Dynamics and efficient conversion of excitons to trions in non-uniformly strained monolayer WS2

In recent years, there has been ongoing effort in achieving efficient transport of excitons in monolayer transition metal dichalcogenides subjected to highly non-uniform strain. Here we investigate the transport of excitons and trions in monolayer semiconductor WS2 subjected to controlled non-uniform mechanical strain. An atomic force microscope (AFM)-based setup is applied to actively control and tune the strain profiles by indenting the monolayer with an AFM tip. Optical spectroscopy is used to reveal the dynamics of the excited carriers. The non-uniform strain configuration locally changes the valence and conduction bands of WS2, giving rise to effective forces attracting excitons and trions towards the point of maximum strain underneath the AFM tip. We observe large changes in the photoluminescence spectra of WS2 under strain, which we interpret using a drift–diffusion model. We show that the transport of neutral excitons, a process that was previously thought to be efficient in non-uniformly strained two-dimensional semiconductors and termed as funnelling, is negligible at room temperature, in contrast to previous observations. Conversely, we discover that redistribution of free carriers under non-uniform strain profiles leads to highly efficient conversion of excitons to trions. Conversion efficiency reaches up to about 100% even without electrical gating. Our results explain inconsistencies in previous experiments and pave the way towards new types of optoelectronic devices

Neutral and charged excitons interplay in non-uniformly strain-engineered WS2

We investigate the response of excitons in two-dimensional semiconductors to nonuniformity of mechanical strain. In our approach to non-uniform strain-engineering, a WS2 monolayer is suspended over a triangular hole. Large (>2%), strongly non-uniform (>0.28% µm–1), and in-situ tunable strain is induced in WS2 by pressurizing it with inert gas. We observe a pronounced shift of the spectral weight from neutral to charged excitons at the center of the membrane, in addition to well-known strain-dependent bandgap modification. We show that the former phenomenon is a signature of a new effect unique for non-uniform strain: funneling of free carriers towards the region of high strain followed by neutral to charged exciton conversion. Our result establishes non-uniform strain engineering as a novel and useful experimental 'knob' for tuning optoelectronic properties of 2D semiconductors

Studying the extremes: hydrometeorological investigation of a flood-causing rainstorm over Israel

International audienceAnalysis of extreme hydrometeorological events is important for characterizing and better understanding the meteorological conditions that can generate severe rainstorms and the consequent catastrophic flooding. According to several studies (e.g., Alpert et al., 2004; Wittenberg et al., 2007), the occurrence of such extreme events is increasing over the eastern Mediterranean although total rain amounts are generally decreasing. The current study presents an analysis of an extreme event utilizing different methodologies: (a) synoptic maps and high resolution satellite imagery for atmospheric condition analysis; (b) rainfall analysis by rain gauges data; (c) meteorological radar rainfall calibration and analysis; (d) field measurements for estimating maximum peak discharges; and, (e) high resolution aerial photographs together with field surveying for quantifying the geomorphic impacts. The unusual storm occurred over Israel between 30 March and 2 April, 2006. Heavy rainfall produced more than 100 mm in some locations in only few hours and more than 200 mm in the major core area. Extreme rain intensities with recurrence intervals of more than 100 years were found for durations of 1 h and more as well as for the daily rain depth values. In the most severely affected area, Wadi Ara, extreme flash floods caused damages and casualties. Specific peak discharges were as high as 10?30 m³/s/km² for catchments of the size of 1?10 km², values larger than any recorded floods in similar climatic regions in Israel

Neutral and charged excitons interplay in non uniformly strain engineered WS2

We investigate the response of excitons in two dimensional semiconductors to nonuniformity of mechanical strain. In our approach to non uniform strain engineering, a WS2 monolayer is suspended over a triangular hole. Large gt;2 , strongly non uniform gt;0.28 amp; 956;m 1 , and in situ tunable strain is induced in WS2 by pressurizing it with inert gas. We observe a pronounced shift of the spectral weight from neutral to charged excitons at the center of the membrane, in addition to well known strain dependent bandgap modification. We show that the former phenomenon is a signature of a new effect unique for non uniform strain funneling of free carriers towards the region of high strain followed by neutral to charged exciton conversion. Our result establishes non uniform strain engineering as a novel and useful experimental knob for tuning optoelectronic properties of 2D semiconductor

