The Influence of Specimen Thickness on the High Temperature Corrosion Behavior of CMSX-4 during Thermal-Cycling Exposure

CMSX-4 is a single-crystalline Ni-base superalloy designed to be used at very high temperatures and high mechanical loadings. Its excellent corrosion resistance is due to external alumina-scale formation, which however can become less protective under thermal-cycling conditions. The metallic substrate in combination with its superficial oxide scale has to be considered as a composite suffering high stresses. Factors like different coefficients of thermal expansion between oxide and substrate during temperature changes or growing stresses affect the integrity of the oxide scale. This must also be strongly influenced by the thickness of the oxide scale and the substrate as well as the ability to relief such stresses, e.g., by creep deformation. In order to quantify these effects, thin-walled specimens of different thickness (t = 100500 lm) were prepared. Discontinuous measurements of their mass changes were carried out under thermal-cycling conditions at a hot dwell temperature of 1100 C up to 300 thermal cycles. Thin-walled specimens revealed a much lower oxide-spallation rate compared to thick-walled specimens, while thinwalled specimens might show a premature depletion of scale-forming elements. In order to determine which of these competetive factor is more detrimental in terms of a component’s lifetime, the degradation by internal precipitation was studied using scanning electron microscopy (SEM) in combination with energy-dispersive X-ray spectroscopy (EDS). Additionally, a recently developed statistical spallation model was applied to experimental data [D. Poquillon and D. Monceau, Oxidation of Metals, 59, 409–431 (2003)]. The model describes the overall mass change by oxide scale spallation during thermal cycling exposure and is a useful simulation tool for oxide scale spallation processes accounting for variations in the specimen geometry. The evolution of the net-mass change vs. the number of thermal cycles seems to be strongly dependent on the sample thickness

Effect of 475 °C embrittlement on the mechanical properties of duplex stainless steel

The binary iron–chromium alloy embrittles in the temperature range of 280–500 °C limiting its applications to temperatures below 280 °C. The embrittlement is caused by the decomposition of the alloy to chromium-rich phase, α′ and iron-rich phase, α. This phenomenon is termed 475 °C embrittlement as the rate of embrittlement is highest at 475 °C. Primarily the investigations on 475 °C embrittlement were confined to binary iron–chromium alloys and ferritic stainless steels. Duplex stainless steel grades contain varying proportions of ferrite and austenite in the microstructure and the ferritic phase is highly alloyed. Moreover, this grade of steel has several variants depending on the alloy composition and processing route. This modifies the precipitation behaviour and the resulting change in mechanical properties in duplex stainless steels when embrittled at 475 °C as compared to binary iron chromium systems. The precipitation behaviour of duplex stainless steel at 475 °C and the effect on tensile, fracture and fatigue behaviour are reviewed in this article

A three-dimensional model for stage I-crack propagation

The propagation of short fatigue cracks is simulated by means of a three-dimensional model. Under loading conditions in the high cycle fatigue regime the growth of these cracks can determine up to 90% of the lifetime of a component. Stage I-cracks often grow on slip bands and exhibit strong interactions with microstructural features such as grain boundaries. Experimental investigations have shown that the crack propagation rate decreases significantly when the crack tip approaches a grain boundary and even a complete stop of crack propagation is possible. In order to consider the real three-dimensional orientation of a slip plane an existing two-dimensional mechanism-based model (Künkler el al., 2008) is extended to simulate the propagation of a three-dimensional surface crack. The crack geometry is modelled using dislocation loops (Hills et al., 1996), which represent the relative displacement between the crack flanks. To describe the propagation of stage Icracks elastic-plastic material behaviour is considered by allowing a plastic deformation due to slip on the active slip plane. The extension of the plastic zone is blocked by the grain boundary. The crack propagation law is based on the range of the crack tip slide displacement, which is obtained from the plastic solution. Behind the grain boundary the shear stress field is evaluated. Results show that a high twist angle between the slip planes causes a significant decrease in the stresses, which can yield a crack stop

Microwave radiometric observations near 19.35, 92 and 183 GHz of precipitation in tropical storm Cora

Observations of rain cells in the remains of a decaying tropical storm were made by Airborne Microwave Radiometers at 19.35,92 and three frequencies near 183 GHz. Extremely low brightness temperatures, as low as 140 K were noted in the 92 and 183 GHz observations. These can be accounted for by the ice often associated with raindrop formation. Further, 183 GHz observations can be interpreted in terms of the height of the ice. The brightness temperatures observed suggest the presence of precipitation sized ice as high as 9 km or more

