Investigation of Parietal Polysaccharides from Retama raetam Roots

This study characterizes the cell wall hemicellulose and pectins polymers of Retama raetam. This species develops a particularly important root system and is adapted to arid areas. The cellulose, hemicelluloses and pectins were extracted. The cellulose remains the major component of the wall (27% for young roots and 80% for  adult roots), hemicelluloses (14.3% for young roots and 3.6%  for adult roots) and pectins (17.3% for young roots and 4.1% for adult roots). The monosaccharidic composition of water soluble extracts determined by gas liquid chromatography (GLC) and completed by infrared (FTIR) spectroscopy of hemicellulosic shows the presence of xylose as a major monosaccharide in the non-cellulose polysaccharides (47.8% for young roots and 59.5% for adult roots). These results indicate the presence of the homogalacturonans and rhamnogalacturonans in pectin. This study constitutes the preliminary data obtained in the biochemical analysis of the parietal compounds of the roots of a species which grows in an arid area in comparison with those of its aerial parts.Keywords: Retama raetam, Roots, Cell Wall, Investigation, Polysaccharides, Monosaccharidi

Large Deformation Effects in the N = Z 44Ti Compound Nucleus

The N = Z 44Ti* nucleus has been populated in Fusion Evaporation process at very high excitation energies and angular momenta using two entrance channels with different mass-asymmetry. The deformation effects in the rapidly rotating nuclei have been investigated through the energy distribution of the alpha-particle combined to statistical-model calculations. In the case of low-multiplicity events, the ratio between first particle emitted has been measured and shows significant disagreement with the predictions of the statistical-model. This may explain The large discrepancies observed in proton energy spectra measured in previous experiments performed in the same mass region.Comment: Proceeding of the 10th International Conference on Nuclear Reaction Mechanisms, Varenna Italy, June 9-13 2003. 10 pages, 6 figures, 1 tabl

Casimir force in critical ternary polymer solutions

Consider a mixture of two incompatible polymers A and B in a common good solvent, confined between two parallel plates separated by a finite distance L. We assume that these plates strongly attract one of the two polymers close to the consolute point (critical adsorption). The plates then experience an effective force resulting from strong fluctuations of the composition. To simplify, we suppose that either plates have the same preference to attract one component (symmetric plates) or they have an opposed preference (asymmetric plates). The force is attractive for symmetric plates and repulsive for asymmetric ones. We first exactly compute the force using the blob model, and find that the attractive and repulsive forces decay similarly to L⁻⁴. To go beyond the blob model that is a mean-field theory, and in order to get a correct induced force, we apply the Renormalization-Group to a φ⁴ -field theory ( φ is the composition fluctuation), with two suitable boundary conditions at the surfaces. The main result is that the expected force is the sum of two contributions. The first one is the mean-field contribution decaying as L⁻⁴, and the second one is the force deviation originating from strong fluctuations of the composition that decreases rather as L⁻³. This implies the existence of some cross-over distance L* ∼ aNφ¹/² ( a is the monomer size, N is the polymerization degree of chains and φ is the monomer volumic fraction), which separates two distance-regimes. For small distances (L L*) the fluctuation force is more important.Розглядається суміш двох несумісних полімерів A і B , що добре розчиняються в спільному розчиннику, вміщена між двома паралельними пластинами, розділеними скінченною відстанню L. Ми вважаємо, що поблизу точки розчинення вони сильно притягають один з двох полімерів (критична адсорбція). При цьому пластини знаходяться під впливом ефективної сили, породженої сильними флуктуаціями суміші. Для спрощення ми припускаємо, що або обидві пластини притягають той самий компонент (симетричні пластини) або вони віддають перевагу різним компонентам (асиметричні пластини). Симетричним пластинам відповідає сила притягання, асиметричним – відштовхування. Спершу ми точно розрахували цю силу, використовуючи краплинну модель, і встановили, що сили притягання і відштовхування загасають подібним чином як L⁻⁴. Щоб вийти поза межі краплинної моделі, яка відповідає наближенню середнього поля, і з метою отримати правильний вигляд індукованої сили, ми застосували ренорм-груповий підхід до теорії поля φ⁴ ( φ – флуктуація суміші) з двома відповідними граничними умовами на поверхнях. У результаті встановлено, що шукана сила є сумою двох вкладів. Перший з них – це вклад середнього поля, що загасає якL⁻⁴, а другий – відхилення, викликане сильними флуктуаціями суміші, що зменшується радше як L⁻³. Це означає, що існує певна відстань кроссоверу L* ∼ aNφ¹/² ( a – розмір мономера, N – ступінь полімеризації ланцюжків і φ – об’ємна частка мономера), що розділяє характерні відстані двох згаданих режимів. На малих відстанях (L L*) більш важливим стає флуктуаційний вклад

