensions

We calculate the basic parameters of the Fermi Liquid: the scattering vertex, the Landau interaction function, the effective mass, and physical susceptibilities for a model of two-dimensional (2D) fermions with a short ranged interaction at non-zero temperature. The leading temperature dependences of the spin components of the scattering vertex, the Landau function, and the spin susceptibility are found to be linear. T-linear terms in the effective mass and in the ``charge-sector''- quantities are found to cancel to second order in the interaction, but the cancellation is argued not to be generic. The connection with previous studies of the 2D Fermi-Liquid parameters is discussed.Comment: 4 pages, 1 figur

Giant Extrinsic Spin Hall Effect due to Rare-Earth Impurities

We investigate the extrinsic spin Hall effect in the electron gas model due to magnetic impurities, by focusing on Ce- and Yb-impurities. In the dilute limit, the skew scattering term dominates the side jump term. For Ce-impurities, the spin Hall angle $\alpha_{\rm SH}$ due to skew scattering is given by $-8\pi\sin\delta_2/7$, where $\delta_2 (\ll 1)$ is the phase shift for$d (l=2)$ partial wave. Since $\alpha_{\rm SH}$ reaches $O(10^{-1})$ if \delta_2 \simge 0.03, the spin Hall effect is anticipated to be considerable in metals with rare-earth impurities. The giant extrinsic SHE originates from the large orbital angular momentum, which is also significant for the intrinsic SHE.Comment: 5 pages, 3 figures, to be published in New Journal of Physic

Phase Diagram of the Electron-Doped Cuprate Superconductors

We investigate the phase diagram of the electron-doped systems in high-Tc cuprates. We calculate the superconducting transition temperature Tc, the antiferromagnetic transition temperature TN, the NMR relaxation rate 1/T1 with the antiferromagnetic fluctuations in the fluctuation-exchange (FLEX) approximation and with the superconducting fluctuations in the self-consistent t-matrix approximation. Obtained phase diagram has common features as those in the hole-doped systems, including the antiferromagnetic state, the superconducting state and the spin gap phenomenon. Doping-dependences of TN, Tc and Tsg (spin gap temperature) are, however, different with those in the hole-doped systems. These differences are due to the intrinsic nature of the ingap states which are intimately related with the Zhang-Rice singlets in the hole-doped systems and are correlated d-electrons in the electron-doped systems, respectively, which has been shown in the d-p model.Comment: 4 pages, 3 figure

Anomalous Transport Phenomena in Fermi Liquids with Strong Magnetic Fluctuations

In many strongly correlated electron systems, remarkable violation of the relaxation time approximation (RTA) is observed. The most famous example would be high-Tc superconductors (HTSCs), and similar anomalous transport phenomena have been observed in metals near their antiferromagnetic (AF) quantum critical point (QCP). Here, we develop a transport theory involving resistivity and Hall coefficient on the basis of the microscopic Fermi liquid theory, by considering the current vertex correction (CVC). In nearly AF Fermi liquids, the CVC accounts for the significant enhancements in the Hall coefficient, magnetoresistance, thermoelectric power, and Nernst coefficient in nearly AF metals. According to the numerical study, aspects of anomalous transport phenomena in HTSC are explained in a unified way by considering the CVC, without introducing any fitting parameters; this strongly supports the idea that HTSCs are Fermi liquids with strong AF fluctuations. In addition, the striking \omega-dependence of the AC Hall coefficient and the remarkable effects of impurities on the transport coefficients in HTSCs appear to fit naturally into the present theory. The present theory also explains very similar anomalous transport phenomena occurring in CeCoIn5 and CeRhIn5, which is a heavy-fermion system near the AF QCP, and in the organic superconductor \kappa-(BEDT-TTF).Comment: 100 pages, Rep. Prog. Phys. 71, 026501 (2008

Primary skin fibroblasts as a model of Parkinson's disease

Parkinson's disease is the second most frequent neurodegenerative disorder. While most cases occur sporadic mutations in a growing number of genes including Parkin (PARK2) and PINK1 (PARK6) have been associated with the disease. Different animal models and cell models like patient skin fibroblasts and recombinant cell lines can be used as model systems for Parkinson's disease. Skin fibroblasts present a system with defined mutations and the cumulative cellular damage of the patients. PINK1 and Parkin genes show relevant expression levels in human fibroblasts and since both genes participate in stress response pathways, we believe fibroblasts advantageous in order to assess, e.g. the effect of stressors. Furthermore, since a bioenergetic deficit underlies early stage Parkinson's disease, while atrophy underlies later stages, the use of primary cells seems preferable over the use of tumor cell lines. The new option to use fibroblast-derived induced pluripotent stem cells redifferentiated into dopaminergic neurons is an additional benefit. However, the use of fibroblast has also some drawbacks. We have investigated PARK6 fibroblasts and they mirror closely the respiratory alterations, the expression profiles, the mitochondrial dynamics pathology and the vulnerability to proteasomal stress that has been documented in other model systems. Fibroblasts from patients with PARK2, PARK6, idiopathic Parkinson's disease, Alzheimer's disease, and spinocerebellar ataxia type 2 demonstrated a distinct and unique mRNA expression pattern of key genes in neurodegeneration. Thus, primary skin fibroblasts are a useful Parkinson's disease model, able to serve as a complement to animal mutants, transformed cell lines and patient tissues

Iterated perturbation theory for the attractive Holstein and Hubbard models

A strictly truncated (weak-coupling) perturbation theory is applied to the attractive Holstein and Hubbard models in infinite dimensions. These results are qualified by comparison with essentially exact Monte Carlo results. The second order iterated perturbation theory is shown to be quite accurate in calculating transition temperatures for retarded interactions, but is not as accurate for the self energy or the irreducible vertex functions themselves. Iterated perturbation theory is carried out thru fourth order for the Hubbard model. The self energy is quite accurately reproduced by the theory, but the vertex functions are not. Anomalous behavior occurs near half filling because the iterated perturbation theory is not a conserving approximation. (REPLACED WITH UUENCODED FIGURES AT THE END. THE TEXT IS UNCHANGED)Comment: 27 pages, RevTex (figures appended at end