Infrared Absorption and Its Sources of CdZnTe at Cryogenic Temperature

To reveal the causes of infrared absorption in the wavelength region between electronic and lattice absorptions, we measured the temperature dependence of the absorption coefficient of p-type low-resistivity (∼102 Ωcm) CdZnTe crystals. We measured the absorption coefficients of CdZnTe crystals in four wavelength bands (λ=6.45, 10.6, 11.6, 15.1 μm) over the temperature range of T=8.6-300 K with an originally developed system. The CdZnTe absorption coefficient was measured to be α=0.3-0.5 cm−1 at T=300 K and α=0.4-0.9 cm−1 at T=8.6 K in the investigated wavelength range. With an absorption model based on transitions of free holes and holes trapped at an acceptor level, we conclude that the absorption due to free holes at T=150-300 K and that due to trapped-holes at T<50 K are dominant absorption causes in CdZnTe. We also discuss a method to predict the CdZnTe absorption coefficient at cryogenic temperature based on the room-temperature resistivity

Identifying, counting, and characterizing superfine activated-carbon particles remaining after coagulation, sedimentation, and sand filtration

Superfine powdered activated carbon (SPAC; particle diameter ∼1 μm) has greater adsorptivity for organic molecules than conventionally sized powdered activated carbon (PAC). Although SPAC is currently used in the pretreatment to membrane filtration at drinking water purification plants, it is not used in conventional water treatment consisting of coagulation–flocculation, sedimentation, and rapid sand filtration (CSF), because it is unclear whether CSF can adequately remove SPAC from the water. In this study, we therefore investigated the residual SPAC particles in water after CSF treatment. First, we developed a method to detect and quantify trace concentration of carbon particles in the sand filtrate. This method consisted of 1) sampling particles with a membrane filter and then 2) using image analysis software to manipulate a photomicrograph of the filter so that black spots with a diameter >0.2 μm (considered to be carbon particles) could be visualized. Use of this method revealed that CSF removed a very high percentage of SPAC: approximately 5-log in terms of particle number concentrations and approximately 6-log in terms of particle volume concentrations. When waters containing 7.5-mg/L SPAC and 30-mg/L PAC, concentrations that achieved the same adsorption performance, were treated, the removal rate of SPAC was somewhat superior to that of PAC, and the residual particle number concentrations for SPAC and PAC were at the same low level (100–200 particles/mL). Together, these results suggest that SPAC can be used in place of PAC in CSF treatment without compromising the quality of the filtered water in terms of particulate matter contamination. However, it should be noted that the activated carbon particles after sand filtration were smaller in terms of particle size and were charge-neutralized to a lesser extent than the activated carbon particles before sand filtration. Therefore, the tendency of small particles to escape in the filtrate would appear to be related to the fact that their small size leads to a low destabilization rate during the coagulation process and a low collision rate during the flocculation and filtration processes

Minimizing residual black particles in sand filtrate when applying super-fine powdered activated carbon: Coagulants and coagulation conditions

Because of the eminent adsorptive capacity and rate for dissolved organic molecules compared to conventionally-sized powdered activated carbon (PAC), super-fine powdered activated carbon (SPAC) is gathering momentum for use in not only the pretreatment for membrane filtration for drinking water purification but also the conventional water purification process consisting of coagulation-flocculation, sedimentation, and rapid sand-filtration (CSF). However, the probability of SPAC particles to leak through a sand bed is higher than that of PAC, and their strict leakage control is an issue to be challenged when applying SPAC to CSF. However, study focusing on very high particle removal, which yield residual concentrations down to around 100 particles/mL, has been very limited. A previous study mentioned that the tendency of SPAC leakage is related to its low destabilization. In response to this, the present study focused on the two key components of coagulation (mixing intensity and coagulants) and investigated how to effectively reduce the residual SPAC after CSF. Astonishingly, the flash mixing (the first process of CSF), especially its G (velocity gradient) value, played the most important role in determining the residual SPAC in the filtrate of sand filter (the fourth process). Even if the slow mixing time was short, a sufficiently large G value but short T (mixing time) value in flash mixing effectively reduced the residual SPAC. When the total GT value of flash and slow mixing was fixed at a constant, priority should be given to flash mixing to reduce the residual SPAC. Among 23 PACI (poly-aluminum chloride) coagulants, PACI with a high-basicity (basicity 70%) and with sulfate ion (0.14 of sulfate/aluminum in molar ratio), produced by Al(OH)(3)-dissolution, were the most effective to reduce the residual SPAC after CSF. PACIs produced by base-titration, which have been intensively investigated in previous researches, were not effective due to lack of floc-formation ability. However, their Al species composition determined by the ferron method were almost the same as those of PACT by Al(OH)(3)-dissolution, and their charge-neutralization capacities were higher. PACIs produced by Al(OH)(3)-dissolution possessed both charge-neutralization and floc-formation abilities, but the former ability was more important to minimize the residual of SPAC