Macroion adsorption: The crucial role of excluded volume and coions

The adsorption of charged colloids (macroions) onto an oppositely charged planar substrate is investigated theoretically. Taking properly into account the finite size of the macroions, unusual behaviors are reported. It is found that the role of the coions (the little salt-ions carrying the same sign of charge as that of the substrate) is crucial to understand the mechanisms involved in the process of macroion adsorption. In particular, the coions can accumulate near the substrate's surface and lead to a counter-intuitive {\it surface charge amplification}.Comment: 11 pages - 4 figures. To appear in JC

Skoleankomstanalyser

COWI præsenterer på Trafikdage en konceptualiseret tilgang til skoleankomstanalyser. Skolernes nærområde er typisk der, hvor der kan opnås den største, koncentrerede trafiksikkerhedsmæssige effekt. Derfor har COWI udviklet en tidssvarende metode til at gennemføre netop skoleankomstanalyserne. Metoden indebærer filmoptagelse af trafikafviklingen med en drone, analyse af videoen med avanceret analysesoftware og på baggrund af analysen at udpege problemstillinger og hertil knyttede anbefalinger til forbedringer. Med COWIs koncept kan der med få ressourcer gennemføres en analyse, som giver en ensartet metodisk tilgang på tværs af skoler og geografier. I dette paper beskrives konceptet, ligesom der gives eksempler på anvendelse i Fredensborg Kommune

Reachability-based impact as a measure for insiderness

Insider threats pose a difficult problem for many organisations. While organisations in principle would like to judge the risk posed by a specific insider threat, this is in general not possible. This limitation is caused partly by the lack of models for human behaviour, partly by restrictions on how much and what may be monitored, and by our inability to identify relevant features in large amounts of logged data. To overcome this, the notion of insiderness has been proposed, which measures the degree of access an actor has to a certain resource. We extend this notion with the concept of impact of an insider, and present different realisations of impact. The suggested approach results in readily usable techniques that allow to get a quick overview of potential insider threats based on locations and assets reachable by employees. We present several variations ranging from pure reachability to potential damage to assets causable by an insider

Model-based Abstraction of Data Provenance

Identifying provenance of data provides insights to the origin of data and intermediate results, and has recently gained increased interest due to data-centric applications. In this work we extend a data-centric system view with actors handling the data and policies restricting actions. This extension is based on provenance analysis performed on system models. System models have been introduced to model and analyse spatial and organisational aspects of organisations, to identify, e.g., potential insider threats. Both the models and analyses are naturally modular; models can be combined to bigger models, and the analyses adapt accordingly. Our approach extends provenance both with the origin of data, the actors and processes involved in the handling of data, and policies applied while doing so. The model and corresponding analyses are based on a formal model of spatial and organisational aspects, and static analyses of permissible actions in the models. While currently applied to organisational models, our approach can also be extended to work flows, thus targeting a more traditional model of provenance

Soft repulsive mixtures under gravity: brazil-nut effect, depletion bubbles, boundary layering, nonequilibrium shaking

A binary mixture of particles interacting via long-ranged repulsive forces is studied in gravity by computer simulation and theory. The more repulsive A-particles create a depletion zone of less repulsive B-particles around them reminiscent to a bubble. Applying Archimedes' principle effectively to this bubble, an A-particle can be lifted in a fluid background of B-particles. This "depletion bubble" mechanism explains and predicts a brazil-nut effect where the heavier A-particles float on top of the lighter B-particles. It also implies an effective attraction of an A-particle towards a hard container bottom wall which leads to boundary layering of A-particles. Additionally, we have studied a periodic inversion of gravity causing perpetual mutual penetration of the mixture in a slit geometry. In this nonequilibrium case of time-dependent gravity, the boundary layering persists. Our results are based on computer simulations and density functional theory of a two-dimensional binary mixture of colloidal repulsive dipoles. The predicted effects also occur for other long-ranged repulsive interactions and in three spatial dimensions. They are therefore verifiable in settling experiments on dipolar or charged colloidal mixtures as well as in charged granulates and dusty plasmas.Comment: 10 pages, 11 figure