2,122 research outputs found

    Statistical mechanics of temporal association in neural networks with transmission delays

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    We study the representation of static patterns and temporal sequences in neural networks with signal delays and a stochastic parallel dynamics. For a wide class of delay distributions, the asymptotic network behavior can be described by a generalized Gibbs distribution, generated by a novel Lyapunov functional for the determination dynamics. We extend techniques of equilibrium statistical mechanics so as to deal with time-dependent phenomena, derive analytic results for both retrieval quality and storage capacity, and compare them with numerical simulations

    Exciton bimolecular annihilation dynamics in supramolecular nanostructures of conjugated oligomers

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    We present femtosecond transient absorption measurements on π\pi-conjugated supramolecular assemblies in a high pump fluence regime. Oligo(\emph{p}-phenylenevinylene) monofunctionalized with ureido-\emph{s}-triazine (MOPV) self-assembles into chiral stacks in dodecane solution below 75^{\circ}C at a concentration of 4×1044\times 10^{-4} M. We observe exciton bimolecular annihilation in MOPV stacks at high excitation fluence, indicated by the fluence-dependent decay of 111^1Bu_{u}-exciton spectral signatures, and by the sub-linear fluence dependence of time- and wavelength-integrated photoluminescence (PL) intensity. These two characteristics are much less pronounced in MOPV solution where the phase equilibrium is shifted significantly away from supramolecular assembly, slightly below the transition temperature. A mesoscopic rate-equation model is applied to extract the bimolecular annihilation rate constant from the excitation fluence dependence of transient absorption and PL signals. The results demonstrate that the bimolecular annihilation rate is very high with a square-root dependence in time. The exciton annihilation results from a combination of fast exciton diffusion and resonance energy transfer. The supramolecular nanostructures studied here have electronic properties that are intermediate between molecular aggregates and polymeric semiconductors

    Why, what, and how? case study on law, risk, and decision making as necessary themes in built environment teaching

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    The paper considers (and defends) the necessity of including legal studies as a core part of built environment undergraduate and postgraduate curricula. The writer reflects upon his own experience as a lawyer working alongside and advising built environment professionals in complex land remediation and site safety management situations in the United Kingdom and explains how themes of liability, risk, and decision making can be integrated into a practical simulation in order to underpin more traditional lecture-based law teaching. Through reflection upon the writer's experiments with simulation-based teaching, the paper suggests some innovations that may better orientate law teaching to engage these themes and, thereby, enhance the relevance of law studies to the future needs of built environment professionals in practice.</p

    Temperature Dependence of Exciton Diffusion in Conjugated Polymers

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    The temperature dependence of the exciton dynamics in a conjugated polymer is studied using time-resolved spectroscopy. Photoluminescence decays were measured in heterostructured samples containing a sharp polymer-fullerene interface, which acts as an exciton quenching wall. Using a 1D diffusion model, the exciton diffusion length and diffusion coefficient were extracted in the temperature range of 4-293 K. The exciton dynamics reveal two temperature regimes: in the range of 4-150 K, the exciton diffusion length (coefficient) of ~3 nm (~1.5 × 10-4 cm2/s) is nearly temperature independent. Increasing the temperature up to 293 K leads to a gradual growth up to 4.5 nm (~3.2 × 10-4 cm2/s). This demonstrates that exciton diffusion in conjugated polymers is governed by two processes: an initial downhill migration toward lower energy states in the inhomogenously broadened density of states, followed by temperature activated hopping. The latter process is switched off below 150 K.

