Biologically active Phytophthora mating hormone prepared by catalytic asymmetric total synthesis

A Phytophthora mating hormone with an array of 1,5-stereogenic centers has been synthesized by using our recently developed methodology of catalytic enantioselective conjugate addition of Grignard reagents. We applied this methodology in a diastereo- and enantioselective iterative route and obtained two of the 16 possible stereoisomers of Phytophthora hormone α1. These synthetic stereoisomers induced the formation of sexual spores (oospores) in A2 mating type strains of three heterothallic Phytophthora species, P. infestans, P. capsici, and P. nicotianae but not in A1 mating type strains. The response was concentration-dependent, and the oospores were viable. These results demonstrate that the biological activity of the synthetic hormone resembles that of the natural hormone α1. Mating hormones are essential components in the sexual life cycle of a variety of organisms. For plant pathogens like Phytophthora, sexual reproduction is important as a source of genetic variation. Moreover, the thick-walled oospores are the most durable propagules that can survive harsh environmental conditions. Sexual reproduction can thus greatly affect disease epidemics. The availability of synthetic compounds mimicking the activity of Phytophthora mating hormone will be instrumental for further unravelling sexual reproduction in this important group of plant pathogens.

Observation of Resonant Diffusive Radiation in Random Multilayered Systems

Diffusive Radiation is a new type of radiation predicted to occur in randomly inhomogeneous media due to the multiple scattering of pseudophotons. This theoretical effect is now observed experimentally. The radiation is generated by the passage of electrons of energy 200KeV-2.2MeV through a random stack of films in the visible light region. The radiation intensity increases resonantly provided the Cherenkov condition is satisfied for the average dielectric constant of the medium. The observed angular dependence and electron resonance energy are in agreement with the theoretical predictions. These observations open a road to application of diffusive radiation in particle detection, astrophysics, soft X-ray generation and etc.. `Comment: 4pages, 4figure

Interacting supernovae and supernova impostors. SN 2007sv: the major eruption of a massive star in UGC 5979

We report the results of the photometric and spectroscopic monitoring campaign of the transient SN 2007sv. The observables are similar to those of type IIn supernovae, a well-known class of objects whose ejecta interact with pre-existing circum-stellar material. The spectra show a blue continuum at early phases and prominent Balmer lines in emission, however, the absolute magnitude at the discovery of SN 2007sv (M_R = - 14.25 +/- 0.38) indicate it to be most likely a supernova impostor. This classification is also supported by the lack of evidence in the spectra of very high velocity material as expected in supernova ejecta. In addition we find no unequivocal evidence of broad lines of alpha - and/or Fe-peak elements. The comparison with the absolute light curves of other interacting objects (including type IIn supernovae) highlights the overall similarity with the prototypical impostor SN 1997bs. This supports our claim that SN 2007sv was not a genuine supernova, and was instead a supernova impostor, most likely similar to the major eruption of a luminous blue variable.Comment: Accepted for publication in MNRAS. 15 pages, 11 figures, 5 table

The GAPS Programme with HARPS-N at TNG. III: The retrograde orbit of HAT-P-18b

The measurement of the Rossiter-McLaughlin effect for transiting exoplanets places constraints on the orientation of the orbital axis with respect to the stellar spin axis, which can shed light on the mechanisms shaping the orbital configuration of planetary systems. Here we present the interesting case of the Saturn-mass planet HAT-P-18b, which orbits one of the coolest stars for which the Rossiter-McLaughlin effect has been measured so far. We acquired a spectroscopic time-series, spanning a full transit, with the HARPS-N spectrograph mounted at the TNG telescope. The very precise radial velocity measurements delivered by the HARPS-N pipeline were used to measure the Rossiter-McLaughlin effect. Complementary new photometric observations of another full transit were also analysed to obtain an independent determination of the star and planet parameters. We find that HAT-P-18b lies on a counter-rotating orbit, the sky-projected angle between the stellar spin axis and the planet orbital axis being lambda=132 +/- 15 deg. By joint modelling of the radial velocity and photometric data we obtain new determinations of the star (M_star = 0.770 +/- 0.027 M_Sun; R_star= 0.717 +/- 0.026 R_Sun; Vsin(I_star) = 1.58 +/- 0.18 km/s) and planet (M_pl = 0.196 +/- 0.008 M_J; R_pl = 0.947 +/- 0.044 R_J) parameters. Our spectra provide for the host star an effective temperature T_eff = 4870 +/- 50 K, a surface gravity of log(g_star) = 4.57 +/- 0.07 cm/s, and an iron abundance of [Fe/H] = 0.10 +/- 0.06. HAT-P-18b is one of the few planets known to transit a star with T_eff < 6250 K on a retrograde orbit. Objects such as HAT-P-18b (low planet mass and/or relatively long orbital period) most likely have a weak tidal coupling with their parent stars, therefore their orbits preserve any original misalignment. As such, they are ideal targets to study the causes of orbital evolution in cool main-sequence stars.Comment: 5 pages, 2 figure

