High-mode spoof SPP of periodic metal grooves for ultra-sensitive terahertz sensing

We report terahertz surface plasmon resonance (SPR) sensing based on prism-coupling to the spoof surface plasmon polariton (SSPP) mode existing on periodically grooved metal films. It was demonstrated that, except for the fundamental mode of the SSPP, there was also a higher mode SSPP wave when the depth of groove was larger. Both fundamental and high-order modes of SSPP could be used for terahertz sensing. We compared the performance of different modes of SSPP on the sensing sensitivity using both reflection amplitude and phase-jump information. The results indicated that the gap distance between the prism base and the metal film had a significant influence on the reflectivity of SPR sensing by affecting the coupling efficiency of an evanescent wave to an SSPP wave; also, high-order mode SSPP-based sensing had a high sensitivity of up to 2.27 THz/RIU, which nearly doubled the sensitivity of the fundamental mode. The application of high-mode SSPP has enormous potential for ultra-sensitive SPR sensing in the terahertz regime

Performance analysis of higher mode spoof surface plasmon polariton for terahertz sensing

We investigated the spoof surface plasmon polaritons (SSPPs) on 1D grooved metal surface for terahertz sensing of refractive index of the filling analyte through a prism-coupling attenuated total reflection setup. From the dispersion relation analysis and the finite element method-based simulation, we revealed that the dispersion curve of SSPP got suppressed as the filling refractive index increased, which cause the coupling resonance frequency redshifting in the reflection spectrum. The simulated results for testing various refractive indexes demonstrated that the incident angle of terahertz radiation has a great effect on the performance of sensing. Smaller incident angle will result in a higher sensitive sensing with a narrower detection range. In the meanwhile, the higher order mode SSPP-based sensing has a higher sensitivity with a narrower detection range. The maximum sensitivity is 2.57 THz/RIU for the second-order mode sensing at 45° internal incident angle. The proposed SSPP-based method has great potential for high sensitive terahertz sensing

Plasmonic corrugated cylinder–cone terahertz probe

The spoof surface plasmon polariton (SPP) effect on the electromagnetic field distribution near the tip of a periodically corrugated metal cylinder–cone probe working at the terahertz regime was studied. We found that radially polarized terahertz radiation could be coupled effectively through a spoof SPP into a surface wave and propagated along the corrugated surface, resulting in more than 20× electric field enhancement near the tip of probe. Multiple resonances caused by the antenna effect were discussed in detail by finite element computation and theoretical analysis of dispersion relation for spoof SPP modes. Moreover, the key figures of merit such as the resonance frequency of the SPP can be flexibly tuned by modifying the geometry of the probe structure, making it attractive for application in an apertureless background-free terahertz near-field microscope

Optical conductivity of an electron gas driven by a pulsed terahertz radiation field

We present a theoretical study to examine the optical conductivity of an electron gas in the presence of a pulsed terahertz (THz) radiation field. Applying a very simple Drude like approach, we calculate the transit current for an electron gas driven by a pulsed light field. By taking three types of the pulsed radiation fields with different analytical forms, we prove analytically or numerically that although the corresponding transit current depends on the shape of the radiation field in time-domain, the optical conductivity in frequency-domain is independent upon the profile of the pulsed light field when optical conductivity in frequency-domain is obtained by Fourier transformation of both the pulsed radiation field and the transit current. Thus, the optical conductivity in frequency-domain can be described by the well known Drude formula even in the presence of the pulsed THz field. This finding can be applied for experimental measurement of the real and imaginary parts of optical conductivity in electronic and optoelectronic materials by using, e.g., the THz time-domain spectroscopy (TDS)

High-Performance Surface-Enhanced Raman Scattering Substrates Based on the ZnO/Ag Core-Satellite Nanostructures

Recently, hierarchical hybrid structures based on the combination of semiconductor micro/nanostructures and noble metal nanoparticles have become a hot research topic in the area of surface-enhanced Raman scattering (SERS). In this work, two core-satellite nanostructures of metal oxide/metal nanoparticles were successfully introduced into SERS substrates, assembling monodispersed small silver nanoparticles (Ag NPs) on large polydispersed ZnO nanospheres (p-ZnO NSs) or monodispersed ZnO nanospheres (m-ZnO NSs) core. The p-ZnO NSs and m-ZnO NSs were synthesized by the pyrolysis method without any template. The Ag NPs were prepared by the thermal evaporation method without any annealing process. An ultralow limit of detection (LOD) of 1 × 10−13 M was achieved in the two core-satellite nanostructures with Rhodamine 6G (R6G) as the probe molecule. Compared with the silicon (Si)/Ag NPs substrate, the two core-satellite nanostructures of Si/p-ZnO NSs/Ag NPs and Si/m-ZnO NSs/Ag NPs substrates have higher enhancement factors (EF) of 2.6 × 108 and 2.5 × 108 for R6G as the probe molecule due to the enhanced electromagnetic field. The two core-satellite nanostructures have great application potential in the low-cost massive production of large-area SERS substrates due to their excellent SERS effect and simple preparation process without any template

