A seawater desalination scheme for global hydrological models

Seawater desalination is a practical technology for providing fresh water to coastal arid regions. Indeed, the use of desalination is rapidly increasing due to growing water demand in these areas and decreases in production costs due to technological advances. In this study, we developed a model to estimate the areas where seawater desalination is likely to be used as a major water source and the likely volume of production. The model was designed to be incorporated into global hydrological models (GHMs) that explicitly include human water usage. The model requires spatially detailed information on climate, income levels, and industrial and municipal water use, which represent standard input/output data in GHMs. The model was applied to a specific historical year (2005) and showed fairly good reproduction of the present geographical distribution and national production of desalinated water in the world. The model was applied globally to two periods in the future (2011-2040 and 2041-2070) under three distinct socioeconomic conditions, i.e., SSP (shared socioeconomic pathway) 1, SSP2, and SSP3. The results indicate that the usage of seawater desalination will have expanded considerably in geographical extent, and that production will have increased by 1.4-2.1-fold in 2011-2040 compared to the present (from 2.8×109 m3 yr-1 in 2005 to 4.0-6.0×109 m3 yr-1/, and 6.7-17.3-fold in 2041-2070 (from 18.7 to 48.6×109 m3 yr-1/. The estimated global costs for production for each period are USD 1.1-10.6×109 (0.002-0.019% of the total global GDP), USD 1.6-22.8×109 (0.001-0.020 %), and USD 7.5-183.9×109 (0.002-0.100 %), respectively. The large spreads in these projections are primarily attributable to variations within the socioeconomic scenarios

Anomalous Nernst Effect in Nonmagnetic Nodal Line Semimetal PbTaSe2_2

PbTaSe$_2$ is a unique topological material, in which the number of nodal lines is expected to change at the structural transition between the lower temperature/pressure "L" phase and the higher temperature/pressure "H" phase. We report the anomalous Nernst effect attributed to the Berry curvature of nodal lines and its change with the structural transition. In the L phase, the Nernst coefficient ($S_{yx}$) shows the step-like magnetic field dependence reminiscent of the anomalous Nernst effect of nonmagnetic Dirac/Weyl semimetals. By applying hydrostatic pressure, we discovered that the amplitude of the anomalous component significantly decreases at the transition to the H phase, which might correspond to the partial annihilation of nodal line structures.Comment: 29 page, 14 figure

An integrated model for the assessment of global water resources ? Part 1: Input meteorological forcing and natural hydrological cycle modules

International audienceAn integrated global water resources model was developed consisting of six modules: land surface hydrology, river routing, crop growth, reservoir operation, environmental flow requirement estimation, and anthropogenic water withdrawal. It simulates both natural and anthropogenic water flow globally (excluding Antarctica) on a daily basis at a spatial resolution of 1°×1° (longitude and latitude). The simulation period is 10 years, from 1986 to 1995. This first part of the two-feature report describes the input meteorological forcing and natural hydrological cycle modules of the integrated model, namely the land surface hydrology module and the river routing module. The input meteorological forcing was provided by the second Global Soil Wetness Project (GSWP2), an international land surface modeling project. Several reported shortcomings of the forcing component were improved. The land surface hydrology module was developed based on a bucket type model that simulates energy and water balance on land surfaces. Simulated runoff was compared and validated with observation-based global runoff data sets and observed streamflow records at 32 major river gauging stations around the world. Mean annual runoff agreed well with earlier studies at global, continental, and continental zonal mean scales, indicating the validity of the input meteorological data and land surface hydrology module. In individual basins, the mean bias was less than ±20% in 14 of the 32 river basins and less than ±50% in 24 of the basins. The performance was similar to the best available precedent studies with closure of energy and water. The timing of the peak in streamflow and the shape of monthly hydrographs were well simulated in most of the river basins when large lakes or reservoirs did not affect them. The results indicate that the input meteorological forcing component and the land surface hydrology module provide a framework with which to assess global water resources, with the potential application to investigate the subannual variability in water resources. GSWP2 participants are encouraged to re-run their model using this newly developed meteorological forcing input, which is in identical format to the original GSWP2 forcing input

Unconventional charge density wave in the organic conductor alpha-(BEDT-TTF)_2KHg(SCN)_4

The low temperature phase (LTP) of alpha-(BEDT-TTF)_2KHg(SCN)_4 salt is known for its surprising angular dependent magnetoresistance (ADMR), which has been studied intensively in the last decade. However, the nature of the LTP has not been understood until now. Here we analyse theoretically ADMR in unconventional (or nodal) charge density wave (UCDW). In magnetic field the quasiparticle spectrum in UCDW is quantized, which gives rise to spectacular ADMR. The present model accounts for many striking features of ADMR data in alpha-(BEDT-TTF)_2KHg(SCN)_4.Comment: 5 pages, 6 figure