Supernova rates from the SUDARE VST-Omegacam search II. Rates in a galaxy sample

This is the second paper of a series in which we present measurements of the Supernova (SN) rates from the SUDARE survey. In this paper, we study the trend of the SN rates with the intrinsic colours, the star formation activity and the mass of the parent galaxies. We have considered a sample of about 130000 galaxies and a SN sample of about 50 events. We found that the SN Ia rate per unit mass is higher by a factor of six in the star-forming galaxies with respect to the passive galaxies. The SN Ia rate per unit mass is also higher in the less massive galaxies that are also younger. These results suggest a distribution of the delay times (DTD) less populated at long delay times than at short delays. The CC SN rate per unit mass is proportional to both the sSFR and the galaxy mass. The trends of the Type Ia and CC SN rates as a function of the sSFR and the galaxy mass that we observed from SUDARE data are in agreement with literature results at different redshifts. The expected number of SNe Ia is in agreement with the observed one for all four DTD models considered both in passive and star-forming galaxies so we can not discriminate between different progenitor scenarios. The expected number of CC SNe is higher than the observed one, suggesting a higher limit for the minimum progenitor mass. We also compare the expected and observed trends of the SN Ia rate with the intrinsic U - J colour of the parent galaxy, assumed as a tracer of the age distribution. While the slope of the relation between the SN Ia rate and the U - J color in star-forming galaxies can be reproduced well by all four DTD models considered, only the steepest of them is able to account for the rates and colour in star-forming and passive galaxies with the same value of the SN Ia production efficiency.Comment: A& A accepte

Optical and near-infrared observations of SN 2011dh - The first 100 days

We present optical and near-infrared (NIR) photometry and spectroscopy of the Type IIb supernova (SN) 2011dh for the first 100 days. We complement our extensive dataset with SWIFT ultra-violet (UV) and Spitzer mid-infrared (MIR) data to build a UV to MIR bolometric lightcurve using both photometric and spectroscopic data. Hydrodynamical modelling of the SN based on this bolometric lightcurve have been presented in Bersten (2012). We find that the absorption minimum for the hydrogen lines is never seen below ~11000 km/s but approaches this value as the lines get weaker. This suggests that the interface between the helium core and hydrogen rich envelope is located near this velocity in agreement with the Bersten et al. (2012) He4R270 ejecta model. Spectral modelling of the hydrogen lines using this ejecta model supports the conclusion and we find a hydrogen mass of 0.01-0.04 solar masses to be consistent with the observed spectral evolution. We estimate that the photosphere reaches the helium core at 5-7 days whereas the helium lines appear between ~10 and ~15 days, close to the photosphere and then move outward in velocity until ~40 days. This suggests that increasing non-thermal excitation due to decreasing optical depth for the gamma-rays is driving the early evolution of these lines. We also provide and discuss pre- and post-explosion observations of the SN site which shows a reduction by 75 percent in flux at the position of the yellow supergiant coincident with SN 2011dh. The B, V and r band decline rates of 0.0073, 0.0090 and 0.0053 mag/day respectively are consistent with the remaining flux being emitted by the SN. Hence we find that the star was indeed the progenitor of SN 2011dh as previously suggested by Maund et al. (2011) and which is also consistent with the results from the hydrodynamical modelling.Comment: 38 pages, 27 figures, 18 tables, accepted for publication by A&

Theoretical study of the thermal behavior of free and alumina-supported Fe-C nanoparticles