    Phase Diagram for the Winfree Model of Coupled Nonlinear Oscillators

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    In 1967 Winfree proposed a mean-field model for the spontaneous synchronization of chorusing crickets, flashing fireflies, circadian pacemaker cells, or other large populations of biological oscillators. Here we give the first bifurcation analysis of the model, for a tractable special case. The system displays rich collective dynamics as a function of the coupling strength and the spread of natural frequencies. Besides incoherence, frequency locking, and oscillator death, there exist novel hybrid solutions that combine two or more of these states. We present the phase diagram and derive several of the stability boundaries analytically.Comment: 4 pages, 4 figure

    Noncommutative Figa-Talamanca-Herz algebras for Schur multipliers

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    We introduce a noncommutative analogue of the Fig\'a-Talamanca-Herz algebra Ap(G)A_p(G) on the natural predual of the operator space Mp,cb\frak{M}_{p,cb} of completely bounded Schur multipliers on Schatten space SpS_p. We determine the isometric Schur multipliers and prove that the space Mp\frak{M}_{p} of bounded Schur multipliers on Schatten space SpS_p is the closure in the weak operator topology of the span of isometric multipliers.Comment: 24 pages; corrected typo

    Spatial representation of temporal information through spike timing dependent plasticity

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    We suggest a mechanism based on spike time dependent plasticity (STDP) of synapses to store, retrieve and predict temporal sequences. The mechanism is demonstrated in a model system of simplified integrate-and-fire type neurons densely connected by STDP synapses. All synapses are modified according to the so-called normal STDP rule observed in various real biological synapses. After conditioning through repeated input of a limited number of of temporal sequences the system is able to complete the temporal sequence upon receiving the input of a fraction of them. This is an example of effective unsupervised learning in an biologically realistic system. We investigate the dependence of learning success on entrainment time, system size and presence of noise. Possible applications include learning of motor sequences, recognition and prediction of temporal sensory information in the visual as well as the auditory system and late processing in the olfactory system of insects.Comment: 13 pages, 14 figures, completely revised and augmented versio

    Jacobi structures revisited

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    Jacobi algebroids, that is graded Lie brackets on the Grassmann algebra associated with a vector bundle which satisfy a property similar to that of the Jacobi brackets, are introduced. They turn out to be equivalent to generalized Lie algebroids in the sense of Iglesias and Marrero and can be viewed also as odd Jacobi brackets on the supermanifolds associated with the vector bundles. Jacobi bialgebroids are defined in the same manner. A lifting procedure of elements of this Grassmann algebra to multivector fields on the total space of the vector bundle which preserves the corresponding brackets is developed. This gives the possibility of associating canonically a Lie algebroid with any local Lie algebra in the sense of Kirillov.Comment: 20 page

    Associative memory storing an extensive number of patterns based on a network of oscillators with distributed natural frequencies in the presence of external white noise

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    We study associative memory based on temporal coding in which successful retrieval is realized as an entrainment in a network of simple phase oscillators with distributed natural frequencies under the influence of white noise. The memory patterns are assumed to be given by uniformly distributed random numbers on [0,2π)[0,2\pi) so that the patterns encode the phase differences of the oscillators. To derive the macroscopic order parameter equations for the network with an extensive number of stored patterns, we introduce the effective transfer function by assuming the fixed-point equation of the form of the TAP equation, which describes the time-averaged output as a function of the effective time-averaged local field. Properties of the networks associated with synchronization phenomena for a discrete symmetric natural frequency distribution with three frequency components are studied based on the order parameter equations, and are shown to be in good agreement with the results of numerical simulations. Two types of retrieval states are found to occur with respect to the degree of synchronization, when the size of the width of the natural frequency distribution is changed.Comment: published in Phys. Rev.

    Noise Stabilization of Self-Organized Memories

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    We investigate a nonlinear dynamical system which ``remembers'' preselected values of a system parameter. The deterministic version of the system can encode many parameter values during a transient period, but in the limit of long times, almost all of them are forgotten. Here we show that a certain type of stochastic noise can stabilize multiple memories, enabling many parameter values to be encoded permanently. We present analytic results that provide insight both into the memory formation and into the noise-induced memory stabilization. The relevance of our results to experiments on the charge-density wave material NbSe3NbSe_3 is discussed.Comment: 29 pages, 6 figures, submitted to Physical Review
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