The FERRUM Project: experimental and theoretical transition rates of forbidden [Sc II] lines and radiative lifetimes of metastable Sc II levels

Context. In many plasmas, long-lived metastable atomic levels are depopulated by collisions (quenched) before they decay radiatively. In low-density regions, however, the low collision rate may allow depopulation by electric dipole (E1) forbidden radiative transitions, so-called forbidden lines (mainly M1 and E2 transitions). If the atomic transition data are known, these lines are indicators of physical plasma conditions and used for abundance determination. Aims. Transition rates can be derived by combining relative intensities between the decay channels, so-called branching fractions (BFs), and the radiative lifetime of the common upper level. We use this approach for forbidden [Sc ii] lines, along with new calculations. Methods. Neither BFs for forbidden lines, nor lifetimes of metastable levels, are easily measured in a laboratory. Therefore, astrophysical BFs measured in Space Telescope Imaging Spectrograph (STIS) spectra of the strontium filament of Eta Carinae are combined with lifetime measurements using a laser probing technique on a stored ion-beam (CRYRING facility,MSL, Stockholm). These quantities are used to derive the absolute transition rates (A-values). New theoretical transition rates and lifetimes are calulated using the CIV3 code. Results. We report experimental lifetimes of the Sc ii levels 3d2 a3P0,1,2 with lifetimes 1.28, 1.42, and 1.24 s, respectively, and transition rates for lines from these levels down to 3d4s a3D in the region 8270-8390 A. These are the most important forbidden [Sc ii] transitions. New calculations for lines and metastable lifetimes are also presented, and are in good agreement with the experimental data.Comment: 5 pages. Accepted for A&

An innovative method of extraction of coffee oil using an advanced microwave system: in comparison with conventional Soxhlet extraction method

The production of energy and chemicals from waste biomass is an attractive alternative by comparison with first generation biofuels and fossil feedstocks. This paper investigates oil extraction from spent coffee grounds (SCG) by means of an advanced microwave process and compares this with a conventional Soxhlet extraction (SE) method. Microwave assisted oil extraction (MAE) from SCG was performed over different durations, varying solvent volumes and extraction temperatures. It was found that each of these parameters had an effect on the process, with the largest yield being over 11.54 wt %, oil extracted in 10 minutes using 160 ml of hexane at 95 oC. In 10 minutes, MAE was successful in extracting more oil than SE. MAE achieved a 24 fold decrease in duration for the extraction compared with SE and used less solvent per gram of oil produced. It is proposed that a certain moisture content in the SCG would be beneficial to the extraction process and might it also play a role in the heating process. The extracted oil can be converted into biodiesel and biochemicals leaving the remaining solids suitable for processing into bioethanol, fertiliser, adsorptive material and fuel pellets

The FERRUM project: Transition probabilities for forbidden lines in [FeII] and experimental metastable lifetimes

Accurate transition probabilities for forbidden lines are important diagnostic parameters for low-density astrophysical plasmas. In this paper we present experimental atomic data for forbidden [FeII] transitions that are observed as strong features in astrophysical spectra. Aims: To measure lifetimes for the 3d^6(^3G)4s a ^4G_{11/2} and 3d^6(^3D)4s b ^4D_{1/2} metastable levels in FeII and experimental transition probabilities for the forbidden transitions 3d^7 a ^4F_{7/2,9/2}- 3d^6(^3G)4s a ^4G_{11/2}. Methods: The lifetimes were measured at the ion storage ring facility CRYRING using a laser probing technique. Astrophysical branching fractions were obtained from spectra of Eta Carinae, obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope. The lifetimes and branching fractions were combined to yield absolute transition probabilities. Results: The lifetimes of the a ^4G_{11/2} and the b ^4D_{1/2} levels have been measured and have the following values, 0.75(10) s and 0.54(3) s respectively. Furthermore, we have determined the transition probabilities for two forbidden transitions of a ^4F_{7/2,9/2}- a ^4G_{11/2} at 4243.97 and 4346.85 A. Both the lifetimes and the transition probabilities are compared to calculated values in the literature.Comment: 5 pages, accepted for publication in A&

The deuterium-to-oxygen ratio in the interstellar medium

Because the ionization balances for HI, OI, and DI are locked together by charge exchange, D/O is an important tracer for the value of the D/H ratio and for potential spatial variations in the ratio. As the DI and OI column densities are of similar orders of magnitude for a given sight line, comparisons of the two values will generally be less subject to systematic errors than comparisons of DI and HI, which differ by about five orders of magnitude. Moreover, D/O is additionally sensitive to astration, because as stars destroy deuterium, they should produce oxygen. We report here the results of a survey of D/O in the interstellar medium performed with FUSE. We also compare these results with those for D/N. Together with a few results from previous missions, the sample totals 24 lines of sight. The distances range from a few pc to ~2000 pc and log N(DI) from ~13 to ~16 (cm-2). The D/O ratio is constant in the local interstellar medium out to distances of ~150 pc and N(DI) ~ 1x10^15 cm-2, i.e. within the Local Bubble. In this region of the interstellar space, we find D/O = (3.84+/-0.16)x10^-2 (1 sigma in the mean). The homogeneity of the local D/O measurements shows that the spatial variations in the local D/H and O/H must be extremely small, if any. A comparison of the Local Bubble mean value with the few D/O measurements available for low metallicity quasar sight lines shows that the D/O ratio decreases with cosmic evolution, as expected. Beyond the Local Bubble we detected significant spatial variations in the value of D/O. This likely implies a variation in D/H, as O/H is known to not vary significantly over the distances covered in this study. Our dataset suggests a present-epoch deuterium abundance below 1x10^-5, i.e. lower than the value usually assumed, around 1.5x10^-5.Comment: 17 pages, 9 figures, 4 tables, accepted for publication in the Astrophysical Journa

Mixed configuration-interaction and many-body perturbation theory calculations of energies and oscillator strengths of J=1 odd states of neon

Ab-initio theory is developed for energies of J=1 particle-hole states of neutral neon and for oscillator strengths of transitions from such states to the J=0 ground state. Hole energies of low-Z neonlike ions are evaluated.Comment: 5 pages, 1 figure, 4 table

V453 Oph: a s-process enriched, but carbon-deficient RV Tauri star of low intrinsic metallicity

This paper reports the detection of a heavy element enriched RV Tauri variable with an abundance pattern that differs significantly from a standard s-process enriched object: V453 Oph. Based on optical high-resolution spectra, we determined that this object of low intrinsic metallicity ([Fe/H] = -2.2) has a mild, but significant, enrichment ([s/Fe] ~ +0.5) of heavy elements for which the distribution points to slow neutron capture nucleosynthesis. This result is strengthened by a comparative analysis to the non-enriched RV Tauri star DS Aqr ([s/Fe] = 0.0). Although V453 Oph is the first RV Tauri star showing a strong s-process signature, it is NOT accompanied by C enhancement, challenging our current nucleosynthetic models of post-AGB stars that predict a simultaneous enrichment in C and s-process elements. The low N abundance excludes CN cycling as being responsible for the low C abundance. We explore three different scenarios to explain the heavy element distribution in this evolved object: an enrichment of the parental cloud, an accretion scenario in which the chemical patterns were acquired by mass transfer in a binary system and an intrinsic enrichment by dredge-up.Comment: Accepted for publication in A&