The thermal behavior of free and alumina-supported iron-carbon nanoparticles is investigated via molecular dynamics simulations, in which the effect of the substrate is treated with a simple Morse potential fitted to ab initio data. We observe that the presence of the substrate raises the melting temperature of medium and large $Fe_{1-x}C_x$ nanoparticles ($x$ = 0-0.16, $N$ = 80-1000, non- magic numbers) by 40-60 K; it also plays an important role in defining the ground state of smaller Fe nanoparticles ($N$ = 50-80). The main focus of our study is the investigation of Fe-C phase diagrams as a function of the nanoparticle size. We find that as the cluster size decreases in the 1.1-1.6-nm-diameter range the eutectic point shifts significantly not only toward lower temperatures, as expected from the Gibbs-Thomson law, but also toward lower concentrations of C. The strong dependence of the maximum C solubility on the Fe-C cluster size may have important implications for the catalytic growth of carbon nanotubes by chemical vapor deposition.Comment: 13 pages, 11 figures, higher quality figures can be seen in article 9 at http://alpha.mems.duke.edu/wahyu

Neutral Iron Emission Lines From The Day-side Of KELT-9b -- The GAPS Programme With HARPS-N At TNG XX

We present the first detection of atomic emission lines from the atmosphere of an exoplanet. We detect neutral iron lines from the day-side of KELT-9b (Teq $\sim$ 4, 000 K). We combined thousands of spectrally resolved lines observed during one night with the HARPS-N spectrograph (R $\sim$ 115, 000), mounted at the Telescopio Nazionale Galileo. We introduce a novel statistical approach to extract the planetary parameters from the binary mask cross-correlation analysis. We also adapt the concept of contribution function to the context of high spectral resolution observations, to identify the location in the planetary atmosphere where the detected emission originates. The average planetary line profile intersected by a stellar G2 binary mask was found in emission with a contrast of 84 $\pm$ 14 ppm relative to the planetary plus stellar continuum (40 $\pm$ 5$\%$ relative to the planetary continuum only). This result unambiguously indicates the presence of an atmospheric thermal inversion. Finally, assuming a modelled temperature profile previously published (Lothringer et al. 2018), we show that an iron abundance consistent with a few times the stellar value explains the data well. In this scenario, the iron emission originates at the $10^{-3}$-$10^{-5}$ bar level.Comment: Accepted for publication on ApJL; 19 pages, 4 figures, 3 table

The GAPS Programme with HARPS-N at TNG XV. A substellar companion around a K giant star identified with quasi-simultaneous HARPS-N and GIANO measurements

Context. Identification of planetary companions of giant stars is made difficult because of the astrophysical noise, that may produce radial velocity (RV) variations similar to those induced by a companion. On the other hand any stellar signal is wavelength dependent, while signals due to a companion are achromatic. Aims. Our goal is to determine the origin of the Doppler periodic variations observed in the thick disk K giant star TYC 4282-605-1 by HARPS-N at the Telescopio Nazionale Galileo (TNG) and verify if they can be due to the presence of a substellar companion. Methods. Several methods have been used to exclude the stellar origin of the observed signal including detailed analysis of activity indicators and bisector and the analysis of the photometric light curve. Finally we have conducted an observational campaign to monitor the near infrared (NIR) RV with GIANO at the TNG in order to verify whether the NIR amplitude variations are comparable with those observed in the visible. Results. Both optical and NIR RVs show consistent variations with a period at 101 days and similar amplitude, pointing to the presence of a companion orbiting the target. The main orbital properties obtained for our giant star with a derived mass of M=0.97+-0.03M_sun are M_Psini=10.78+-0.12MJ;P=101.54+-0.05days;e=0.28+-0.01 and a=0.422+-0.009AU. The chemical analysis shows a significant enrichment in the abundance of Nai, Mgi, Ali and S i while the rest of analyzed elements are consistent with the solar value demonstrating that the chemical composition corresponds with an old K giant (age = 10.1 Gyr) belonging to local thick disk. Conclusions. We conclude that the substellar companion hypothesis for this K giant is the best explanation for the observed periodic RV variation. This study also shows the high potential of multi-wavelength RV observations for the validation of planet candidates.Comment: Accepted in Journal reference A&A 14/06/201