174 research outputs found
High-pressure study of substrate material ScAlMgO4
We report on the structural properties of ScAlMgO4 studied under
quasi-hydrostatic pressure using synchrotron high-pressure x-ray diffraction up
to 40 GPa. We also report on single-crystal studies of ScAlMgO4 performed at
300 K and 100 K. We found that the low-pressure phase remains stable up to 24
GPa. At 28 GPa, we detected a reversible phase transformation. The
high-pressure phase is assigned to a monoclinic distortion of the low-pressure
phase. No additional phase transition is observed up to 40 GPa. In addition,
the equation of state, compressibility tensor, and thermal expansion
coefficients of ScAlMgO4 are determined. The bulk modulus of ScAlMgO4 is found
to be 143(8) GPa, with a strong compressibility anisotropy. For the trigonal
low-pressure phase, the compressibility along the c-axis is twice than
perpendicular one. A perfect lattice match with ZnO is retained under pressure
in the pressure range of stability of wurtzite ZnO.Comment: 22 pages, 5 figures, 4 tables, 24 reference
Elastic constants of beta-eucryptite: A density functional theory study
The five independent elastic constants of hexagonal -eucryptite have
been determined using density functional theory (DFT) total energy
calculations. The calculated values agree well, to within 15%, with the
experimental data. Using the calculated elastic constants, the linear
compressibility of -eucryptite parallel to the c-axis, , and
perpendicular to it, , have been evaluated. These values are in close
agreement to those obtained from experimentally known elastic constants, but
are in contradiction to the direct measurements based on a three-terminal
technique. The calculated compressibility parallel to the c-axis was found to
positive as opposed to the negative value obtained by direct measurements. We
have demonstrated that must be positive and discussed the implications
of a positive in the context of explaining the negative bulk thermal
expansion of -eucryptite.Comment: 3 eps figures, submitted for publicatio
Ground state properties of heavy alkali halides
We extend previous work on alkali halides by calculations for the heavy-atom
species RbF, RbCl, LiBr, NaBr, KBr, RbBr, LiI, NaI, KI, and RbI. Relativistic
effects are included by means of energy-consistent pseudopotentials,
correlations are treated at the coupled-cluster level. A striking deficiency of
the Hartree-Fock approach are lattice constants deviating by up to 7.5 % from
experimental values which is reduced to a maximum error of 2.4 % by taking into
account electron correlation. Besides, we provide ab-initio data for in-crystal
polarizabilities and van der Waals coefficients.Comment: accepted by Phys. Rev.
High-pressure crystal structure, lattice vibrations, and band structure of BiSbO4
"This document is the Accepted Manuscript version of a Published Work that appeared in final form in
Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.inorgchem.6b00503”The high-pressure crystal structure, lattice-vibrations HP crystal structure, lattice vibrations, and band , and electronic band structure of BiSbO4 were studied by ab initio simulations. We also performed Raman spectroscopy, infrared spectroscopy, and diffuse-reflectance measurements, as well as synchrotron powder X-ray diffraction. High-pressure X-ray diffraction measurements show that the crystal structure of BiSbO4 remains stable up to at least 70 GPa, unlike other known MTO4-type ternary oxides. These experiments also give information on the pressure dependence of the unit-cell parameters. Calculations properly describe the crystal structure of BiSbO4 and the changes induced by pressure on it. They also predict a possible high-pressure phase. A room-temperature pressure volume equation of state is determined, and the effect of pressure on the coordination polyhedron of Bi and Sb is discussed. Raman- and infrared-active phonons were measured and calculated. In particular, calculations provide assignments for all the vibrational modes as well as their pressure dependence. In addition, the band structure and electronic density of states under pressure were also calculated. The calculations combined with the optical measurements allow us to conclude that BiSbO4 is an indirect-gap semiconductor, with an electronic band gap of 2.9(1) eV. Finally, the isothermal compressibility tensor for. BiSbO4 is given at 1.8 GPa. The experimental (theoretical) data revealed that the direction of maximum compressibility is in the (0 1 0) plane at similar to 33 degrees (38 degrees) to the c-axis and 47 degrees (42 degrees) to the a-axis. The reliability of the reported results is supported by the consistency between experiments and calculations.Research supported by the Spanish government MINECO under Grant Nos. MAT2013-46649-C4-1/2/3-P and MAT2015-71070-REDC. We also acknowledge the computer time provided by MALTA cluster and the Red Espanola de Supercomputacion. Experiments were performed at MSPD beamline at ALBA Synchrotron Light Facility with the collaboration of ALBA staff.Errandonea, D.; Muñoz, A.; Rodríguez-Hernández, P.; Gomis, O.; Achary, SN.; Popescu, C.; Patwe, SJ.... (2016). High-pressure crystal structure, lattice vibrations, and band structure of BiSbO4. Inorganic Chemistry. 55(10):4958-4969. doi:10.1021/acs.inorgchem.6b00503S49584969551
