Segregation and precipitation of Er in Ge

Although Er-doped Genanomaterials are attractive for photonic applications, very little is known about the basic properties of Er in Ge. Here, the authors study the annealing behavior of Geimplanted with keV Er ions to doses resulting in ≲1at.% of Er. Large redistribution of Er, with segregation at the amorphous/crystalline interface, starts at ≳500°C, while lower temperatures are required for material recrystallization. However, even at 400°C, Er forms precipitates. The concentration of Er trapped in the bulk after recrystallization decreases with increasing temperature but is independent of the initial bulk Er concentration for the range of ion doses studied here.Work at the ANU was supported by the ARC

Inertial Confinement Fusion Materials Science

Demonstration of thermonuclear ignition and gain on a laboratory scale is one of science's grand challenges. The National Ignition Facility (NIF) is committed to achieving inertial confinement fusion (ICF) by 2010. Success in this endeavor depends on four elements: the laser driver performance, target design, experimental diagnostics performance, and target fabrication and target materials performance. This article discusses the current state of target fabrication and target materials performance. The first three elements will only be discussed insofar as they relate to target fabrication specifications and target materials performance. Excellent reviews of the physics of ICF are given by Lindl [Lindl 1998] and Lindl et al. [Lindl 2004]. To achieve conditions under which inertial confinement is sufficient to achieve thermonuclear burn, an imploded fuel capsule is compressed to conditions of high density and temperature. In the laboratory a driver is required to impart energy to the capsule to effect an implosion. There are three drivers currently being considered for ICF in the laboratory: high-powered lasers, accelerated heavy ions, and x rays resulting from pulsed power machines. Of these, high-powered lasers are the most developed, provide the most symmetric drive, and provide the most energy. Laser drive operates in two configurations. The first is direct drive where the laser energy impinges directly on the ICF capsule and drives the implosion. The second is indirect drive, where the energy from the laser is first absorbed in a high-Z enclosure or hohlraum surrounding the capsule, and the resulting x-rays emitted by the hohlraum material drives the implosion. Using direct drive the laser beam energy is absorbed by the electrons in the outer corona of the target. The electrons transport the energy to the denser shell region to provide the ablation and the resulting implosion. Laser direct drive is generally less efficient and more hydrodynamically unstable than the x-ray driven ablation of indirect drive. The symmetry of the implosion depends sensitively on the balance of the intensity of the individual beams driving the target. Variations in intensity imprint perturbations on the target that are amplified by hydrodynamic instabilities. Indirect drive is less efficient at coupling energy to a capsule than direct drive because of the conversion to x-rays in the hohlraum. However, indirect drive is less sensitive to variations in beam intensity and hydrodynamic instabilities. The ignition threshold for directly-driven and indirectly-driven targets is about the same. However, the gain is calculated to be about a factor of 2 greater in directly driven targets

Surface thermal perturbations of the recent past at low latitudes ? inferences based on borehole temperature data from Eastern Brazil

International audienceBorehole temperature data from the eastern parts of Brazil has been examined in an attempt to extract information on surface thermal perturbations of the recent past at low latitudes. Forward models were employed in the analysis of temperature logs from 16 localities and, in addition, inverse modeling was carried out for data from 10 selected sites. The model results have allowed determination of the magnitude as well as the duration of ground surface temperature (GST) changes in three major geographic zones of Brazil. Prominent among such events are the warming episodes that occurred over much of the subtropical highland regions in the southeastern parts of Brazil. The present magnitude of GST changes in this region are in the range of 2 to 3.5°C but have had their beginning during the early decades of the 20th century. Nearly similar trends are also seen in temperature-depth profiles of bore holes in the subtropical humid zones of the interior and coastal areas of southern Brazil. The data from semi arid zones of northeast Brazil also indicate occurrence of surface warming events but the magnitudes are in the range of 1.4 to 2.2°C while the duration of the warming event is larger, extending back into the last decades of the 19th century. There are indications that changes in both climate and vegetation cover contribute to variations in GST. Thus the magnitudes of GST variations are relatively large in localities which have undergone changes in vegetation cover. Also there are indications that GST changes are practically insignificant in areas of tropical rain forest. Another important result emerging from model studies is that the climate was relatively cooler during the 17th and 18th centuries. The climate histories, deduced from geothermal data, are found to be consistent with results of available meteorological records in southern Brazil. Comparative studies also indicate that the magnitudes and duration of recent climate changes in southern and eastern Brazil are similar to those found in other continental areas such as North America, Asia and Europe

DFT and PM3 Computational Studies of the Reaction Mechanism of the Oxidation of L-Tyrosine by Iodine in the Gas Phase

- The oxidation of L-Tyrosine by molecular iodine was studied using semi-empirical and density functional theory methods. Molecular information such as net charges, values of frontier orbital energies, composition, proportions and bonding contribution were obtained and analyzed. Thus, possible reactive sites were proposed and the reaction mechanism was postulated. The postulated transition states, intermediates and products were also computed using the PM3 and DFT methods. Computed enthalpies of the oxidation reaction at standard conditions for the PM3 and DFT calculation were 216.97 kJ/mol and -36327404.72 kJ/mol respectively. The calculated ΔGo andΔSo, for the transition states according to the DFT model were both large and negative indicating that the processes were exergonic associative substitution reactions

