Measurement of g-factor tensor in a quantum dot and disentanglement of exciton spins

We perform polarization-resolved magneto-optical measurements on single InAsP quantum dots embedded in an InP nanowire. In order to determine all elements of the electron and hole $g$-factor tensors, we measure in magnetic field with different orientations. The results of these measurements are in good agreement with a model based on exchange terms and Zeeman interaction. In our experiment, polarization analysis delivers a powerful tool that not only significantly increases the precision of the measurements, but also enables us to probe the exciton spin state evolution in magnetic fields. We propose a disentangling scheme of heavy-hole exciton spins enabling a measurement of the electron spin $T_2$ time

Single-photon Resolved Cross-Kerr Interaction for Autonomous Stabilization of Photon-number States

Quantum states can be stabilized in the presence of intrinsic and environmental losses by either applying active feedback conditioned on an ancillary system or through reservoir engineering. Reservoir engineering maintains a desired quantum state through a combination of drives and designed entropy evacuation. We propose and implement a quantum reservoir engineering protocol that stabilizes Fock states in a microwave cavity. This protocol is realized with a circuit quantum electrodynamics platform where a Josephson junction provides direct, nonlinear coupling between two superconducting waveguide cavities. The nonlinear coupling results in a single photon resolved cross-Kerr effect between the two cavities enabling a photon number dependent coupling to a lossy environment. The quantum state of the microwave cavity is discussed in terms of a net polarization and is analyzed by a measurement of its steady state Wigner function.Comment: 8 pages, 6 figure

Efficient and robust fiber coupling of superconducting single photon detectors

We applied a recently developed fiber coupling technique to superconducting single photon detectors (SSPDs). As the detector area of SSPDs has to be kept as small as possible, coupling to an optical fiber has been either inefficient or unreliable. Etching through the silicon substrate allows fabrication of a circularly shaped chip which self aligns to the core of a ferrule terminated fiber in a fiber sleeve. In situ alignment at cryogenic temperatures is unnecessary and no thermal stress during cooldown, causing misalignment, is induced. We measured the quantum efficiency of these devices with an attenuated tunable broadband source. The combination of a lithographically defined chip and high precision standard telecommunication components yields near unity coupling efficiency and a system detection efficiency of 34% at a wavelength of 1200 nm. This quantum efficiency measurement is confirmed by an absolute efficiency measurement using correlated photon pairs (with $\lambda$ = 1064 nm) produced by spontaneous parametric down-conversion. The efficiency obtained via this method agrees well with the efficiency measured with the attenuated tunable broadband source

Torque measurement as a tool to monitor the breakdown of cassava starch gels, by the effect of Fenton's initiator for graft copolymerization

The use of a combined stirrer-torque meter allows for monitoring viscosity during polymerizations and other reactions, much faster and more continuous than off-line viscosity measurements. This method was applied in previous research about the grafting of acrylic acid onto cassava starch using Fenton's initiator. In this article the method is used to assess the effect of Fenton's initiator on gels of cassava starch in the absence of the monomer. The intention here is to activate the starch selectively first, which could improve graft selectivity. The interaction of a redox graft copolymerization initiator with starch gels when there is no monomer in the system yet, is hardly ever addressed in grafting literature. Remarkably, the present experimental study shows a rapid viscosity decrease of the starch gel, in the order of 70% in less than 2 min, at conditions reflecting graft copolymerization. This result must be considered a major setback for the application of pre-initiation. Torque measurement also allows to identify the important steps in the reaction of Fenton's reagent with starch without the need to do other, more intensive analyses on the chemistry. For example, it could be concluded that the second stage of Fenton's reaction, the slower decomposition of hydrogen peroxide by Fe3+ ions, accounts for another 20% loss of the original gel viscosity but over a longer period, some 30–60 min. Possible further decrease over a longer period is too slow or small relative to the measuring accuracy of the torque meter. FTIR analyses show the occurrence of peaks at 1730–1740 cm−1 in starch which has been subjected to reaction with Fenton's. These peaks are in the range of the vibrational frequencies associated to C[dbnd]O bonds, that are not present in the original starch. This provides at least a strong indication for oxidative degradation of the starch chains

Deterministic nano-assembly of a coupled quantum emitter - photonic crystal cavity system

The interaction of a single quantum emitter with its environment is a central theme in quantum optics. When placed in highly confined optical fields, such as those created in optical cavities or plasmonic structures, the optical properties of the emitter can change drastically. In particular, photonic crystal (PC) cavities show high quality factors combined with an extremely small mode volume. Efficiently coupling a single quantum emitter to a PC cavity is challenging because of the required positioning accuracy. Here, we demonstrate deterministic coupling of single Nitrogen-Vacancy (NV) centers to high-quality gallium phosphide PC cavities, by deterministically positioning their 50 nm-sized host nanocrystals into the cavity mode maximum with few-nanometer accuracy. The coupling results in a 25-fold enhancement of NV center emission at the cavity wavelength. With this technique, the NV center photoluminescence spectrum can be reshaped allowing for efficient generation of coherent photons, providing new opportunities for quantum science.Comment: 13 pages, 4 figure

