Micro-abrasion-corrosion interactions of Ni-Cr/WC based coatings : approaches to construction of tribo-corrosion maps for the abrasion-corrosion synergism

The process of micro-abrasion-corrosion has been the subject of much research in recent years due to the fact that the action of micron sized particles, typically less than 10 um in diameter, can cause significant degradation of materials in many diverse environments involving aqueous corrosion. Cermet based coatings are often used to combat micro-abrasion-corrosion, but has been little work carried out to characterize the performance of such coatings exposed to micro-abrasion-corrosion or to provide a basis for coating optimisation. In addition, a basis for defining the various micro-abrasion-corrosion interactions has not been suggested to date. In this study the micro-abrasion-corrosion performance of a Ni-Cr/WC coating was assessed and compared to the performance of the steel substrate. The results were used to identify regimes of micro-abrasion as a function of applied load and pH of the solution. In addition, micro-abrasion-corrosion maps were constructed based on the results, showing the variation between micro-abrasion-corrosion regimes, as a function of applied load and pH of the solution

Copper Complexation by Dissolved Organic Matter in arid Soils: A Voltametric Study

A voltammetric method was used to estimate the complexing capacity of water extracts from both desert soils sampled at the root zone of creosote and salt cedar plants, and in soils from interspace or background regions where no vegetative influence was apparent. The copper complexing capacity of water extracts of these desert soils was influenced by contact time and pH. In soils from the root zones of creosote and salt cedar plant, copper complexation capacities at pH 8 were from 5 µM to 60 µM after five min contact periods, while 18 h contact periods yielded copper complexation capacities of 40 µM–80 µM. Soils with no vegetative influence had copper complexing capacities of less the 2 µM. The copper complexing capacities of these soils are well correlated with the concentration of organic carbon in the water extract (r2 = 0.86). The abundance of soluble organic matter in the root zone of desert shrubs has the potential to control the solution speciation of Cu2+. The formation of soluble complexes should also have an important influence on the plant uptake and transport of copper, as well as other heavy metals in the root zones of desert shrubs and beyond

CASK regulates CaMKII autophosphorylation in neuronal growth, calcium signaling, and learning

Calcium (Ca2+)/calmodulin (CaM)-dependent kinase II (CaMKII) activity plays a fundamental role in learning and memory. A key feature of CaMKII in memory formation is its ability to be regulated by autophosphorylation, which switches its activity on and off during synaptic plasticity. The synaptic scaffolding protein CASK (calcium (Ca2+)/calmodulin (CaM) associated serine kinase) is also important for learning and memory, as mutations in CASK result in intellectual disability and neurological defects in humans. We show that in Drosophila larvae, CASK interacts with CaMKII to control neuronal growth and calcium signalling. Furthermore, deletion of the CaMK-like and L27 domains of CASK (CASK β null) or expression of overactive CaMKII (T287D) produced similar effects on synaptic growth and Ca2+ signalling. CASK overexpression rescues the effects of CaMKII overactivity, consistent with the notion that CASK and CaMKII act in a common pathway that controls these neuronal processes. The reduction in Ca2+ signalling observed in the CASK β null mutant caused a decrease in vesicle trafficking at synapses. In addition, the decrease in Ca2+ signalling in CASK mutants was associated with an increase in Ether-à-go-go (EAG) potassium (K+) channel localisation to synapses. Reducing EAG restored the decrease in Ca2+ signalling observed in CASK mutants to the level of wildtype, suggesting that CASK regulates Ca2+ signalling via EAG. CASK knockdown reduced both appetitive associative learning and odour evoked Ca2+ responses in Drosophila mushroom bodies, which are the learning centres of Drosophila. Expression of human CASK in Drosophila rescued the effect of CASK deletion on the activity state of CaMKII, suggesting that human CASK may also regulate CaMKII autophosphorylation

The optimization of self-phased arrays for diurnal motion tracking of synchronous satellites

The diurnal motion of a synchronous satellite necessitates mechanical tracking when a large aperture, high gain antenna is employed at the earth terminal. An alternative solution to this tracking problem is to use a self phased array consisting of a number of fixed pointed elements, each with moderate directivity. Non-mechanical tracking and adequate directive gain are achieved electronically by phase coherent summing of the element outputs. The element beamwidths provide overlapping area coverage of the satellite motion but introduce a diurnal variation into the array gain. The optimum element beamwidth and pointing direction of these elements can be obtained under the condition that the array gain is maximized simultaneously with the minimization of the diurnal variation

ATS-6 millimeter wavelength propagation experiment

An empirical relation for path diversity gain as a function of terminal separation distance and single site fade depth is presented. This relation is based on existing 15.3 GHz ATS-5 attenuation data and 16.0 GHz radiometric temperature data for earth-space propagation paths. Preliminary 30 GHz ATS-6 diversity data are presented and are found to agree well with this empirical relation

Gain degradation and amplitude scintillation due to tropospheric turbulence

It is shown that a simple physical model is adequate for the prediction of the long term statistics of both the reduced signal levels and increased peak-to-peak fluctuations. The model is based on conventional atmospheric turbulence theory and incorporates both amplitude and angle of arrival fluctuations. This model predicts the average variance of signals observed under clear air conditions at low elevation angles on earth-space paths at 2, 7.3, 20 and 30 GHz. Design curves based on this model for gain degradation, realizable gain, amplitude fluctuation as a function of antenna aperture size, frequency, and either terrestrial path length or earth-space path elevation angle are presented

ATS-6 millimeter wavelength propagation experiment

The real time digital data acquisition system used to acquire ATS-6 propagation data at the fixed, transportable, and unmanned terminals is described. This system performs all digital conversion, formating, merging, and recording. All data from the remote sites are transferred to the fixed terminal for recording on a common digital tape. The current status and summary of operations are also reviewed

The OSU self-phased array for propagation measurements using the 11.7 GHz CTS beacon

A self phased array was developed for propagation measurements on an earth-space path. The 11.7 GHz CTS beacon was used as the signal source. The self phased array was used to measure angle of arrival as well as attenuation and scintillation statistics. The performance of the array is described, and sample data are presented. The tracking capability of the self phased array was also studied. This technique permits fully electronic, nonmechanical satellite tracking, thus simplifying unmanned operation and eliminating severe weather tracking constraints

Enabling transition into higher education for students with asperger syndrome

This project report provides an insight into the lives of students with Asperger Syndrome (AS) during their transition into higher education. It details the experiences of eight students with AS. Students were interviewed multiple times at various junctures throughout their first academic year. Although they told stories of everyday disabling barriers, they also shared experiences of academic and social successes. The project was primarily focused on students with AS; however, its findings will hopefully help inform inclusive policy and practice within higher education institutions