Dark cloud chemistry in initially H-rich regions

The chemistry in dark regions of dense cores is explored as a function of the initial abundance ratio of H to H 2, on the assumption that some cores form on a timescale and are younger than the time required for the H :H 2 ratio to attain its equilibrium value. Observational diagnostics of non-equilibrium values of the initial H :H 2 ratio are identified. In initially H-rich material, the abundances of OH, NH 3, CN, and HNC are for some time higher than they are in initially H-poor material. In initially H-poor regions, the abundances of CO, species containing multiple carbon atoms in each molecule, and CS are larger for an (observationally significant) period than in initially H-rich material

The modifcation by diffuse radiation of "cometary tail" formation behind globules

We study the evolution of a globule of neutral material immersed in the more tenuous hotter plasma of an H II region surrounding newly born OB stars. The neutral globule is illuminated by the direct ionizing radiation of OB stars, and by diffuse radiation emitted by recombination in the surrounding ionized gas. We perform 2D, time dependent axisymmetric hydrodynamic simulations, and find that, for values of the diffuse field of the order of 10% of the direct field, the evolution of the globule is completely different to its evolution when the diffuse field is neglected

Chemical telemetry of OH observed to measure interstellar magnetic fields

We present models for the chemistry in gas moving towards the ionization front of an HII region. When it is far from the ionization front, the gas is highly depleted of elements more massive than helium. However, as it approaches the ionization front, ices are destroyed and species formed on the grain surfaces are injected into the gas phase. Photodissociation removes gas phase molecular species as the gas flows towards the ionization front. We identify models for which the OH column densities are comparable to those measured in observations undertaken to study the magnetic fields in star forming regions and give results for the column densities of other species that should be abundant if the observed OH arises through a combination of the liberation of H2O from surfaces and photodissociation. They include CH3OH, H2CO, and H2S. Observations of these other species may help establish the nature of the OH spatial distribution in the clouds, which is important for the interpretation of the magnetic field results.Comment: 11 pages, 2 figures, accepted by Astrophysics and Space Scienc

Supernova Hosts for Gamma-Ray Burst Jets: Dynamical Constraints

I constrain a possible supernova origin for gamma-ray bursts by modeling the dynamical interaction between a relativistic jet and a stellar envelope surrounding it. The delay in observer's time introduced by the jet traversing the envelope should not be long compared to the duration of gamma-ray emission; also, the jet should not be swallowed by a spherical explosion it powers. The only stellar progenitors that comfortably satisfy these constraints, if one assumes that jets move ballistically within their host stars, are compact carbon-oxygen or helium post-Wolf-Rayet stars (type Ic or Ib supernovae); type II supernovae are ruled out. Notably, very massive stars do not appear capable of producing the observed bursts at any redshift unless the stellar envelope is stripped prior to collapse. The presence of a dense stellar wind places an upper limit on the Lorentz factor of the jet in the internal shock model; however, this constraint may be evaded if the wind is swept forward by a photon precursor. Shock breakout and cocoon blowout are considered individually; neither presents a likely source of precursors for cosmological GRBs. These envelope constraints could conceivably be circumvented if jets are laterally pressure-confined while traversing the outer stellar envelope. If so, jets responsible for observed GRBs must either have been launched from a region several hundred kilometers wide, or have mixed with envelope material as they travel. A phase of pressure confinement and mixing would imprint correlations among jets that may explain observed GRB variability-luminosity and lag-luminosity correlations.Comment: 17 pages, MNRAS, accepted. Contains new analysis of pressure-confined jets, of jets that experience oblique shocks or mix with their cocoons, and of cocoons after breakou

Grain Surface Models and Data for Astrochemistry

AbstractThe cross-disciplinary field of astrochemistry exists to understand the formation, destruction, and survival of molecules in astrophysical environments. Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. A broad consensus has been reached in the astrochemistry community on how to suitably treat gas-phase processes in models, and also on how to present the necessary reaction data in databases; however, no such consensus has yet been reached for grain-surface processes. A team of ∼25 experts covering observational, laboratory and theoretical (astro)chemistry met in summer of 2014 at the Lorentz Center in Leiden with the aim to provide solutions for this problem and to review the current state-of-the-art of grain surface models, both in terms of technical implementation into models as well as the most up-to-date information available from experiments and chemical computations. This review builds on the results of this workshop and gives an outlook for future directions

Wind-Blown Bubbles around Evolved Stars

Most stars will experience episodes of substantial mass loss at some point in their lives. For very massive stars, mass loss dominates their evolution, although the mass loss rates are not known exactly, particularly once the star has left the main sequence. Direct observations of the stellar winds of massive stars can give information on the current mass-loss rates, while studies of the ring nebulae and HI shells that surround many Wolf-Rayet (WR) and luminous blue variable (LBV) stars provide information on the previous mass-loss history. The evolution of the most massive stars, (M > 25 solar masses), essentially follows the sequence O star to LBV or red supergiant (RSG) to WR star to supernova. For stars of mass less than 25 solar masses there is no final WR stage. During the main sequence and WR stages, the mass loss takes the form of highly supersonic stellar winds, which blow bubbles in the interstellar and circumstellar medium. In this way, the mechanical luminosity of the stellar wind is converted into kinetic energy of the swept-up ambient material, which is important for the dynamics of the interstellar medium. In this review article, analytic and numerical models are used to describe the hydrodynamics and energetics of wind-blown bubbles. A brief review of observations of bubbles is given, and the degree to which theory is supported by observations is discussed.Comment: To be published as a chapter in 'Diffuse Matter from Star Forming Regions to Active Galaxies' - A volume Honouring John Dyson. Eds. T. W. Harquist, J. M. Pittard and S. A. E. G. Falle. 22 pages, 12 figure

Alexander Dalgarno. 5 January 1928-9 April 2015

History of Scienc