4 research outputs found
2-Hydroxy-N′-[2-(6-methoxynaphthalen-2-yl)propanoyl]benzohydrazide
In the title compound, C21H20N2O4, the naphthalene ring system makes a dihedral angle of 84.5 (3)° with the benzene ring, and the –C(=O)–N(H)–N(H)–C(=O)– torsion angle is 70.7 (7)°, so that the molecule is twisted. An S(6) ring motif is formed via an intramolecular O—H⋯O hydrogen bond. In the crystal, molecules are linked by N—H⋯O and C–H⋯O hydrogen bonds into supramolecular layers in the ab plane
7-Bromo-9-(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one
In the xanthene ring system of the title compound, C23H25BrO4, the 4H-pyran ring is almost planar [maximum deviation = 0.040 (3) Å] and the cyclohexene ring adopts a sofa conformation. The cyclohexene ring attached to the xanthene system is puckered [Q
T = 0.427 (3) Å, θ = 55.0 (4) ° and ϕ = 164.4 (6) °]. In the crystal, molecules are linked to each other by O—H⋯O and C—H⋯O hydrogen bonds
4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile
The asymmetric unit of the title Schiff base, C14H11N3O, contains two independent molecules which have similar conformations. The dihedral angles between the benzene rings are 4.19 (9) and 14.18 (9)° in the two molecules. An intramolecular O—H...N hydrogen bond stabilizes the molecular conformation of each molecules. The crystal packing is dominated by pairs of equivalent N—H...N and C—H...O hydrogen bonds which arrange the molecules into layers parallel to (-111)