699 research outputs found
Large-Scale Preparation of Giant Vesicles by Squeezing a Lipid-Coated Marshmallow-like Silicone Gel in a Buffer
Giant
vesicles were efficiently produced by squeezing a lipid (l-α-phosphatidylcholine from egg yolk)-coated marshmallow-like
flexible macroporous silicone monolith in a buffer. The mean diameter
of the obtained vesicles was 2 μm, showing a wide distribution,
up to tens of micrometers, which was similar to that of vesicles formed
by a natural swelling method. It was possible to prepare vesicle dispersions
on a scale from several microliters to several hundred milliliters.
A protein synthesis system (PURE system) contained in vesicles prepared
using this method functioned effectively. Our absorbing–squeezing
method is expected to help in studies that use giant vesicles such
as artificial cells and drug delivery systems
Theory of multiwave mixing and decoherence control in qubit array system
We develop a theory to analyze the decoherence effect in a charged qubit
array system with photon echo signals in the multiwave mixing configuration. We
present how the decoherence suppression effect by the {\it bang-bang} control
with the pulses can be demonstrated in laboratory by using a bulk
ensemble of exciton qubits and optical pulses whose pulse area is even smaller
than . Analysis is made on the time-integated multiwave mixing signals
diffracted into certain phase matching directions from a bulk ensemble.
Depending on the pulse interval conditions, the cross over from the decoherence
acceleration regime to the decoherence suppression regime, which is a peculiar
feature of the coherent interaction between a qubit and the reservoir bosons,
may be observed in the time-integated multiwave mixing signals in the realistic
case including inhomogeneous broadening effect. Our analysis will successfully
be applied to precise estimation of the reservoir parameters from experimental
data of the direction resolved signal intensities obtained in the multiwave
mixing technique.Comment: 19 pages, 11 figure
Orientation Characteristics of Non-regiocontrolled Poly (3-hexyl-thiophene) Film by FTM on Various Liquid Substrates
Orientation characteristics of non-regiocontrolled poly (3-hexylthiophene) (NR-P3HT) films prepared by dynamic casting of floating film and transferring method (FTM) has been investigated. The film was first cast on liquid-substrate to obtain as a floating-film followed by its transfer on solid-substrate such as white-glass or Si-wafer in order to evaluate their optoelectronic characteristics. As a possible key-factor to generate the orientation of conjugated polymer in this method we focused on the components of liquid-substrate in this study. The orientation dependence upon various liquid-substrates reveals that dichroic ratio strongly changes with liquid-substrates. Pictures of floating-film show the change in size of floating-parts depending upon the liquid-substrate, representing the expansion length of casting solution upon the viscosity. These findings have indicated that spreading speed of polymer solution and solvent evaporation speed controls the size of floating-film leading to change in the orientation intensity. The multilayer coatings of oriented NR-P3HT films were used for polarized FTIR analysis exhibiting clear dichroism. The obtained dichroic characteristics were well corresponded with in-plane, out-of-plane and non-oriented vibronic modes of P3HT.India-Japan Expert Group Meeting on Biomolecular Electronics & Organic Nanotechnology for Environment Preservation (IJEGMBE 2015), December 23-26, 2015, Fukuoka, Japa
spectra in elementary cellular automata and fractal signals
We systematically compute the power spectra of the one-dimensional elementary
cellular automata introduced by Wolfram. On the one hand our analysis reveals
that one automaton displays spectra though considered as trivial, and on
the other hand that various automata classified as chaotic/complex display no
spectra. We model the results generalizing the recently investigated
Sierpinski signal to a class of fractal signals that are tailored to produce
spectra. From the widespread occurrence of (elementary) cellular
automata patterns in chemistry, physics and computer sciences, there are
various candidates to show spectra similar to our results.Comment: 4 pages (3 figs included
Parametric Optimization of Dye-Sensitized Solar Cells Using Far red Sensitizing Dye with Cobalt Electrolyte
A far-red sensitizing dye SQ-75 has been employed as a model sensitizer with Co(bpy)2+/3+ redox electrolytes to fabricate dye-sensitized solar cells (DSSCs) and optimize the various device parameters which influence the overall photoconversion efficiency (PCE). It has been found that the optimization of the TiO2 thickness, surface treatment with TiCl4, and an optimum amount of the chenodeoxycholic acid (CDCA) as coadsorber are necessary to attain the overall improved PCE. TiCl4 surface treatment on both FTO and TiO2 has been found to outperform as compared to their untreated counterparts owing to the suppression of the charge recombination. DSSCs with an optimized TiO2 thickness of 6 μm and CDCA concentration of 4 mM have exhibited best performance due to enhanced photon harvesting and reduced dye aggregation, respectively.12th International Conference on Nanomolecular Electronics (ICNME-2016), December 14-16, 2016, Kobe International Conference Center, Kobe, Japa
Sierpinski signal generates spectra
We investigate the row sum of the binary pattern generated by the Sierpinski
automaton: Interpreted as a time series we calculate the power spectrum of this
Sierpinski signal analytically and obtain a unique rugged fine structure with
underlying power law decay with an exponent of approximately 1.15. Despite the
simplicity of the model, it can serve as a model for spectra in a
certain class of experimental and natural systems like catalytic reactions and
mollusc patterns.Comment: 4 pages (4 figs included). Accepted for publication in Physical
Review
Casting Control of Floating-films into Ribbon-shape Structure by modified Dynamic FTM
We have developed a new method to obtain Ribbon-shaped floating films via dynamic casting of floating-film and transfer method (dynamic-FTM). Dynamic-FTM is a unique method to prepare oriented thin-film of conjugated polymers (CPs) which is quick and easy. This method has several advantages as compared to the other conventional casting procedure to prepare oriented CP films. In the conventional dynamic FTM appearance of large scale circular orientation poses difficulty not only for practical applications but also hinders the detailed analysis of the orientation mechanism. In this present work, pros and cons of this newly proposed ribbon-shaped floating-film have been discussed in detail from those of the conventional floating-film prepared by dynamic-FTM.12th International Conference on Nanomolecular Electronics (ICNME-2016), December 14-16, 2016, Kobe International Conference Center, Kobe, Japa
- …