A high-resolution magnetic record of drift sediments in the neighbourhood of mound provinces in the Porcupine Seabight

The Porcupine Seabight forms a deep embayment in the Atlantic margin, off the south-western coast of Ireland. Very-high resolution seismic profiling, acquired since 1997, revealed the presence of large (carbonate) mounds.In general, the mounds are surrounded by bottom-current related deposits. The changes of seismic characteristics within the uppermost unit are interpreted as phases in a slope parallel drift under changing oceanographic conditions.The magnetic susceptibility records of two giant piston cores (MD01-2450 and MD01-2452), taken respectively in the drift sediments at the SE-flank of a Belgica mound (eastern flank of the basin) and above a Magellan mound (northern flank of the basin), were analysed in order to provide a relative time frame and to investigate possible changes in paleoceanography and paleoclimatology.Core MD01-2450 enabled us to propose a relative dating of over 74 ka, which has been confirmed by comparing the intensity of the NRM (Natural Remanent Magnetization) to ARM (Anhysteretic Remanent Magnetization) ratio with known intensity data. Another very remarkable observation in this core is the presence of iron sulfides between 630 and 1080 cm depth. This local iron sulfide enrichment could be the result of an anaerobic process with sulfate reduction during a period of non-steady-state diagenesis.Core MD01-2452, located in the sediments on top of the buried Magellan mounds, shows more pronounced paleoclimatological changes than the core located at the SE-flank of the Belgica mound. Moreover, typical HL can be recognized very clearly from magnetic susceptibility and P-wave velocity data during the latest glacial. The influence of European HE in the northern part of the basin could be less than on the eastern flank. However, we should be bear in mind that currents seem to be much weaker in the Magellan province than in the Belgica province. These weaker currents can be responsible for better preserved and thus more pronounced paleoclimatological and paleoceanographic changes in the uppermost quaternary sediment layers

COCARDE: new view on old mounds – an international network of carbonate mound research

EGU2012-12550 Carbonate mounds are important contributors of life in different settings, from warm-water to cold-water environments, and throughout geological history. Research on modern cold-water coral carbonate mounds over the last decades made a major contribution to our overall understanding of these particular sedimentary systems. By looking to the modern carbonate mound community with cold-water corals as main framework builders, some fundamental questions could be addressed, until now not yet explored in fossil mound settings. The international network COCARDE (http://www.cocarde.eu) is a platform for exploring new insights in carbonate mound research of recent and ancient mound systems. The aim of the COCARDE network is to bring together scientific communities, studying Recent carbonate mounds in midslope environments in the present ocean and investigating fossil mounds spanning the whole Phanerozoic time, respectively. Scientific challenges in modern and ancient carbonate mound research got well defined during the ESF Magellan Workshop COCARDE in Fribourg, Switzerland (21.–24.01.2009). The Special Volume Cold-water Carbonate Reservoir systems in Deep Environments – COCARDE (Marine Geology, Vol. 282) was the major outcome of this meeting and highlights the diversity of Recent arbonate mound studies. The following first jointWorkshop and Field Seminar held in Oviedo, Spain (16.–20.09.2009) highlighted ongoing research from both Recent and fossil academic groups integrating the message from the industry. The field seminar focused on mounds from the Carboniferous platform of Asturias and Cantabria, already intensively visited by industrial and academic researchers. However, by comparing ancient, mixed carbonate-siliciclastic mound systems of Cantabria with the Recent ones in the Porcupine Seabight, striking similarities in their genesis and processes in mound development asked for an integrated drilling campaign to understand better the 3D internal mound build-up. The Oviedo Workshop and Field Seminar led to the submission of a White Paper on Carbonate Mound Drilling and the initiation of the ESF European Research Network Programme Cold-Water Carbonate Mounds in Shallow and Deep Time – The European Research Network (COCARDE-ERN) launched in June 2011. The second COCARDE Workshop and Field Seminar was held in Rabat, Morocco (24.–30.10.2011) and thematically focussed on carbonate mounds of(f) Morocco. The compact workshop invited students from Moroccan Universities to experience ongoing carbonate mound research in Recent and Ancient environments of Morocco. Two Round Tables discussed innovative approaches in carbonate mound research in Morocco (Recent vs. Ancient - offshore vs. onshore) and reviewed together with oil industry opportunities of international collaboration. The outcome of this workshop will lead into joint research projects, drilling campaigns on- and offshore, and expansion of COCARDE onto the African continent

Drilling Challenger Mound (Porcupine Basin,W of Ireland): a contribution to European research on the microbial mediation in carbonate formation at low temperatures?