Modeling and Selection of RF Thermal Plasma Hot-Wall Torch for Large-Scale Production of Nanopowders

Fouling is a great problem that significantly affects the continuous operation for large-scale radio-frequency (RF) thermal plasma synthesizing nanopowders. In order to eliminate or weaken the phenomenon, numerical simulations based on FLUENT software were founded to investigate the effect of operation parameters, including feeding style of central gas and sheath gas, on plasma torches. It is shown that the tangential feeding style of central gas brings serious negative axial velocity regions, which always forces the synthesized nanopowders to back-mix, and further leads to the fouling of the quartz tube. Moreover, it is shown that sheath gas should be tangentially fed into the plasma reactor to further eliminate the gas stream's back-mixing. However, when this feeding style is applied, although the negative axial velocity region is decreased, the plasma gas and kinetic energy of the vapor phase near the wall of the plasma reactor are less and lower, respectively; as a result, that plasma flame is more difficult to be arced. A new plasma arcing method by way of feeding gun instead of torch wall was proposed and put in use. The fouling problem has been well solved and plasma arcing is well ensured, and as a result, the experiment on large-scale production of nanopowders can be carried out for 8 h without any interruption, and synthesized Si and Al2O3 nanopowders exhibit good dispersion and sphericity

Oxygen Vacancies-Induced Antifouling Photoelectrochemical Aptasensor for Highly Sensitive and Selective Determination of α‑Fetoprotein

Accurate measurement of cancer markers in urine is a convenient method for tumor monitoring. However, the concentration of cancer markers in urine is so low that it is difficult to achieve their measurement. Photoelectrochemical (PEC) sensors are a promising technology to realize the detection of trace cancer markers due to their high sensitivity. Currently, the interference of nonspecific biomolecules in urine is the main reason affecting the high sensitivity and selectivity of PEC sensors in detecting cancer markers. In this work, a strategy of oxygen vacancy (OV) modulation is proposed to construct a fouling-resistant PEC aptamer sensing platform for the detection of α-fetoprotein (AFP), a liver cancer marker. The introduction of OVs induces the formation of intermediate localized states in the photoelectric material, which not only facilitates the separation of photogenerated carriers but also leads to the redshift of the light absorption edge. More importantly, OVs with positive electrical properties can be employed to modify the antifouling layer (C-PEG) with negatively charged groups through an electrostatic interaction. The synergistic effect of OVs, antifouling layer, and aptamer resulted in a TiO2/OVs/C-PEG-based PEC sensor achieves a wide linear range from 1 pg/mL to 100 ng/mL and a low detection limit of 0.3 pg/mL for AFP. In addition, the sensor successfully realized the determination of AFP in urine samples and accurately differentiated between normal people and liver cancer patients in the early and advanced stages. This project is of great significance in advancing the application of photoelectrochemical bioanalytical technology to achieve the detection of cancer markers in urine by investigating the construction of an OVs-regulated fouling-resistant sensing interface

Au Nanostars Coated with a Thin Film of MIL-100 (Fe) for SERS-Based Sensing of Volatile Organic Compound Indicators in Saliva

Mortality of gastric cancer is the second in cancer-associated deaths due to the lack of specific symptoms at an early stage, and thus, early detection of gastric cancer is receiving more attention. Nowadays, volatile organic compound (VOC) indicators have been found to be helpful for screening a variety of cancers. Meanwhile, hybrid VOC indicators, namely, VOCs derived from both human breath and body fluids, provide more information about health status. Nevertheless, details of VOCs in body fluid (e.g. saliva) are still unclear and tracking of these VOCs remains a challenge. In this research, 10 kinds of VOCs released from the saliva were reported to be potential indicators for gastric cancer prewarning. To track these potential indicators with high specificity, a surface-enhanced Raman scattering (SERS) sensor based on a thin layer of MIL-100 (Fe) shell-wrapped Au nanostars (Au-star) was developed, and part of the aforementioned VOC indicators (e.g., 2-butanone, eucalyptol, and isopropanol) were found to be selectively detected by the sensor. These pilot results indicate a bright future for the proposed strategy for disease screening and the design of future high-performance SERS sensors