Germanium quantum dots: Optical properties and synthesis

Three different size distributions of Ge quantum dots (>~200, 110, and 60 Å) have been synthesized via the ultrasonic mediated reduction of mixtures of chlorogermanes and organochlorogermanes (or organochlorosilanes) by a colloidal sodium/potassium alloy in heptane, followed by annealing in a sealed pressure vessel at 270 °C. The quantum dots are characterized by transmission electron microscopy, x-ray powder diffraction, x-ray photoemission, infrared spectroscopy, and Raman spectroscopy. Colloidal suspensions of these quantum dots were prepared and their extinction spectra are measured with ultraviolet/visible (UV/Vis) and near infrared (IR) spectroscopy, in the regime from 0.6 to 5 eV. The optical spectra are correlated with a Mie theory extinction calculation utilizing bulk optical constants. This leads to an assignment of three optical features to the E(1), E(0'), and E(2) direct band gap transitions. The E(0') transitions exhibit a strong size dependence. The near IR spectra of the largest dots is dominated by E(0) direct gap absorptions. For the smallest dots the near IR spectrum is dominated by the Gamma25-->L indirect transitions

Radioisotope thermionic power supply for spacecraft

Power supply design for unmanned electric propulsion missions to outer planets utilizes a store of curium-244 in compact array of capsules as energy source. Supply subassemblies are: heat source, converter equipment which supplies power, and safety equipment. System is designed for a 72,000 hour mission

Thermionic reactor power system: Effects of radiation on integration with Manned Space Station

The application of a thermionic reactor power system to the modular space station is described. The nominal net power is 40 kWe, with the power system designed to be applicable over the power range from 25 to 60 kWe. The power system is designed to be launched by the space shuttle. Radiation protection is provided by LiH neutron shielding and W gamma shielding in a shaped 4 pion configuration, i.e., the reactor is shielded on all sides but not to equal extent. Isodose contours are presented for the region around the modular space station. Levels and spectral distribution of radiation are given for later evaluation of effects on space station experiments. Parametric data on the effects of separation distance on power system mass are presented

A mass action model of a fibroblast growth factor signaling pathway and its simplification

We consider a kinetic law of mass action model for Fibroblast Growth Factor (FGF) signaling, focusing on the induction of the RAS-MAP kinase pathway via GRB2 binding. Our biologically simple model suffers a combinatorial explosion in the number of differential equations required to simulate the system. In addition to numerically solving the full model, we show that it can be accurately simplified. This requires combining matched asymptotics, the quasi-steady state hypothesis, and the fact subsets of the equations decouple asymptotically. Both the full and simplified models reproduce the qualitative dynamics observed experimentally and in previous stochastic models. The simplified model also elucidates both the qualitative features of GRB2 binding and the complex relationship between SHP2 levels, the rate SHP2 induces dephosphorylation and levels of bound GRB2. In addition to providing insight into the important and redundant features of FGF signaling, such work further highlights the usefulness of numerous simplification techniques in the study of mass action models of signal transduction, as also illustrated recently by Borisov and co-workers (Borisov et al. in Biophys. J. 89, 951–66, 2005, Biosystems 83, 152–66, 2006; Kiyatkin et al. in J. Biol. Chem. 281, 19925–9938, 2006). These developments will facilitate the construction of tractable models of FGF signaling, incorporating further biological realism, such as spatial effects or realistic binding stoichiometries, despite a more severe combinatorial explosion associated with the latter

Nanocrystal seeding: A low temperature route to polycrystalline Si films

A novel method is presented for growth of polycrystalline silicon films on amorphous substrates at temperatures of 540–575 °C. Grain nucleation and grain growth are performed in two steps, using Si nanocrystals as nuclei ("seeds"). The nanocrystal seeds are produced by excimer laser photolysis of disilane in a room temperature flow cell. Film (grain) growth occurs epitaxially on the seeds in a separate thermal chemical vapor deposition (CVD) step, with growth rates 10–100 times higher than similar CVD growth rates on crystal Si. Grain size and CVD growth rates are dependent on seed coverage, for seed coverage <0.2 monolayers

The geometric properties of an expandable whirling-membrane solar-energy concentrator

Geometric properties of expandable whirling membrane solar energy concentrator used in conjunction with electrical conversion systems for spacecraft auxiliary power unit

Influence of a solar proton event on stratospheric ozone

Ozone depletion in the stratosphere associated with the solar proton event of August 4, 1972, was observed with the backscattered ultraviolet experiment on the Nimbus 4 satellite. An abrupt ozone decrease in the 75-80 deg N zone of about 0.002 atm-cm above 4 mb was observed to persist throughout the month of August. A decrease was noted in the 55-65 deg N zone on days 219 and 220, but recovery occurred on day 221. Thereafter, a more gradual decrease was observed. The equatorial zone also showed gradual decrease after day 218, but these were not uniquely distinguished from seasonal variations. The observed change in total ozone following the event was -0.003 atm-cm for the 75-80 deg N zone, corresponding to a 1.3 percent reduction in the 0.305 atm-cm zonal average, but within the 0.019 atm-cm standard deviation. Above the 10 mb surface in the 75-80 deg N zone however, a decrease of 0.004 atm-cm may be compared with a standard deviation of 0.001 atm-cm

Variations in the stratospheric ozone field inferred from Nimbus satellite observations

The ultraviolet earth radiance data from the Backscatter Ultraviolet Experiment on Nimbus 4 have been inverted to infer ozone profiles using a single Rayleigh scattering model. Two methods of solution give essentially the same results. Comparisons of these profiles with simultaneous rocket sounding data shows satisfactory agreement at low and middle latitudes. Vertical cross sections of ozone mixing ratio along the orbital tracks indicate that while the gross characteristics of the ozone field above 10 mb are under photochemical control, the influence of atmospheric motions can be found up to the 4 mb level

Constructing packings in Grassmannian manifolds via alternating projection

This paper describes a numerical method for finding good packings in Grassmannian manifolds equipped with various metrics. This investigation also encompasses packing in projective spaces. In each case, producing a good packing is equivalent to constructing a matrix that has certain structural and spectral properties. By alternately enforcing the structural condition and then the spectral condition, it is often possible to reach a matrix that satisfies both. One may then extract a packing from this matrix. This approach is both powerful and versatile. In cases where experiments have been performed, the alternating projection method yields packings that compete with the best packings recorded. It also extends to problems that have not been studied numerically. For example, it can be used to produce packings of subspaces in real and complex Grassmannian spaces equipped with the Fubini--Study distance; these packings are valuable in wireless communications. One can prove that some of the novel configurations constructed by the algorithm have packing diameters that are nearly optimal.Comment: 41 pages, 7 tables, 4 figure