706 research outputs found
Exchange couplings in the magnetic molecular cluster Mn12Ac
The magnetic properties of the molecular cluster Mn12Ac are due to the four
Mn3+ ions which have spins S=3/2 and the eight Mn4+ ions with spins S=2. These
spins are coupled by superexchange mechanism. We determine the four exchange
couplings assuming a Heisenberg-type interaction between the ions. We use exact
diagonalization of the spin Hamiltonian by a Lanczos algorithm and we adjust
the couplings to reproduce the magnetization curve of Mn12Ac. We also impose
the constraint of reproducing a gap of 35K between a S=10 ground state and a
first excited state with S=9. We predict that there is an excited level with
S=8 at 37K above the ground state, only slightly above the S=9 excited state
which lies at 35K and the next excited state is a S=9 multiplet at 67K above
the S=10 ground state.Comment: 15 pages, 6 figures, submitted to Phys Rev B, corrected a misTeX:
values of J1, J2 have changed, refs update
Inhomogeneous Magnetism in La-doped CaMnO3. (II) Mesoscopic Phase Separation due to Lattice-coupled FM Interactions
A detailed investigation of mesoscopic magnetic and crystallographic phase
separation in Ca(1-x)La(x)MnO3, 0.00<=x<=0.20, is reported. Neutron powder
diffraction and DC-magnetization techniques have been used to isolate the
different roles played by electrons doped into the eg level as a function of
their concentration x. The presence of multiple low-temperature magnetic and
crystallographic phases within individual polycrystalline samples is argued to
be an intrinsic feature of the system that follows from the shifting balance
between competing FM and AFM interactions as a function of temperature. FM
double-exchange interactions associated with doped eg electrons are favored
over competing AFM interactions at higher temperatures, and couple more
strongly with the lattice via orbital polarization. These FM interactions
thereby play a privileged role, even at low eg electron concentrations, by
virtue of structural modifications induced above the AFM transition
temperatures.Comment: 8 pages, 7 figure
Low energy magnetic excitations of the Mn_{12}-acetate spin cluster observed by neutron scattering
We performed high resolution diffraction and inelastic neutron scattering
measurements of Mn_{12}-acetate. Using a very high energy resolution, we could
separate the energy levels corresponding to the splitting of the lowest S
multiplet. Data were analyzed within a single spin model (S=10 ground state),
using a spin Hamiltonian with parameters up to 4^{th} order.
The non regular spacing of the transition energies unambiguously shows the
presence of high order terms in the anisotropy (D= -0.457(2) cm^{-1}, B_4^0 =
-2.33(4) 10^{-5}cm^{-1}).
The relative intensity of the lowest energy peaks is very sensitive to the
small transverse term, supposed to be mainly responsible for quantum tunneling.
This allows an accurate determination of this term in zero magnetic field
(B_4^4 = \pm 3.0(5) 10^{-5} cm^{-1}). The neutron results are discussed in view
of recent experiments and theories.Comment: 4 pages ? 3 figures, submitted to Physical Review Lette
Inhomogeneous magnetism in La-doped CaMnO3. (I) Nanometric-scale spin clusters and long-range spin canting
Neutron measurements on Ca{1-x}La{x}MnO3 (0.00 <= x <= 0.20) reveal the
development of a liquid-like spatial distribution of magnetic droplets of
average size ~10 Angstroms, the concentration of which is proportional to x
(one cluster per ~60 doped electrons). In addition, a long-range ordered
ferromagnetic component is observed for ~0.05 < x < ~0.14. This component is
perpendicularly coupled to the simple G-type antiferromagnetic (G-AFM)
structure of the undoped compound, which is a signature of a G-AFM + FM
spin-canted state. The possible relationship between cluster formation and the
stabilization of a long-range spin-canting for intermediate doping is
discussed.Comment: Submitted to Physical Review
Rôle du massage utérin pratiqué lors de l’insémination artificielle sur le pourcentage des fécondations (Résultats préliminaires)
Besançon R., Brochart Michel, Hennion . Rôle du massage utérin pratiqué lors de l’insémination artificielle sur le pourcentage des fécondations (résultats préliminaires). In: Bulletin de l'Académie Vétérinaire de France tome 103 n°9, 1950. pp. 493-494
Static critical exponents of the ferromagnetic transition in spin glass re-entrant systems
The static critical phenomenology near the Curie temperature of the
re-entrant metallic alloys Au_0.81Fe_0.19, Ni_0.78Mn_0.22, Ni_0.79Mn_0.21 and
amorphous a-Fe_0.98Zr_0.08 is studied using a variety of experimental
techniques and methods of analysis. We have generally found that the values for
the exponents alpha, beta, gamma and delta depart significantly from the
predictions for the 3D Heisenberg model and are intermediate between these
expectations and the values characterizing a typical spin glass transition.