Quantitative Angle-Resolved Small-Spot Reflectance Measurements on Plasmonic Perfect Absorbers: Impedance Matching and Disorder Effects

Plasmonic devices with absorbance close to unity have emerged as essential building blocks for a multitude of technological applications ranging from trace gas detection to infrared imaging. A crucial requirement for such elements is the angle independence of the absorptive performance. In this work, we develop theoretically and verify experimentally a quantitative model for the angular behavior of plasmonic perfect absorber structures based on an optical impedance matching picture. To achieve this, we utilize a simple and elegant k-space measurement technique to record quantitative angle-resolved reflectance measurements on various perfect absorber structures. Particularly, this method allows quantitative reflectance measurements on samples where only small areas have been nanostructured, for example, by electron-beam lithography. Combining these results with extensive numerical modeling, we find that matching of both the real and imaginary parts of the optical impedance is crucial to obtain perfect absorption over a large angular range. Furthermore, we successfully apply our model to the angular dispersion of perfect absorber geometries with disordered plasmonic elements as a favorable alternative to current array-based designs

Treatment algorithm for hyaluronic acid-related complication based on a systematic review of case reports, case series, and clinical experience

Study Design: Systematic review of hyaluronic acid (HA)-related complications.Objective: To systematically review all available literature including case reports and case series to identify a pattern forthe management of vascular compromise resulting in facial skin ischemia and ocular manifestations following HA injection.Methods: This review was based on a systematic search of 3 electronic databases PubMed, CINAHL, and Scopus for allavailable literature including case series and case reports from database inception to July 2019. Only a total of 52 casereports/series were eligible for review and included 107 patients.Results: The reviewed literature available was comprised from case reports/series and indicated that management ofboth impending skin necrosis and visual disturbances is variable with no repetitive pattern of action. Yet, successfulmanagement is time dependent as early interventions stopped progression and, in some cases, even reversed adverseeffects.Conclusion: Results found no universal protocol for achieving optimal results for adverse effects and as such, we presenta step-by-step algorithm for the emergency management of complications following HA injection

Thrombophilic factors are not the leading cause of thrombosis in Behçet's disease

Background: Venous and arterial thromboses occur in patients with Behçet's disease and are associated with significant morbidity and mortality. Studies on a possible association between the occurrence of thrombosis and thrombophilia in patients with this disease have been controversial. Objective: To determine the prevalence of the most common thrombophilias and dyslipidaemia in patients with Behçet's disease with and without thrombosis. Methods: Blood samples from 107 patients with Behçet's disease who had or did not have thrombosis were analysed for factor V Leiden, prothrombin G20210A polymorphism, methylenetetrahydrofolate reductase (MTHFR) C677T polymorphism, factor VIII level, homocysteine and C reactive protein concentrations, dyslipidaemia, and plasma glucosylceramide. Results: There was no difference between patients with and without thrombosis in the prevalence of prothrombin G20210A polymorphism, factor V Leiden, homozygous MTHFR C677T, or plasma concentrations of homocysteine, C reactive protein, or glucosylceramide. In contrast, patients with thrombosis were found to have significantly higher mean levels of factor VIII, total cholesterol, triglycerides, VLDL cholesterol, and apolipoproteins B-100, C-II, and C-III than those without thrombosis. Multistepwise logistic regression analysis showed that triglyceride concentration was the best marker associated with thrombosis (p = 0.008), with an estimated odds ratio of 1.58 (95% confidence interval, 1.09 to 2.30) for a difference of 40 mg/dl. Conclusions: Thrombophilia does not seem to play a major role in the tendency to thrombosis in Behçet's disease. However, dyslipidaemia, predominantly hypertriglyceridaemia, might be a risk factor