The Origin of the Charge Ordering and Its Relevance to Superconductivity in θ\theta-(BEDT-TTF)2_2X: The Effect of the Fermi Surface Nesting and the Distant Electron-Electron Interactions

The origin of the charge ordering in organic compounds $\theta$-(BEDT-TTF)$_2 X$ ($X=MM'$(SCN)$_4$, $M=$Tl,Rb,Co, $M'=$Cs,Zn) is studied using an extended Hubbard model. Calculating the charge susceptibility within random phase approximation (RPA), we find that the $(3\times 3)\sim (3\times 4)$ charge ordering observed at relatively high temperatures can be considered as a consequence of a cooperation between the Fermi surface nesting, controlled by the hopping integral in the $c$ direction, and the electron-electron interactions, where the distant (next nearest neighbor) interactions that have not been taken into account in most of the previous studies play an important role.Mean field analysis at T=0 also supports the RPA results, and further shows that in the $3\times 3$ charge ordered state, some portions of the Fermi surface remain ungapped and are nested with a nesting vector close to the modulation wave vector of the horizontal stripe ordering observed at low temperatures in $X=MM'$(SCN)$_4$. We further study the possibility of superconductivity by taking into account the distant off-site repulsions and the band structure corresponding to $X=$I$_3$, in which superconductivity is experimentally observed. We find that there is a close competition between $d_{xy}$-wave-like singlet pairing and $p_{x+2y}$-wave-like triplet pairing due to a cooperation between the charge and the spin fluctuations. The present analysis provides a possible unified understanding of the experimental phase diagram of the $\theta$-(BEDT-TTF)$_2 X$ family, ranging from a charge ordered insulator to a superconductor.Comment: 13 pages, 18 figures (Figs.5,6,7,14,15,18 compressed using jpeg2ps

Magnetothermopower and Nernst effect in unconventional charge density waves

Recently we have shown that the striking angular dependent magnetoresistance in the low temperature phase (LTP) of alpha-(BEDT-TTF)_2KHg(SCN)_4 is consistently described in terms of unconventional charge density wave (UCDW). Here we investigate theoretically the thermoelectric power and the Nernst effect in UDW. The present results account consistently for the recent data of magnetothermopower in alpha-(BEDT-TTF)_2KHg(SCN)_4 obtained by Choi et al. (Phys. Rev. B, 65, 205119 (2002)). This confirms further our identification of LTP in this salt as UCDW. We propose also that the Nernst effect provides a clear signature of UDW.Comment: 4 pages, 4 figure

Novel Charge Order and Superconductivity in Two-Dimensional Frustrated Lattice at Quarter Filling

Motivated by the various physical properties observed in $\theta$-(BEDT-TTF)$_2$X, we study the ground state of extended Hubbard model on two-dimensional anisotropic triangular lattice at 1/4-filling with variational Monte Carlo method. It is shown that the nearest-neighbor Coulomb interaction enhances the charge fluctuation and it induces the anomalous state such as charge-ordered metallic state and the triplet next-nearest-neighbor $f$-wave superconductivity. We discuss the relation to the real materials and propose the unified view of the family of $\theta$-(BEDT-TTF)$_2$X.Comment: 4 pages, 5 figure

Electronic correlation in the infrared optical properties of the quasi two dimensional κ\kappa-type BEDT-TTF dimer system

The polarized optical reflectance spectra of the quasi two dimensional organic correlated electron system $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]$Y$, $Y =$ Br and Cl are measured in the infrared region. The former shows the superconductivity at $T_{\rm c} \simeq$ 11.6 K and the latter does the antiferromagnetic insulator transition at $T_{\rm N} \simeq$ 28 K. Both the specific molecular vibration mode $\nu_{3}(a_{g})$ of the BEDT-TTF molecule and the optical conductivity hump in the mid-infrared region change correlatively at $T^{*} \simeq$ 38 K of $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Br, although no indication of $T^{*}$ but the insulating behaviour below $T_{\rm ins} \simeq$ 50-60 K are found in $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl. The results suggest that the electron-molecular vibration coupling on the $\nu_{3}(a_{g})$ mode becomes weak due to the enhancement of the itinerant nature of the carriers on the dimer of the BEDT-TTF molecules below $T^{*}$, while it does strong below $T_{\rm ins}$ because of the localized carriers on the dimer. These changes are in agreement with the reduction and the enhancement of the mid-infrared conductivity hump below $T^{*}$ and $T_{\rm ins}$, respectively, which originates from the transitions between the upper and lower Mott-Hubbard bands. The present observations demonstrate that two different metallic states of $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Br are regarded as {\it a correlated good metal} below $T^{*}$ including the superconducting state and {\it a half filling bad metal} above $T^{*}$. In contrast the insulating state of $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl below $T_{\rm ins}$ is the Mott insulator.Comment: 8 pages, 7 figure