In his monumental master work ‘The Face of the Earth’, the eminent Vienna geologist Eduard Suess has formulated visionary thoughts on fundamental topics ranging from the tectonic nature of Europe’s margins to the role of the ‘Biosphere’, a word that he had coined in 1875. This word turned into a concept of Life as a Geological Force through the vision of Vladimir I. Vernadksy (Biosfera, 1920). Recent studies (Vasconselos et al. 1995) have unveiled the possible role of microbial mediation in the formation of natural dolomite, a mineral named after Déodat de Dolomieu (1750-1801).But some of the most spectacular geological bodies, built by Life as a Geological Force, are the carbonate mounds. Carbonate mounds from the fossil record provide evidence of microbial mediation in the mound build-up and stabilization (Henriet et al. 2002). The study of carbonate mounds and associated cold-water coral reefs forms one of the first priorities of IOC/UNESCO’s new programme “Geosphere-Biosphere Coupling Processes” (GBCP).IODP Expedition 307 (Modern Carbonate Mounds: Porcupine Drilling) sets sail end of April, 2005 to the Porcupine Seabight, West of Ireland, to investigate the possible role of geofluids, microbial consortia and cold-water corals in the genesis and growth of Challenger mound, a giant carbonate mound towering over 170m above an enigmatic erosional surface, in water depths close to 1000m

TOBI sidescan sonar mapping of carbonate mound provinces and channel heads in the Porcupine Seabight, W. of Ireland

A large-scale sidescan sonar survey, using the 30 kHz TOBI system of the SOC, was carried out in summer 2002 over the carbonate mound provinces of the Porcupine Seabight and Rockall Trough, W of Ireland (EASSS III contract HPRI-CT-1999-00047, survey partly on behalf of the Porcupine Studies Group). The survey in the Porcupine Seabight focused on the Hovland-Magellan province in the north and the Belgica province on the eastern flank of the basin. Furthermore a reconnaissance track was added over the canyon heads of the Gollum Channel System further south in the Seabight.Each area has different characteristics. The Hovland-Magellan province shows a very homogeneous backscatter in the sidescan mosaics, indicating a quiet depositional environment. Mounds appear as sharp features with a strong backscatter and an acoustic shadow. Some Hovland mounds form multiple, ridge-like structures of more than a km in length. The Magellan mounds are nearly all buried, but leave subtle topographic effects at the seafloor.The Belgica mound province is characterised by much less homogeneous backscatter and a steeper seafloor slope. The mounds are placed en echelon along the slope and are bound to the W by a blind channel. Smaller down-slope channels are also found between the mounds. Many small, high-backscatter features, interpreted as incipient (’Moira’) mounds have been found in this province. Striations in the blind channel, and higher up on the slope of the Belgica province indicate the influence of high current speeds. Pockmarks have been found just south of the Belgica province. The Gollum Channels are steep-flanked, U- or V-shaped channels of ca. 200 m deep. Their steep walls are cut by gullies and feeder channels, and evidence of slope failures is present. Lineations and high-backscatter patches are found on some of the channel floors

Biogeochemistry and geomicrobiology of cold-water coral carbonate mounds - lessons learned from IODP Expedition 307