Information exposure from consumer IoT devices: a multidimensional, network-informed measurement approach

Internet of Things (IoT) devices are increasingly found in everyday homes, providing useful functionality for devices such as TVs, smart speakers, and video doorbells. Along with their benefits come potential privacy risks, since these devices can communicate information about their users to other parties over the Internet. However, understanding these risks in depth and at scale is difficult due to heterogeneity in devices' user interfaces, protocols, and functionality. In this work, we conduct a multidimensional analysis of information exposure from 81 devices located in labs in the US and UK. Through a total of 34,586 rigorous automated and manual controlled experiments, we characterize information exposure in terms of destinations of Internet traffic, whether the contents of communication are protected by encryption, what are the IoT-device interactions that can be inferred from such content, and whether there are unexpected exposures of private and/or sensitive information (e.g., video surreptitiously transmitted by a recording device). We highlight regional differences between these results, potentially due to different privacy regulations in the US and UK. Last, we compare our controlled experiments with data gathered from an in situ user study comprising 36 participants

Deformation Behavior of Nanoporous Metals

Nanoporous open-cell foams are a rapidly growing class of high-porosity materials (porosity {ge} 70%). The research in this field is driven by the desire to create functional materials with unique physical, chemical and mechanical properties where the material properties emerge from both morphology and the material itself. An example is the development of nanoporous metallic materials for photonic and plasmonic applications which has recently attracted much interest. The general strategy is to take advantage of various size effects to introduce novel properties. These size effects arise from confinement of the material by pores and ligaments, and can range from electromagnetic resonances to length scale effects in plasticity. In this chapter we will focus on the mechanical properties of low density nanoporous metals and how these properties are affected by length scale effects and bonding characteristics. A thorough understanding of the mechanical behavior will open the door to further improve and fine-tune the mechanical properties of these sometimes very delicate materials, and thus will be crucial for integrating nanoporous metals into products. Cellular solids with pore sizes above 1 micron have been the subject of intense research for many years, and various scaling relations describing the mechanical properties have been developed.[4] In general, it has been found that the most important parameter in controlling their mechanical properties is the relative density, that is, the density of the foam divided by that of solid from which the foam is made. Other factors include the mechanical properties of the solid material and the foam morphology such as ligament shape and connectivity. The characteristic internal length scale of the structure as determined by pores and ligaments, on the other hand, usually has only little effect on the mechanical properties. This changes at the submicron length scale where the surface-to-volume ratio becomes large and the effect of free surfaces can no longer be neglected. As the material becomes more and more constraint by the presence of free surfaces, length scale effects on plasticity become more and more important and bulk properties can no longer be used to describe the material properties. Even the elastic properties may be affected as the reduced coordination of surface atoms and the concomitant redistribution of electrons may soften or stiffen the material. If, and to what extend, such length scale effects control the mechanical behavior of nanoporous materials depends strongly on the material and the characteristic length scale associated with its plastic deformation. For example, ductile materials such as metals which deform via dislocation-mediated processes can be expected to exhibit pronounced length scale effects in the sub-micron regime where free surfaces start to constrain efficient dislocation multiplication. In this chapter we will limit our discussion to our own area of expertise which is the mechanical behavior of nanoporous open-cell gold foams as a typical example of nanoporous metal foams. Throughout this chapter we will review our current understanding of the mechanical properties of nanoporous open-cell foams including both experimental and theoretical studies

Influence of soil physico-chemical properties on productivity of black pepper (Piper nigrum L.)

Soil surveys were conducted to study the physico-chemical characteristics of major black pepper (Piper nigrum) growing soils in Kerala and their relationship with black pepper productivity. Soil samples were collected from four major black pepper growing districts, namely, ldukki, Wayanad (high elevation), Kozhikode and Kannur (low elevation) and were classified based on yield as high, moderate and low yieJdinggardens. The relationships between elevations, physico-chemical properties and black pepper productivity were studied. The investigation revealed that soils of high yielding gardens were high in sand and low in clay fractions. These soils had high pH, base saturation, canon exchange capacity, organic carbon, phosphorus, potassium, calcium, magnesium and zinc status compared to low yielding gardens. These factors favoured good growth of black pepper vines with higher productivity. &nbsp

Evaluation of composted coir p ith with chemical and biofertilizers on nutrient availability, yield and quality of b lack pepper (Piper nigrum L.)

Composted coir pith was evaluated at Madikeri (Karnataka) under integrated plant nutrient management system to substitute chemical input of fertilizers for improving the yield and quality of black pepper (Piper nigrum). Application of composted coir pith (CC) @ 2.5 t ha" with full recommended dose of NPK (100:40:140 kg ha" of N, P,O, and K, O) yielded the highest (4.18 kg vine" ) which was on par with 1.25 t ha·1 CC + full NPK, 2.5 t ha·1 CC + y, NPK + Azospirillum sp., 1.25 t ha" CC + y, NPK + Azospirillum sp. and 2.5 t ha" CC alone. The levels of composted coir pith application were on par with regard to quality (piperine and oleoresin contents). of black pepper. The highest benefit-cost ratio of 1.94 was recorded in the ,treatment with composted coir pith @ 1.25 t ha" + Azospirillum sp. &nbsp