Ni-Based Catalysts for the Hydrotreatment of Fast Pyrolysis Oil

Catalytic hydrotreatment is an attractive technology to convert fast pyrolysis oil to stabilized oil products for co processing in conventional crude oil refinery units. We report here the use of novel bimetallic NiCu- and NiPd-based (Picula) catalysts characterized by a high Ni content (29-58 wt %) and prepared using a sol gel method with SiO2, La2O3, kaolin, ZrO2, and combinations thereof as the support, for the catalytic hydrotreatment of fast pyrolysis oil. The experiments were performed in a batch autoclave (1 h at 150 degrees C, 3 h at 350 degrees C, and 200 bar initial pressure at 350 degrees C). The catalyst with the highest nickel loading (58 wt % Ni) promoted with Pd (0.7 wt %) was the most active, yielding oil products with improved properties compared to the crude pyrolysis oil (lower oxygen content, higher solubility in hydrocarbons, and less tendency for coke formation). For all Picula catalysts, except the ZrO2-based catalysts, methane formation was considerably lower than for Ru/C, the benchmark catalyst in catalytic hydrotreatment of fast pyrolysis oil. To anticipate possible catalyst deactivation at very long times on stream, catalyst regeneration studies were performed using thermogravimetric analysis. Analyses of the regenerated catalysts (X-ray diffraction, high-resolution transmission electron microscopy, and Brunauer Emmett Teller surface area) showed the occurrence of active metal agglomeration.</p

Engineered arrays of NV color centers in diamond based on implantation of CN- molecules through nanoapertures

We report a versatile method to engineer arrays of nitrogen-vacancy (NV) color centers in dia- mond at the nanoscale. The defects were produced in parallel by ion implantation through 80 nm diameter apertures patterned using electron beam lithography in a PMMA layer deposited on a diamond surface. The implantation was performed with CN- molecules which increased the NV defect formation yield. This method could enable the realization of a solid-state coupled-spin array and could be used for positioning an optically active NV center on a photonic microstructure.Comment: 12 pages, 3 figure

Spin dynamics in the optical cycle of single nitrogen-vacancy centres in diamond

We investigate spin-dependent decay and intersystem crossing in the optical cycle of single negatively-charged nitrogen-vacancy (NV) centres in diamond. We use spin control and pulsed optical excitation to extract both the spin-resolved lifetimes of the excited states and the degree of optically-induced spin polarization. By optically exciting the centre with a series of picosecond pulses, we determine the spin-flip probabilities per optical cycle, as well as the spin-dependent probability for intersystem crossing. This information, together with the indepedently measured decay rate of singlet population provides a full description of spin dynamics in the optical cycle of NV centres. The temperature dependence of the singlet population decay rate provides information on the number of singlet states involved in the optical cycle.Comment: 11 pages, 5 figure

Quantum Statistics of Surface Plasmon Polaritons in Metallic Stripe Waveguides

Single surface plasmon polaritons are excited using photons generated via spontaneous parametric down-conversion. The mean excitation rates, intensity correlations and Fock state populations are studied. The observed dependence of the second order coherence in our experiment is consistent with a linear uncorrelated Markovian environment in the quantum regime. Our results provide important information about the effect of loss for assessing the potential of plasmonic waveguides for future nanophotonic circuitry in the quantum regime.Comment: 21 pages, 6 figures, published in Nano Letters, publication date (web): March 27 (2012

Принципы организации объектно-ориентированных систем обработки неформализованной информации

Рассматривается класс логико-аналитических систем, использующих специальные лингвистические процессоры и базы знаний (БЗ) для обработки потоков неформализованных документов с целью решения пользовательских задач. На первом этапе формализации текста документа извлекаются информационные объекты и связи, которые образуют структуры знаний и запоминаются в БЗ. На уровне БЗ организуются различные виды анализа и объектных поисков: поиск похожих объектов и ситуаций, поиск по связям и другие. Рассматриваются основные компоненты подобных систем, называемых объектно-ориентированными, их особенности при использовании в различных приложениях: при обработке криминальной информации, при автоматической формализации резюме (заявок на работу), в системах обработки СМИ с выделением террористических групп и их деяний.A class of the logical-analytical systems using special linguistic processors and knowledge bases is considered. Such systems are called object-oriented. These systems are employed for processing of the unstructured documents flow for the user problems decision. At the first stage the document text is formalized: information objects and links are extracted and transferred into the knowledge structures which are stored in the knowledge base (KB). At the level of KB various kinds of analysis and object search are organized: the search for similar objects and situations, the search on the basis of links and other types of search. The basic components of these systems, their main features and the particular use in different applications are considered.The system operation in the subject areas of criminal information processing, automatic formalization of summary texts (applications for work), mass media analysis for extracting information about terrorist formations and their activities are presented