The Production of Ti44 and Co60 in Supernova

The production of the radioactive isotopes $^{44}$Ti and $^{60}$Co in all types of supernovae is examined and compared to observational constraints including Galactic $\gamma$--ray surveys, measurements of the diffuse 511 keV radiation, $\gamma$--ray observations of Cas A, the late time light curve of SN 1987A, and isotopic anomalies found in silicon carbide grains in meteorites. The (revised) line flux from $^{44}$Ti decay in the Cas A supernova remnant reported by COMPTEL on the Compton Gamma-Ray Observatory is near the upper bound expected from our models. The necessary concurrent ejection of $^{56}$Ni would also imply that Cas A was a brighter supernova than previously thought unless extinction in the intervening matter was very large. Thus, if confirmed, the reported amount of $^{44}$Ti in Cas A provides very interesting constraints on both the supernova environment and its mechanism. The abundances of $^{44}$Ti and $^{60}$Co ejected by Type II supernovae are such that gamma-radiation from $^{44}$Ti decay SN 1987A could be detected by a future generation of gamma-ray telescopes and that the decay of $^{60}$Co might provide an interesting contribution to the late time light curve of SN 1987A and other Type II supernovae. To produce the solar $^{44}$Ca abundance and satisfy all the observational constraints, nature may prefer at least the occasional explosion of sub-Chandrasekhar mass white dwarfs as Type Ia supernovae. Depending on the escape fraction of positrons due to $^{56}$Co made in all kinds of Type Ia supernovae, a significant fraction of the steady state diffuse 511 keV emission may arise from the annihilation of positrons produced during the decay of $^{44}$Ti to $^{44}$Ca. The Ca and Ti isotopic anomalies in pre-solar grains confirm the production of $^{44}$Ti in supernovae and thatComment: 27 pages including 7 figures. uuencoded, compressed, postscript. in press Ap

Mott--Hubbard transition vs. Anderson localization of correlated, disordered electrons

The phase diagram of correlated, disordered electrons is calculated within dynamical mean--field theory using the geometrically averaged (''typical'') local density of states. Correlated metal, Mott insulator and Anderson insulator phases, as well as coexistence and crossover regimes are identified. The Mott and Anderson insulators are found to be continuously connected.Comment: 4 pages, 4 figure

Constraints from 26Al Measurements on the Galaxy\u27s Recent Global Star Formation Rate and Core-Collapse Supernovae Rate

Gamma rays from the decay of 26Al o†er a stringent constraint on the GalaxyÏs global star formation rate over the past million years, supplementing other methods for quantifying the recent Galactic star formation rate, such as equivalent widths of Ha emission. Advantages and disadvantages of using 26Al gamma-ray measurements as a tracer of the massive star formation rate are analyzed. Estimates of the Galactic 26Al mass derived from COMPTEL measurements are coupled with a simple, analytical model of the 26Al injection rate from massive stars and restrict the GalaxyÏs recent star formation rate to 5^4 yr~1. In addition, we show that the derived 26Al mass implies a present-day Type II]Ib super-M_novae rate of 3.4^2.8 per century, which seems consistent with other independent estimates of the Galactic core-collapse supernova rate. If some independent measure of the massive star initial mass func-tion or star formation rate or Type II]Ib supernovae rate were to become available (perhaps through estimates of the Galactic 60Fe mass), then a convenient way to restrain, or possibly determine, the other parameters is presented

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

Spectral densities and partition functions of modular quantum systems as derived from a central limit theorem

Using a central limit theorem for arrays of interacting quantum systems, we give analytical expressions for the density of states and the partition function at finite temperature of such a system, which are valid in the limit of infinite number of subsystems. Even for only small numbers of subsystems we find good accordance with some known, exact results.Comment: 6 pages, 4 figures, some steps added to derivation, accepted for publication in J. Stat. Phy

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

The Production of 44Ti and 60Co in Supernovae

The production of the radioactive isotopes 44Ti and 60Co in all types of supernovae is examined and compared to observational constraints inculding Galactic gamma-ray surveys, measurements of the diffuse 511 keV radiation, gamma-ray observations of Cas A, the late-time light curve of SN 1987A, and isotopic anomalies found in silicon carbide grains in meteorities. The (revished) line flux from 44Ti decay in the Cas A supernova remnant reported by COMPTEL on the Compton Gamma Ray Observatory is near the upper bound expected from our models. The necessary concurrent ejection of 56Ni would also imply that Cas A was a brighter supernova than previously thought unless extinction in the intervening matter was very large. Thus, if confirmed, the reported amount of 44Ti in Cas A provides very interesting constraints on both the supernova environment and its mechanism. The abundances of 44Ti and 60Co ejected by Type II supernovae arch such that gmma-radiation from 44Ti decay SN 1987A could be dectected by a furture generation of gamma-ray telescopes, and that the decay of 60Co might provide an interesting contribution to the late-time light curve of SN 1987A and other core collapse supernovae. To produced the solar 44Ca abundance and satisfy all the obersvational constraints, nature may prfer at least the occasional explosion of sub-Chandrasekhar mass white dwarfs as Type Ia supernovae. Depending on the escape fraction of positrons due to 56Co made in all kinds of Type Ia supernovae, a significant fraction of the steady state diffuse 511 keV emission may arise from the annihilation of positrons produced during the decay of 44Ti to 44Ca. The Ca and Ti isotpic anomalies in presolar grains confirm the production of 44Ti in supernovae and that extensive mixing between zones has occurred, but a quantitative model for this mixing is presently lacking

Titanium as a substrate for three-dimensional hybrid electrodes for vanadium redox flow battery applications

Titanium, either in the form of a Ti foil or in form of a Ti mesh, was used as a novel substrate to grow nitrogen-doped carbon nanotubes (NCNTs) through chemical vapor deposition at moderate temperatures over electrodeposited iron particles. The thus-prepared high-surface-area electrodes were characterized by scanning electron microscopy (SEM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The electrochemical performance towards the V(IV)/V(V) redox couple was investigated by cyclic voltammetry. The parameters for iron particle electrodeposition were adjusted towards high and uniform substrate coverage. Nanotube growth from acetonitrile at moderate temperatures (600 °C) led to N-containing CNTs with a high amount of graphitic nitrogen. NCNTs grown over Ti substrates provide promising performances towards the V(IV)/V(V) as well as the V(III)/V(IV) redox pair. In general, the results of this study show that Ti might be a suitable electrocatalyst substrate for various applications in electrochemical energy conversion

A Novel Method for Real-Time, Continuous, Fluorescence-Based Analysis of Anti-DNA Abzyme Activity in Systemic Lupus

Systemic Lupus Erythematosus (SLE) is an autoimmune disease characterized by the production of antibodies against a variety of self-antigens including nucleic acids. These antibodies are cytotoxic, catalytic (hydrolyzing DNA, RNA, and protein), and nephritogenic. Current methods for investigating catalytic activities of natural abzymes produced by individuals suffering from autoimmunity are mostly discontinuous and often employ hazardous reagents. Here we demonstrate the utility of dual-labeled, fluorogenic DNA hydrolysis probes in highly specific, sensitive, continuous, fluorescence-based measurement of DNA hydrolytic activity of anti-ssDNA abzymes purified from the serum of patients suffering from SLE. An assay for the presence and levels of antibodies exhibiting hydrolytic activity could facilitate disease diagnosis, prediction of flares, monitoring of disease state, and response to therapy. The assay may allow indirect identification of additional targets of anti-DNA antibodies and the discovery of molecules that inhibit their activity. Combined, these approaches may provide new insights into molecular mechanisms of lupus pathogenesis