Combining modern assessment methods to improve understanding of longwall geomechanics

Ongoing, collaborative research between CSIRO\u27s Exploration and Mining and Strata Control Technology has resulted in a better understanding of rock failure mechanisms around longwall extraction. Failure has occurred further ahead of the retreating face than predicted by conventional longwall geomechanics theory. In some cases significant failure has been detected several hundred metres ahead of the face position with demonstrated influences of minor geological discontinuities. Shear, rather than tensile failure has been the predominant failure mechanism in the environments monitored. Validating technologies of microseismic monitoring and new face monitoring techniques have assisted the development of predictive 2D computational modelling tools. The demonstrated 3D consequences of failure has assisted in the ongoing direction of the project to further investigate these effects

O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission

Oxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon?photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core?valence double excitations, while shape resonances are suppressed. In contrast, the partial fluorescence yield in the wavelength window 300?650 nm and the excitation functions of selected O+ and C+ emission lines in the wavelength range 400?500 nm display all of the absorption features. The relative intensity of ionic emission in the visible range increases towards higher photon energies, which is attributed to O 1s shake-off photoionization. VUV photon?photoion coincidence spectra reveal major contributions from the C+ and O+ ions and a minor contribution from C2+. No conclusive changes in the intensity ratios among the different ions are observed above the O 1s threshold. The line shape of the VUV?O+ coincidence peak in the mass spectrum carries some information on the initial core excitatio