Large mound structures associated with cold-water coral ecosystems commonly occur on the slopes of continental margins, for instance, west of Ireland in the Porcupine Seabight, the Gulf of Cadiz or the Straits of Florida. In the Porcupine Seabight over 1500 mounds of up to 5 km in diameter and 250 m height lie at water depths of 600 to 900 m. The cold-water coral reef ecosystems associated with these structures are considered to be “hotspots” of organic carbon mineralization and microbial systems. To establish a depositional and biogeochemical/diagenetic model for cold-water carbonate mounds, Challenger Mound and adjacent continental slope sites were drilled in May 2005 during IODP Expedition 307. One major objective was to test whether deep sub-surface hydrocarbon flow and enhanced microbial activity within the mound structure was important in producing and stabilizing these sedimentary structures.Drilling results showed that the Challenger mound succession (IODP Site U1317) is 130 to 150 meters thick, and mainly consists of floatstone and rudstone facies formed of fine sediments and cold-water branching corals. Pronounced recurring cycles on the scales of several meters are recognized in carbonate content (up to 70% carbonate) and color reflectance, and are probably associated with Pleistocene glacial-interglacial cycles. A role for methane seepage and subsequent anaerobic oxidation was discounted both as a hard-round substrate for mound initiation and as a principal source of carbonate within the mound succession. A broad sulfate-methane transition (approximately 50 m thick) within the Miocene sediments suggested that the zone of anaerobic oxidation of methane principally occurs below the moundbase. In the mound sediments, interstitial water profiles of sulfate, alkalinity, Mg, and Sr suggested a tight coupling between carbonate diagenesis and low rates of microbial sulfate reduction. Overall organic carbon mineralization within cold-water coral mound appeared to be dominated by low rates of iron- and sulfate-reduction that occur in discrete layers within the mound. This was consistent with distributions of total cell-counts, acetate turnover (Webster et al. 2009) and hydrogenase activity (Soffiento et al. 2009). However, biomarker lipid distributions suggested that the Miocene sediments underlying the mound, into which sulfate is diffusing, as well as the sediments from the non-cold water coral reference site (U1318) contain higher abundances of living microbes. The results obtained from Expedition 307 are consistent with a picture emerging from other biogeochemical studies of cold-water coral mound and reef sites. Unless impacted by some external forcing (e.g. fluid flow or erosion event), the microbial activity in the underlying cold-water coral mound sediments is largely decoupled from the highly diverse, active surface ecosystem

Biogeochemistry of carbonate mounds from the Pen Duick escarpment in the Gulf of Cadiz

In the Gulf of Cadiz, carbonate mounds build by cold-water corals were recently discovered on the Renard Ridge, a zone of active fluid flow and mud volcanism. Their sizes vary from 25 to more than 60 m high, at a depth of 520 m and they are aligned along the ridge axis. These mounds, located in the close vicinity of fluid flow markers such as carbonate crusts and mud volcanoes, provided a novel opportunity to study a possible fluid flow control on the mound processes and distribution. Previous geochemical studies on the southernmost mound of the ridge indeed showed that this mound was located on focused fluid flow compared to surrounding sediments, and we observed typical profiles of methane migration and anoxic oxidation (AOM) at 3,8 m below the sea floor within the mound. Such AOM occurrence imprinted a characteristic d13C signature (down to –21,9 %¸ Vs. PDB) and significantly contributes to the overall carbonate budget of the mound.During the recent R/V Maria S. Merian cruise (April-June 2006), we sampled by mean of a gravity corer six new structures likely to be cold-water carbonate mounds, along the Pen Duick escarpment and the Renard Ridge. Our aim was to determine if the geochemical profiles observed in the first mound could be generalized to all the mounds in this area.Each core yielded a full sequence of cold-water corals down to about 5 meters below the sea floor. Hence, the numerous knoll-like structures revealed by high-resolution bathymetry along the ridge are indeed carbonate mounds build by cold-water corals and the entire Ridge has been massively colonized by corals. No live reef-forming coral could be recovered from the cores, nor observed by towed video instruments. Then, fluid migration seems to be a common feature all along the ridge. However, important discrepancies were observed: methane concentrations are higher and sulfate gradients steeper on both side of the ridge, whereas the central part of the ridge seems less active in term of fluid migration. In this case, the sulfate to methane transition zone could not be reached using conventional gravity corer. In order to obtain the full biogeochemical picture of these mounds, the use of a long piston corer, or drilling devices, will be required.The reasons of the formation of massive reefs in this area are still unknown and are probably linked to locally enhanced hydrologic conditions. However, it is possible that cold-water coral could have benefited from the hard substrate and the topographic elevations provided by fluid related structures such as carbonate crusts, chimneys and clasts, as observed in several other locations in the Gulf of Cadiz