8Be cluster emission versus alpha evaporation in 28Si + 12C

The possible occurence of highly deformed configurations in the $^{40}$Ca di-nuclear system formed in the $^{28}$Si + $^{12}$C reaction is investigated by analyzing the spectra of emitted light charged particles. Both inclusive and exclusive measurements of the heavy fragments (A $\geq$ 10) and their associated light charged particles (protons and $\alpha$ particles) have been made at the IReS Strasbourg {\sc VIVITRON} Tandem facility at bombarding energies of $E_{lab}$ ($^{28}$Si) = 112 MeV and 180 MeV by using the {\sc ICARE} charged particle multidetector array. The energy spectra, velocity distributions, in-plane and out-of-plane angular correlations of light charged particles are compared to statistical-model calculations using a consistent set of parameters with spin-dependent level densities. This spin dependence approach suggests the onset of large nuclear deformation in $^{40}$Ca at high spin. This conclusion might be connected with the recent observation of superdeformed bands in the $^{40}$Ca nucleus. The analysis of $\alpha$ particles in coincidence with $^{32}$S fragments suggests a surprisingly strong $^{8}$Be cluster emission of a binary nature.Comment: 39 pages 15 figure

Controlled-release testing of the static chamber methodology for direct measurements of methane emissions

Direct measurements of methane emissions at the component level provide the level of detail necessary for the development of actionable mitigation strategies. As such, there is a need to understand the magnitude of component-level methane emission sources and to test methane quantification methods that can capture methane emissions at the component level used in national inventories. The static chamber method is a direct measurement technique that has been applied to measure large and complex methane sources, such as oil and gas infrastructure. In this work, we compile methane emission factors from the Intergovernmental Panel on Climate Change (IPCC) Emission Factor Database in order to understand the magnitude of component-level methane flow rates, review the tested flow rates and measurement techniques from 40 controlled-release experiments, and perform 64 controlled-release tests of the static chamber methodology with mass flow rates of 1.02, 10.2, 102, and 512 g h−1 of methane. We vary the leak properties, chamber shapes, chamber sizes, and use of fans to evaluate how these factors affect the accuracy of the static chamber method. We find that 99 % of the component-level methane emission rates from the IPCC Emission Factor Database are below 100 g h−1 and that 77 % of the previously available controlled-release experiments did not test for methane mass flow rates below 100 g h−1. We also find that the static chamber method quantified methane flow rates with an overall accuracy of +14/-14 % and that optimal chamber configurations (i.e., chamber shape, volume, and use of fans) can improve accuracy to below ±5 %. We note that smaller chambers (≤20 L) performed better than larger-volume chambers (≥20 L), regardless of the chamber shape or use of fans. However, we found that the use of fans can substantially increase the accuracy of larger chambers, especially at higher methane mass flow rates (≥100 g h−1). Overall, our findings can be used to engineer static chamber systems for future direct measurement campaigns targeting a wide range of sources, including landfills, sewerage utility holes, and oil and natural gas infrastructure.</p

Search for emission of unstable 8^8Be clusters from hot 40^40Ca and 56^56Ni nuclei

The possible occurence of highly deformed configurations is investigated in the $^{40}$Ca and $^{56}$Ni di-nuclear systems as formed in the $^{28}$Si + $^{12}$C and $^{28}$Si + $^{28}$Si reactions, respectively, by using the properties of emitted light charged particles. Inclusive as well as exclusive data of the heavy fragments (A $\geq$ 6) and their associated light charged particles (p, d, t, and $\alpha$-particles) have been collected at the IReS Strasbourg VIVITRON Tandem facility with two bombarding energies $E_{lab}(^{28}$Si) = 112 and 180 MeV by using the ICARE charged particle multidetector array, which consists of nearly 40 telescopes. The measured energy spectra, velocity distributions, in-plane and out-of-plane angular correlations are analysed by Monte Carlo CASCADE statistical-model calculations using a consistent set of parameters with spin-dependent level densities. Although significant deformation effects at high spin are needed, the remaining disagreement observed in the $^{28}$Si + $^{12}$C reaction for the S evaporation residue suggests an unexpected large unstable $^{8}$Be cluster emission of a binary nature.Comment: 13 pages latex, 9 eps figures. Paper presented at the XXXIX International Winter Meeting on Nuclear Physics, Bormio(Italy) January 22-27, 2001 (to be published at Ricerca Scientifica ed Educazione Permanente

