XPS characterization of silver electrodes and catalyst for oxygen reduction

The combined analysis of the silver GDE using an ex-situ surface sensitive technique (XPS) and in-situ electrochemical measurements (EIS, CV) show that the performance of the silver GDE is significantly influenced by the degree of degradation of the electrodes, e. g., the reduction of the active surface due to the decomposition of the PTFE. These findings indicate a different degree of decomposition of the PTFE on the on the GDE

Optical exciton Aharonov-Bohm effect, persistent current, and magnetization in semiconductor nanorings of type I and II

The optical exciton Aharonov-Bohm effect, i. e. an oscillatory component in the energy of optically active (bright) states, is investigated in nanorings. It is shown that a small effective electron mass, strong confinement of the electron, and high barrier for the hole, achieved e. g. by an InAs nanoring embedded in an AlGaSb quantum well, are favorable for observing the optical exciton Aharonov-Bohm effect. The second derivative of the exciton energy with respect to the magnetic field is utilized to extract Aharonov-Bohm oscillations even for the lowest bright state unambiguously. A connection between the theories for infinitesimal narrow and finite width rings is established. Furthermore, the magnetization is compared to the persistent current, which oscillates periodically with the magnetic field and confirms thus the non-trivial (connected) topology of the wave function in the nanoring.Comment: 12 pages, 11 figure

Thermoelectric phenomena in a quantum dot asymmetrically coupled to external leads

We study thermoelectric phenomena in a system consisting of strongly correlated quantum dot coupled to external leads in the Kondo regime. We calculate linear and nonlinear electrical and thermal conductance and thermopower of the quantum dot and discuss the role of asymmetry in the couplings to external electrodes. In the linear regime electrical and thermal conductances are modified, while thermopower remains unchanged. In the nonlinear regime the Kondo resonance in differential conductance develops at non-zero source-drain voltage, which has important consequences on thermoelectric properties of the system and the thermopower starts to depend on the asymmetry. We also discuss Wiedemann-Franz relation, thermoelectric figure of merit and validity of the Mott formula for thermopower.Comment: 6 pages, 7 figure

Do Evaporating Black Holes Form Photospheres?

Several authors, most notably Heckler, have claimed that the observable Hawking emission from a microscopic black hole is significantly modified by the formation of a photosphere around the black hole due to QED or QCD interactions between the emitted particles. In this paper we analyze these claims and identify a number of physical and geometrical effects which invalidate these scenarios. We point out two key problems. First, the interacting particles must be causally connected to interact, and this condition is satisfied by only a small fraction of the emitted particles close to the black hole. Second, a scattered particle requires a distance ~ E/m_e^2 for completing each bremsstrahlung interaction, with the consequence that it is improbable for there to be more than one complete bremsstrahlung interaction per particle near the black hole. These two effects have not been included in previous analyses. We conclude that the emitted particles do not interact sufficiently to form a QED photosphere. Similar arguments apply in the QCD case and prevent a QCD photosphere (chromosphere) from developing when the black hole temperature is much greater than Lambda_QCD, the threshold for QCD particle emission. Additional QCD phenomenological arguments rule out the development of a chromosphere around black hole temperatures of order Lambda_QCD. In all cases, the observational signatures of a cosmic or Galactic halo background of primordial black holes or an individual black hole remain essentially those of the standard Hawking model, with little change to the detection probability. We also consider the possibility, as proposed by Belyanin et al. and D. Cline et al., that plasma interactions between the emitted particles form a photosphere, and we conclude that this scenario too is not supported.Comment: version published in Phys Rev D 78, 064043; 25 pages, 3 figures; includes discussion on extending our analysis to TeV-scale, higher-dimensional black hole

Steps on current-voltage characteristics of a silicon quantum dot covered by natural oxide