Comparing the exponents obtained in our work with indices for other re-entrant
systems reported in the literature, a weak universality class may be defined
where the exponents distribute within a certain range around average values.Comment: 17 pages, 11 figure
Phase diagram and magnetic properties of LaCaMnO compound for
In this article a detailed study of LaCaMnO () phase diagram using powder x-ray diffraction and magnetization
measurements is presented. Unfortunately, in the related literature no properly
characterized samples have been used, with consequence the smearing of the real
physics in this complicated system. As the present results reveal, there are
two families of samples. The first family concerns samples prepared in
atmosphere ( Atm) which are all ferromagnetic with Curie
temperature rising with . The second family concerns samples, where a post
annealing in nearly zero oxygen partial pressure is applied. These samples show
a canted antiferromagnetic structure for below , while
for an unconventional ferromagnetic insulated phase is
present below . The most important difference between nonstoichiometric
and stoichiometric samples concerning the magnetic behavior, is the anisotropy
in the exchange interactions, in the stoichiometric samples putting forward the
idea that a new orbital ordered phase is responsible for the ferromagnetic
insulating regime in the LaCaMnO compound
Percolative conductivity and critical exponents in mixed-valent manganites
Recent experiments have shown that some colossal magnetoresistance (CMR)
materials exhibit a percolation transition. The conductivity exponent varies
substantially with or without an external magnetic field. This finding prompted
us to carry out theoretical studies of percolation transition in CMR systems.
We find that the percolation transition coincides with the magnetic transition
and this causes a large effect of a magnetic field on the percolation
transition. Using real-space-renormalization method and numerical calculations
for two-dimensional (2D) and three-dimensional (3D) models, we obtain the
conductivity exponent to be 5.3 (3D) and 3.3 (2D) without a magnetic field,
and 1.7 (3D) and 1.4 (2D) with a magnetic field.Comment: 4 pages, 4 figures. To appear in Rapid Communications of Phys. Rev.
Heat Conduction and Magnetic Phase Behavior in Electron-Doped Ca_{1-x} La_x MnO_3(0 <= x <= 0.2)
Measurements of thermal conductivity (kappa) vs temperature are reported for
a series of Ca_{1-x} La_x MnO_3(0 <= x <= 0.2) specimens. For the undoped
(x=0), G-type antiferromagnetic compound a large enhancement of kappa below the
Neel temperature (T_N ~ 125 K) indicates a strong coupling of heat-carrying
phonons to the spin system. This enhancement exhibits a nonmonotonic behavior
with increasing x and correlates remarkably well with the small ferromagnetic
component of the magnetization reported previously [Neumeier and Cohn, Phys.
Rev. B 61 14319 (2000).] Magnetoelastic polaron formation appears to underly
the behavior of kappa and the magnetization at x <= 0.02.Comment: submitted to PRB; 4 pp., 4 Fig.'s, RevTex
Properties of low-lying states in some high-nuclearity Mn, Fe and V clusters: Exact studies of Heisenberg models
Using an efficient numerical scheme that exploits spatial symmetries and spin
parity, we have obtained the exact low-lying eigenstates of exchange
Hamiltonians for the high nuclearity spin clusters, Mn_{12}, Fe_8 and V_{15}.
The largest calculation involves the Mn_{12} cluster which spans a Fock space
of a hundred million. Our results show that the earlier estimates of the
exchange constants need to be revised for the Mn_{12} cluster to explain the
level ordering of low-lying eigenstates. In the case of the Fe_8 cluster,
correct level ordering can be obtained which is consistent with the exchange
constants for the already known clusters with butterfly structure. In the
V_{15} cluster, we obtain an effective Hamiltonian that reproduces exactly, the
eight low-lying eigenvalues of the full Hamiltonian.Comment: Revtex, 12 pages, 16 eps figures; this is the final published versio
- …