The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers

Using the self-consistent field approach, the effect of asymmetry of the coil block on the microphase separation is focused in ABC coil-rod-coil triblock copolymers. For different fractions of the rod block $f_{\text B}$, some stable structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell hexagonal lattice, and the phase diagrams are constructed. The calculated results show that the effect of the coil block fraction $f_{\text A}$ is dependent on $f_{\text B}$. When $f_{\text B}=0.2$, the effect of asymmetry of the coil block is similar to that of the ABC flexible triblock copolymers; When $f_{\text B}=0.4$, the self-assembly of ABC coil-rod-coil triblock copolymers behaves like rod-coil diblock copolymers under some condition. When $f_{\text B}$ continues to increase, the effect of asymmetry of the coil block reduces. For $f_{\text B}=0.4$, under the symmetrical and rather asymmetrical conditions, an increase in the interaction parameter between different components leads to different transitions between cylinders and lamellae. The results indicate some remarkable effect of the chain architecture on self-assembly, and can provide the guidance for the design and synthesis of copolymer materials.Comment: 9 pages, 3 figure

Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions

The effects of the length of each hydrophobic end block N_{st} and polymer concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA symmetric triblock copolymer solutions are studied using the self-consistent field lattice model. When the system is cooled, micelles are observed, i.e.,the homogenous solution (unimer)-micelle transition occurs. When N_{st} is increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and the temperature-dependent range of micellar aggregation and half-width of specific heat peak for unimer-micelle transition increase monotonously. Compared with associative polymers, it is found that the magnitude of the transition broadness is determined by the ratio of hydrophobic to hydrophilic blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a large N_{st}, the temperature-dependent range of micellar aggregation and half-width of specific heat peak initially decease, and then remain nearly constant. It is shown that the transition broadness is concerned with the changes of the relative magnitudes of the eductions of nonstickers and solvents from micellar cores.Comment: 8 pages, 4 figure

Effect of distribution of stickers along backbone on temperature-dependent structural properties in associative polymer solutions

Effect of distribution of stickers along the backbone on structural properties in associating polymer solutions is studied using self-consistent field lattice model. Only two inhomogeneous morphologies, i.e., microfluctuation homogenous (MFH) and micelle morphologies, are observed. If the system is cooled, the solvent content within the aggregates decreases. When the spacing of stickers along the backbone is increased the temperature-dependent range of aggregation in MFH morphology and half-width of specific heat peak for homogenous solutions-MFH transition increase, and the symmetry of the peak decreases. However, with increasing spacing of stickers, the above three corresponding quantities related to micelles behave differently. It is demonstrated that the broad nature of the observed transitions can be ascribed to the structural changes which accompany the replacement of solvents in aggregates by polymer, which is consistent with the experimental conclusion. It is found that different effect of spacing of stickers on the two transitions can be interpreted in terms of intrachain and interchain associations.Comment: 10 pages, 4 figures. arXiv admin note: text overlap with arXiv:1202.459

Criticality and Continuity of Explosive Site Percolation in Random Networks

This Letter studies the critical point as well as the discontinuity of a class of explosive site percolation in Erd\"{o}s and R\'{e}nyi (ER) random network. The class of the percolation is implemented by introducing a best-of-m rule. Two major results are found: i). For any specific $m$, the critical percolation point scales with the average degree of the network while its exponent associated with $m$ is bounded by -1 and $\sim-0.5$. ii). Discontinuous percolation could occur on sparse networks if and only if $m$ approaches infinite. These results not only generalize some conclusions of ordinary percolation but also provide new insights to the network robustness.Comment: 5 pages, 5 figure

Creating stable molecular condensate using a generalized Raman adiabatic passage scheme

We study the Feshbach resonance assisted stimulated adiabatic passage of an effective coupling field for creating stable molecules from atomic Bose condensate. By exploring the properties of the coherent population trapping state, we show that, contrary to the previous belief, mean-field shifts need not to limit the conversion efficiency as long as one chooses an adiabatic passage route that compensates the collision mean-field phase shifts and avoids the dynamical unstable regime.Comment: 4+\epsilon pages, 3 figure

Supersymmetric QCD flavor changing top quark decay

We present a detailed and complete calculation of the gluino and scalar quarks contribution to the flavour-changing top quark decay into a charm quark and a photon, gluon, or a Z boson within the minimal supersymmetric standard model including flavour changing gluino-quarks-scalar quarks couplings in the right-handed sector. We compare the results with the ones presented in an earlier paper where we considered flavour changing couplings only in the left-handed sector. We show that these new couplings have important consequences leading to a large enhancement when the mixing of the scalar partners of the left- and right-handed top quark is included. Furthermore CP violation in the flavour changing top quark decay will occur when a SUSY phase is taken into account.Comment: 14 pages, latex, 3 figure

Parallel processing architecture for computing inverse differential kinematic equations of the PUMA arm

In advanced robot control problems, on-line computation of inverse Jacobian solution is frequently required. Parallel processing architecture is an effective way to reduce computation time. A parallel processing architecture is developed for the inverse Jacobian (inverse differential kinematic equation) of the PUMA arm. The proposed pipeline/parallel algorithm can be inplemented on an IC chip using systolic linear arrays. This implementation requires 27 processing cells and 25 time units. Computation time is thus significantly reduced