Considering a double-barrier structure formed by a silicon quantum dot covered by natural oxide with two metallic terminals, we derive simple conditions for a step-like voltage-current curve. Due to standard chemical properties, doping phosphorus atoms located in a certain domain of the dot form geometrically parallel current channels. The height of the current step typically equals to (1.2 pA)N, where N=0,1,2,3... is the number of doping atoms inside the domain, and only negligibly depends on the actual position of the dopants. The found conditions are feasible in experimentally available structures.Comment: 4 pages, 3 figure

Effect of gas flow on electronic transport in a DNA-decorated carbon nanotube

We calculate the two-time current correlation function using the experimental data of the current-time characteristics of the Gas-DNA-decorated carbon nanotube field effect transistor. The pattern of the correlation function is a measure of the sensitivity and selectivity of the sensors and suggest that these gas flow sensors may also be used as DNA sequence detectors. The system is modelled by a one-dimensional tight-binding Hamiltonian and we present analytical calculations of quantum electronic transport for the system using the time-dependent nonequilibrium Green's function formalism and the adiabatic expansion. The zeroth and first order contributions to the current $I^{(0)}(\bar{t})$ and $I^{(1)}(\bar{t})$ are calculated, where $I^{(0)} (\bar{t})$ is the Landauer formula. The formula for the time-dependent current is then used to compare the theoretical results with the experiment.Comment: 14 pages, 5 figures and 2 table

Bremsstrahlung and pair production processes at low energies, multi-differential cross section and polarization phenomena

Radiative electron-proton scattering is studied in peripheral kinematics, where the scattered electron and photon move close to the direction of the initial electron. Even in the case of unpolarized initial electron the photon may have a definite polarization. The differential cross sections with longitudinally or transversal polarized initial electron are calculated. The same phenomena are considered for the production of an electron-positron pair by the photon, where the final positron (electron) can be also polarized. Differential distributions for the case of polarized initial photon are given. Both cases of unscreened and completely screened atomic targets are considered.Comment: 15 pages, 6 figure

Efficient graphene-based photodetector with two cavities

We present an efficient graphene-based photodetector with two Fabri-P\'erot cavities. It is shown that the absorption can reach almost 100% around a given frequency, which is determined by the two-cavity lengths. It is also shown that hysteresis in the absorbance is possible, with the transmittance amplitude of the mirrors working as an external driving field. The role of non-linear contributions to the optical susceptibility of graphene is discussed.Comment: 10 pages, 8 figures. published version: minor revisio

Spin-polarized tunneling currents through a ferromagnetic insulator between two metallic or superconducting leads

Using the Keldysh formalism the tunneling current through a hybrid structure where a confined magnetic insulator (I) is sandwiched between two non-magnetic leads is calculated. The leads can be either normal metals (M) or superconductors (S). Each region is modelled as a single band in tight-binding approximation in order to understand the formation of the tunneling current as clearly as possible. The tunneling process itself is simulated by a hybridization between the lead and insulator conduction bands. The insulator is assumed to have localized moments which can interact with the tunneling electrons. This is described by the Kondo Lattice Model (KLM) and treated within an interpolating self-energy approach. For the superconductor the mean-field BCS theory is used. The spin polarization of the current shows a strong dependence both on the applied voltage and the properties of the materials. Even for this idealized three band model there is a qualitative agreement with experiment.Comment: 15 pages, 23 figures, accepted for publication in PR

Theory of the optical absorption of light carrying orbital angular momentum by semiconductors

We develop a free-carrier theory of the optical absorption of light carrying orbital angular momentum (twisted light) by bulk semiconductors. We obtain the optical transition matrix elements for Bessel-mode twisted light and use them to calculate the wave function of photo-excited electrons to first-order in the vector potential of the laser. The associated net electric currents of first and second-order on the field are obtained. It is shown that the magnetic field produced at the center of the beam for the $\ell=1$ mode is of the order of a millitesla, and could therefore be detected experimentally using, for example, the technique of time-resolved Faraday rotation.Comment: Submitted to Phys. Rev. Lett. (23 Jan 2008