6 research outputs found
Mechanisms of Nanoglass Ultrastability
The origin of the astonishing properties
of recently discovered
ultrastable nanoglasses is presently not well understood. Nanoglasses
appear to exhibit density variations not common in bulk glasses and
differ significantly in thermal, magnetic, biocompatible, and mechanic
properties from the bulk materials of the same composition. Here,
we investigate a generic model system that permits modeling of both
the physical vapor deposition process (PVD) of the nanoparticles and
their consolidation into a nanoglass. We performed molecular dynamics
simulations to investigate the PVD process generating nanometer-sized
noncrystalline clusters and the formation of the PVD-nanoglass when
these nanoclusters are consolidated. In agreement with the experiments,
we find that the resulting PVD-nanoglass consists of two structural
components: noncrystalline nanometer-sized cores and interfacial regions
that are formed during the consolidation process. The interfacial
regions were found to have an atomic structure and an internal energy
that differ from the structure and internal energy of the corresponding
melt-quenched glass. The resulting material represents a noncrystalline
state that differs from a bulk glass with the same chemical composition
and a glass obtained from nanoparticles derived from the bulk glass
Mechanisms of Nanoglass Ultrastability
The origin of the astonishing properties
of recently discovered
ultrastable nanoglasses is presently not well understood. Nanoglasses
appear to exhibit density variations not common in bulk glasses and
differ significantly in thermal, magnetic, biocompatible, and mechanic
properties from the bulk materials of the same composition. Here,
we investigate a generic model system that permits modeling of both
the physical vapor deposition process (PVD) of the nanoparticles and
their consolidation into a nanoglass. We performed molecular dynamics
simulations to investigate the PVD process generating nanometer-sized
noncrystalline clusters and the formation of the PVD-nanoglass when
these nanoclusters are consolidated. In agreement with the experiments,
we find that the resulting PVD-nanoglass consists of two structural
components: noncrystalline nanometer-sized cores and interfacial regions
that are formed during the consolidation process. The interfacial
regions were found to have an atomic structure and an internal energy
that differ from the structure and internal energy of the corresponding
melt-quenched glass. The resulting material represents a noncrystalline
state that differs from a bulk glass with the same chemical composition
and a glass obtained from nanoparticles derived from the bulk glass
Ni-P nanoglass prepared by multi-phase pulsed electrodeposition
<p>Ni-P nanoglass consisting of nanometer-sized amorphous grains separated by amorphous interfaces was prepared by a specially designed multi-phase pulsed electrodeposition technique. The microstructure of the deposited Ni-P nanoglass was confirmed by X-ray diffraction, high-resolution transmission electron microscopy, small-angle X-ray scattering, and X-ray photoelectron spectroscopy. The formation of the Ni-P nanoglass, which is characterized by inhomogeneities on the nanometer length scale, is achieved via proper control of the rate of cluster formation and cluster growth by a multi-phase pulsed electrodeposition process.</p
Low temperature structural stability of Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses
<p>The structural stability of Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses has been studied by means of low temperature crystallization. Specimens were annealed <i>in situ</i> in a transmission electron microscope, and <i>ex situ</i> in an ultra-high vacuum tube-furnace. Both studies led to similar results. The structure of the Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses was stable for up to 2 h when annealed at 150°C. Annealing the Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses at higher temperature resulted in the formation of the nanocrystalline bcc-Fe(Sc).</p> <p><b>Impact statement</b></p> <p>The structural evolution of Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses has been studied in detail during low temperature annealing. Our results indicate that the nanostructure of Fe<sub>90</sub>Sc<sub>10</sub> nanoglasses is quite stable at low temperature.</p
Enhanced inter-diffusion of immiscible elements Fe/Cu at the interface of FeZr/CuZr amorphous multilayers
<p>Fe<sub>75</sub>Zr<sub>25</sub>/Cu<sub>64</sub>Zr<sub>36</sub> amorphous multilayers were prepared by magnetron sputtering. Atom probe tomography was employed to analyze the atomic inter-diffusion at the interface of the multilayers before and after annealing (573 K, 60 min). An unexpected enhanced inter-diffusion of the immiscible elements Fe and Cu was detected at the interface of the multilayers. As the inter-diffusion in amorphous multilayers is much faster than that in the crystalline counterparts, this process may open a way to manipulate or create amorphous multilayers with new properties. This idea agrees with the observation of the variation of magnetic properties of Fe<sub>75</sub>Zr<sub>25</sub>/Cu<sub>64</sub>Zr<sub>36</sub> amorphous multilayers.</p> <p><b>IMPACT STATEMENT</b> This paper reveals the enhanced atomic inter-diffusion at the interface of amorphous materials, and may open a way to manipulate or create amorphous multilayers with new properties.</p
Nanoscale Structural Evolution and Anomalous Mechanical Response of Nanoglasses by Cryogenic Thermal Cycling
One
of the central themes in the amorphous materials research is
to understand the nanoscale structural responses to mechanical and
thermal agitations, the decoding of which is expected to provide new
insights into the complex amorphous structural-property relationship.
For common metallic glasses, their inherent atomic structural inhomogeneities
can be rejuvenated and amplified by cryogenic thermal cycling, thus
can be decoded from their responses to mechanical and thermal agitations.
Here, we reported an anomalous mechanical response of a new kind of
metallic glass (nanoglass) with nanoscale interface structures to
cryogenic thermal cycling. As compared to those metallic glasses by
liquid quenching, the Sc<sub>75</sub>Fe<sub>25</sub> (at. %) nanoglass
exhibits a decrease in the Young’s modulus but a significant
increase in the yield strength after cryogenic cycling treatments.
The abnormal mechanical property change can be attributed to the complex
atomic rearrangements at the short- and medium- range orders due to
the intrinsic nonuniformity of the nanoglass architecture. The present
work gives a new route for designing high-performance metallic glassy
materials by manipulating their atomic structures and helps for understanding
the complex atomic structure–property relationship in amorphous
materials