Cenozoic inversion of the Weald-Boulonnais and the Dover Strait: new data

The Boulonnais is a former marine gulf superimposed on a zone of tectonic inversion, which was already excavated at least at the early Middle Eocene. New sedimentalogical and paleopedological data discover within the Boulonnais and fresh seismic sections able now to better understand the process of inversion step by step. The initial breaching probably took place in the late Eocene. The Dover Strait was probably open during the Lutetian, a part of the Oligocene and of the Late Neogene. Oligocene and Pliocene faunal assemblages are identical on both sides of the Strait. It was closed again for tectonic and eustatic reasons in the early Quaternary and reopen lately from Last Interglacial. This reopening is related with the evolution of the Western Channel and of its paleovalley system. This inversion of the Variscan front accommodates most of the shortening induced by the Pyrenean Orogen on the Western border of the European plate. The inversion of the Dover Strait region is almost synchronic with those of other basins of the Channel and North Sea areas. Tectonic, geomorphologic and climatic implications of this dynamic are discussed within the Western European context

The early diagenetic and PETROphysical behaviour of recent cold-water CARbonate mounds in Deep Environments (PETROCARDE)

Sub-recent cold-water carbonate mounds localized in deeper slope settings on the Atlantic continental margins cannot be any longer neglected in the study of carbonate systems. They clearly play a major role in the dynamics of mixed siliciclastic-carbonate and/or carbonate-dominated continental slopes. Carbonate accumulation rates of cold-water carbonate mounds are about 4 to 12 % of the carbonate accumulation rates of tropical shallow-water reefs but exceed the carbonate accumulation rates of their slope settings by a factor of 4 to 12 (Titschack et al.,2009). These findings emphasize the importance of these carbonate factories as carbonate niches on the continental margins. The primary environmental architecture of such carbonate bodies is well-characterized. However, despite proven evidences of early diagenesis overprinting the primary environmental record (e.g. aragonite dissolution) (Foubert & Henriet, 2009), the extent of early diagenetic and biogeochemical processes shaping the petrophysical nature of mounds is until now not yet fully understood.Understanding (1) the functioning of a carbonate mound as biogeochemical reactor triggering early diagenetic processes and (2) the impact of early diagenesis on the petrophysical behaviour of a carbonate mound in space and through time are necessary (vital) for the reliable prediction of potential late diagenetic processes. Approaching the fossil carbonate mound record, through a profound study of recent carbonate bodies is innovative and will help to better understand processes observed in the fossil mound world (such as cementation, brecciation, fracturing, etc. . . ).In this study, the 155-m high Challenger mound (Porcupine Seabight, SW of Ireland), drilled during IODP Expedition 307 aboard the R/V Joides Resolution (Foubert & Henriet, 2009), and mounds from the Gulf of Cadiz (Moroccan margin) will be discussed in terms of early diagenetic processes and petrophysical behaviour. Early differential diagenesis overprints the primary environmental signals in Challenger mound, with extensive coral dissolution and the genesis of small-scaled semi-lithified layers in the Ca-rich intervals. The low cementation rates compared to the extensive dissolution patterns can be explained by an open-system diagenetic model. Moreover, Pirlet et al. (2009) emphasizes the occurrence of gypsum and dolomite in another mound system (Mound Perseverance) in Porcupine Seabight, which might be also related with fluid oxidation events in a semi-open diagenetic system. Along the Moroccan margins, fluid seepage and fluxes in pore water transport affect the development of mound structures, enhancing extensive cold-water coral dissolution and precipitation of diagenetic minerals such as dolomite, calcite, pyrite, etc. (Foubert et al., 2008). Recent carbonate mounds provide indeed an excellent opportunity to study early diagenetic processes in carbonate systems without the complications of burial and/or later meteoric diagenesis