On perturbations of Dirac operators with variable magnetic field of constant direction

We carry out the spectral analysis of matrix valued perturbations of 3-dimensional Dirac operators with variable magnetic field of constant direction. Under suitable assumptions on the magnetic field and on the pertubations, we obtain a limiting absorption principle, we prove the absence of singular continuous spectrum in certain intervals and state properties of the point spectrum. Various situations, for example when the magnetic field is constant, periodic or diverging at infinity, are covered. The importance of an internal-type operator (a 2-dimensional Dirac operator) is also revealed in our study. The proofs rely on commutator methods.Comment: 12 page

Sperm DNA methylation mediates the association of male age on reproductive outcomes among couples undergoing infertility treatment

Parental age at time of offspring conception is increasing in developed countries. Advanced male age is associated with decreased reproductive success and increased risk of adverse neurodevelopmental outcomes in offspring. Mechanisms for these male age effects remain unclear, but changes in sperm DNA methylation over time is one potential explanation. We assessed genome-wide methylation of sperm DNA from 47 semen samples collected from male participants of couples seeking infertility treatment. We report that higher male age was associated with lower likelihood of fertilization and live birth, and poor embryo development (p \u3c 0.05). Furthermore, our multivariable linear models showed male age was associated with alterations in sperm methylation at 1698 CpGs and 1146 regions (q \u3c 0.05), which were associated with \u3e 750 genes enriched in embryonic development, behavior and neurodevelopment among others. High dimensional mediation analyses identified four genes (DEFB126, TPI1P3, PLCH2 and DLGAP2) with age-related sperm differential methylation that accounted for 64% (95% CI 0.42–0.86%; p \u3c 0.05) of the effect of male age on lower fertilization rate. Our findings from this modest IVF population provide evidence for sperm methylation as a mechanism of age-induced poor reproductive outcomes and identifies possible candidate genes for mediating these effects

Vanishing spin alignment : experimental indication of triaxial 28Si+28Si\bf ^{28}Si + {^{28}Si} nuclear molecule

Fragment-fragment-$\gamma$ coincidences have been measured for $\rm ^{28}Si + {^{28}Si}$ at an energy corresponding to the population of a conjectured resonance in $^{56}$Ni. Fragment angular distributions as well as $\gamma$-ray angular correlations indicate that the spin orientations of the outgoing fragments are perpendicular to the orbital angular momentum. This differs from the $\rm ^{24}Mg+{^{24}Mg}$ and the $\rm ^{12}C+{^{12}C}$ resonances, and suggests two oblate $\rm ^{28}Si$ nuclei interacting in an equator-to-equator molecular configuration.Comment: 14 pages standard REVTeX file, 3 ps Figures -- Accepted for publication in Physical Review C (Rapid Communication

Deformation effects in the 28^{28}Si+12^{12}C and 28^{28}Si+28^{28}Si reaction Search

The possible occurence of highly deformed configurations is investigated in the $^{40}$Ca and $^{56}$Ni di-nuclear systems as formed in the $^{28}$Si+$^{12}$C,$^{28}$Si reactions by using the properties of emitted light charged particles. Inclusive as well as exclusive data of the heavy fragments and their associated light charged particles have been collected by using the {\sc ICARE} charged particle multidetector array. The data are analysed by Monte Carlo CASCADE statistical-model calculations using a consistent set of parameters with spin-dependent level densities. Significant deformation effects at high spin are observed as well as an unexpected large $^{8}$Be cluster emission of a binary nature.Comment: 3 pages latex, 2 eps figures, paper presented in "wokshop on physics with multidetector array (pmda2000)Calcutta, India (to be published at PRAMANA, journal of Physics, India