Dip coating process: Silicon sheet growth development for the large-area silicon sheet task of the low-cost silicon solar array project

To date, an experimental dip-coating facility was constructed. Using this facility, relatively thin (1 mm) mullite and alumina substrates were successfully dip-coated with 2.5 - 3.0 ohm-cm, p-type silicon with areas of approximately 20 sq cm. The thickness and grain size of these coatings are influenced by the temperature of the melt and the rate at which the substrate is pulled from the melt. One mullite substrate had dendrite-like crystallites of the order of 1 mm wide and 1 to 2 cm long. Their axes were aligned along the direction of pulling. A large variety of substrate materials were purchased or developed enabling the program to commence a substrate definition evaluation. Due to the insulating nature of the substrate, the bottom layer of the p-n junction may have to be made via the top surface. The feasibility of accomplishing this was demonstrated using single crystal wafers

Quantum tunneling in a three dimensional network of exchange coupled single-molecule magnets

A Mn4 single-molecule magnet (SMM) is used to show that quantum tunneling of magnetization (QTM) is not suppressed by moderate three dimensional exchange coupling between molecules. Instead, it leads to an exchange bias of the quantum resonances which allows precise measurements of the effective exchange coupling that is mainly due to weak intermolecular hydrogen bounds. The magnetization versus applied field was recorded on single crystals of [Mn4]2 using an array of micro-SQUIDs. The step fine structure was studied via minor hysteresis loops.Comment: 4 pages, 4 figure

Optical Transparency Using Interference Between Two Modes of a Cavity

In electromagnetically-induced transparency (EIT), the absorption of a probe beam is greatly reduced due to destructive interference between two dressed atomic states produced by a strong laser beam. Here we show that a similar reduction in the single-photon absorption rate can be achieved by tuning a probe beam to be halfway between the resonant frequencies of two modes of a cavity. This technique is expected to be useful in enhancing two-photon absorption while reducing losses due to single-photon scattering.Comment: 4 pages, 5 figure

Crop Species Diversity Changes in the United States: 1978-2012

Citation: Aguilar, J., Gramig, G. G., Hendrickson, J. R., Archer, D. W., Forcella, F., & Liebig, M. A. (2015). Crop Species Diversity Changes in the United States: 1978-2012. Plos One, 10(8), 14. doi:10.1371/journal.pone.0136580Anecdotal accounts regarding reduced US cropping system diversity have raised concerns about negative impacts of increasingly homogeneous cropping systems. However, formal analyses to document such changes are lacking. Using US Agriculture Census data, which are collected every five years, we quantified crop species diversity from 1978 to 2012, for the contiguous US on a county level basis. We used Shannon diversity indices expressed as effective number of crop species (ENCS) to quantify crop diversity. We then evaluated changes in county-level crop diversity both nationally and for each of the eight Farm Resource Regions developed by the National Agriculture Statistics Service. During the 34 years we considered in our analyses, both national and regional ENCS changed. Nationally, crop diversity was lower in 2012 than in 1978. However, our analyses also revealed interesting trends between and within different Resource Regions. Overall, the Heartland Resource Region had the lowest crop diversity whereas the Fruitful Rim and Northern Crescent had the highest. In contrast to the other Resource Regions, the Mississippi Portal had significantly higher crop diversity in 2012 than in 1978. Also, within regions there were differences between counties in crop diversity. Spatial autocorrelation revealed clustering of low and high ENCS and this trend became stronger over time. These results show that, nationally counties have been clustering into areas of either low diversity or high diversity. Moreover, a significant trend of more counties shifting to lower rather than to higher crop diversity was detected. The clustering and shifting demonstrates a trend toward crop diversity loss and attendant homogenization of agricultural production systems, which could have far-reaching consequences for provision of ecosystem system services associated with agricultural systems as well as food system sustainability

Dip coating process: Silicon sheet growth development for the large-area silicon sheet task of the low-cost silicon solar array project

The technical and economic feasibility of producing solar cell quality sheet silicon by dip-coating one surface of carbonized ceramic substrates with a thin layer of large grain polycrystalline silicon was investigated. The dip-coating methods studied were directed toward a minimum cost process with the ultimate objective of producing solar cells with a conversion efficiency of 10% or greater. The technique shows excellent promise for low cost, labor-saving, scale-up potentialities and would provide an end product of sheet silicon with a rigid and strong supportive backing. An experimental dip-coating facility was designed and constructed, several substrates were successfully dip-coated with areas as large as 25 sq cm and thicknesses of 12 micron to 250 micron. There appears to be no serious limitation on the area of a substrate that could be coated. Of the various substrate materials dip-coated, mullite appears to best satisfy the requirement of the program. An inexpensive process was developed for producing mullite in the desired geometry

Chinese and African migrant entrepreneur's articulation shaped by African agency

Much has been written on the relationship of China and Africa in the past decade. However, the subject of Chinese migrant entrepreneurs in Africa and their articulation with African counterparts was little explored up to the early 2010s. Apparently, this research gap has been closed, as shown by four publications in recent years: three edited volumes and one monography, focusing on this subject. In view of early prejudices on the passive or even disapproving reception of Chinese migrants by Africans, the state of the art underlines the importance and scope of African agency vis à vis Chinese migrant entrepreneurs in Africa. This has been underlined unison in the four books under review. Book review of:(1) Giese, Karsten, Marfaing, Laurence (eds) (2016): Entrepreneurs Africains et Chinois. Les impacts sociaux d’une rencontre particulière. Paris: Karthala. (2) Gadzala, Aleksandra W. (ed) (2015): Africa and China: how Africans and their governments are shaping relations with China. Lanham/Md.: Rowman & Littlefield. (3) Mohan, Giles, Lampert, Ben et al (eds) (2014): Chinese Migrants and Africa's Development: new imperialists or agents of change? London: Zed books. (4) French, Howard W. (2015): China's Second Continent: how a million migrants are building a new empire in Africa. London: Penguin Random House / New York: Knopf.On a beaucoup écrit sur la relation entre la Chine et l'Afrique dans la dernière décennie. Cependant, le sujet des entrepreneurs migrants chinois en Afrique et leur articulation avec leurs homologues africains a été peu exploré jusqu'au début des années 2010. Apparemment, cet écart de recherche a été fermé, comme indiqué par quatre publications au cours des dernières années: trois volumes édités et une monographie, en se concentrant sur ce sujet. Compte tenu des premiers préjugés sur la réception passive ou même désapprobateur des migrants chinois par les Africains, l'état de l'art souligne l'importance et la portée de l'agence africaine vis-à-vis des entrepreneurs migrants chinois en Afrique

Tunneling Splittings in Mn12-Acetate Single Crystals

A Landau-Zener multi-crossing method has been used to investigate the tunnel splittings in high quality Mn$_{12}$-acetate single crystals in the pure quantum relaxation regime and for fields applied parallel to the magnetic easy axis. With this method several individual tunneling resonances have been studied over a broad range of time scales. The relaxation is found to be non-exponential and a distribution of tunnel splittings is inferred from the data. The distributions suggest that the inhomogeneity in the tunneling rates is due to disorder that produces a non-zero mean value of the average transverse anisotropy, such as in a solvent disorder model. Further, the effect of intermolecular dipolar interaction on the magnetic relaxation has been studied.Comment: Europhysics Letters (in press). 7 pages, including 3 figure