The constitutive tensor of linear elasticity: its decompositions, Cauchy relations, null Lagrangians, and wave propagation
In linear anisotropic elasticity, the elastic properties of a medium are
described by the fourth rank elasticity tensor C. The decomposition of C into a
partially symmetric tensor M and a partially antisymmetric tensors N is often
used in the literature. An alternative, less well-known decomposition, into the
completely symmetric part S of C plus the reminder A, turns out to be
irreducible under the 3-dimensional general linear group. We show that the
SA-decomposition is unique, irreducible, and preserves the symmetries of the
elasticity tensor. The MN-decomposition fails to have these desirable
properties and is such inferior from a physical point of view. Various
applications of the SA-decomposition are discussed: the Cauchy relations
(vanishing of A), the non-existence of elastic null Lagrangians, the
decomposition of the elastic energy and of the acoustic wave propagation. The
acoustic or Christoffel tensor is split in a Cauchy and a non-Cauchy part. The
Cauchy part governs the longitudinal wave propagation. We provide explicit
examples of the effectiveness of the SA-decomposition. A complete class of
anisotropic media is proposed that allows pure polarizations in arbitrary
directions, similarly as in an isotropic medium.Comment: 1 figur
Structural, Vibrational, and Electronic Study of α‑As2Te3 under Compression
This document is the Accepted Manuscript version of a Published Work that appeared in final form in
Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see http://dx.doi.org/10.1021/acs.jpcc.6b06049We report a study of the structural, vibrational, and electronic
properties of layered monoclinic arsenic telluride (α-As2Te3) at high
pressures. Powder X-ray diffraction and Raman scattering measurements up
to 17 GPa have been complemented with ab initio total-energy, lattice
dynamics, and electronic band structure calculations. Our measurements,
which include previously unreported Raman scattering measurements for
crystalline α-As2Te3, show that this compound undergoes a reversible phase
transition above 14 GPa at room temperature. The monoclinic crystalline
structure of α-As2Te3 and its behavior under compression are analyzed by
means of the compressibility tensor. Major structural and vibrational changes
are observed in the range between 2 and 4 GPa and can be ascribed to the
strengthening of interlayer bonds. No evidence of any isostructural phase
transition has been observed in α-As2Te3. A comparison with other group 15
sesquichalcogenides allows understanding the structure of α-As2Te3 and its
behavior under compression based on the activity of the cation lone electron pair in these compounds. Finally, our electronic
band structure calculations show that α-As2Te3 is a semiconductor at 1 atm, which undergoes a trivial semiconducting−metal
transition above 4 GPa. The absence of a pressure-induced electronic topological transition in α-As2Te3 is discussed.This work has been performed under financial support from Projects MAT2013-46649-C4-2-P, MAT2013-46649-C4-3-P, MAT2015-71070-REDC, FIS2013-48286-C2-1-P, and FIS2013-48286-C2-2-P of the Spanish Ministry of Economy and Competitiveness (MINECO), and the Department of Education, Universities and Research of the Basque Government and UPV/EHU (Grant No. IT756-13). This publication is also fruit of "Programa de Valoracion y Recursos Conjuntos de I+D+i VLC/CAMPUS" and has been financed by the Spanish Ministerio de Educacion, Cultura y Deporte as part of "Programa Campus de Excelencia Internacional" through Projects SP20140701 and SP20140871. Finally, authors thank ALBA Light Source for beam allocation at beamline MSPD.Cuenca Gotor, VP.; Sans-Tresserras, JÁ.; Ibáñez, J.; Popescu, C.; Gomis, O.; Vilaplana Cerda, RI.; Manjón Herrera, FJ.... (2016). Structural, Vibrational, and Electronic Study of α‑As2Te3 under Compression. Journal of Physical Chemistry C. 120(34):19340-19352. https://doi.org/10.1021/acs.jpcc.6b06049S19340193521203
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