Rain observations in tropical storm Cora

Passive microwave observations were made in tropical storm Cora at 19.35 and 94GHz. These observations suggest that 94GHz is appropriate for mapping the extent of rain over either land or ocean backgrounds and that some rainfall intensity measurement is also possible

Cassini plasma observations of Saturn's magnetospheric cusp

The magnetospheric cusp is a funnel-shaped region where shocked solar wind plasma is able to enter the high latitude magnetosphere via the process of magnetic reconnection. The plasma observations include various cusp signatures such as ion energy dispersions as well as diamagnetic effects. We present an overview analysis of the cusp plasma observations at the Saturnian magnetosphere from the Cassini spacecraft era. A comparison of the observations is made as well as classification into groups due to varying characteristics. The locations of the reconnection site are calculated and shown to vary along the subsolar magnetopause. We show the first in situ evidence for lobe reconnection that occurred at nearly the same time as dayside reconnection for one of the cusp crossings. Evidence for 'bursty' and more 'continous' reconnection signatures are observed in different cusp events. The events are compared to solar wind propagation models and it is shown that magnetic reconnection and plasma injection into the cusp can occur for a variety of upstream conditions. These are important results because they show that Saturn's magnetospheric interaction with the solar wind and the resulting cusp signatures are dynamic, and that plasma injection in the cusp occurs due to a variety of solar wind conditions. Furthermore, reconnection can proceed at a variety of locations along the magnetopause

Diamagnetic depression observations at Saturn’s magnetospheric cusp by the Cassini spacecraft

The magnetospheric cusp is a region where shocked solar wind plasma can enter a planetary magnetosphere, after magnetic reconnection has occurred at the dayside magnetopause or in the lobes. The dense plasma that enters the high‐latitude magnetosphere creates diamagnetic effects whereby a depression is observed in the magnetic field. We present observations of the cusp events at Saturn’s magnetosphere where these diamagnetic depressions are found. The data are subtracted from a magnetic field model, and the calculated magnetic pressure deficits are compared to the particle pressures. A high plasma pressure layer in the magnetosphere adjacent to the cusp is discovered to also depress the magnetic field, outside of the cusp. This layer is observed to contain energetic He++ (up to ∼100 keV) from the solar wind as well as heavy water group ions (W+) originating from the moon Enceladus. We also find a modest correlation of diamagnetic depression strength to solar wind dynamic pressure and velocity; however, unlike at Earth, there is no correlation found with He++ counts.Key PointsDiamagnetic depressions are found in the cusp and are observed to continue into the adjacent magnetosphereA heated plasma layer of mixed composition is found to depress the adjacent magnetospheric fieldDiamagnetic depression strength is correlated to solar wind dynamic pressure and velocity but not to the observed He++ counts, like at EarthPeer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/137687/1/jgra53517_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/137687/2/jgra53517-sup-0001-supinfo.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/137687/3/jgra53517.pd

Brief International Cognitive Assessment for MS (BICAMS): International Standards for Validation

An international expert consensus committee recently recommended a brief battery of tests for cognitive evaluation in multiple sclerosis. The Brief International Cognitive Assessment for MS (BICAMS) battery includes tests of mental processing speed and memory. Recognizing that resources for validation will vary internationally, the committee identified validation priorities, to facilitate international acceptance of BICAMS. Practical matters pertaining to implementation across different languages and countries were discussed. Five steps to achieve optimal psychometric validation were proposed. In Step 1, test stimuli should be standardized for the target culture or language under consideration. In Step 2, examiner instructions must be standardized and translated, including all information from manuals necessary for administration and interpretation. In Step 3, samples of at least 65 healthy persons should be studied for normalization, matched to patients on demographics such as age, gender and education. The objective of Step 4 is test-retest reliability, which can be investigated in a small sample of MS and/or healthy volunteers over 1–3 weeks. Finally, in Step 5, criterion validity should be established by comparing MS and healthy controls. At this time, preliminary studies are underway in a number of countries as we move forward with this international assessment tool for cognition in MS

Peripheral Nα\alpha Scattering: A Tool For Identifying The Two Pion Exchange Component Of The NN Potential

We study elastic N$\alpha$ scattering and produce a quantitative correlation between the range of the effective potential and the energy of the system. This allows the identification of the waves and energies for which the scattering may be said to be peripheral. We then show that the corresponding phase shifts are sensitive to the tail of the NN potential, which is due to the exchange of two pions. However, the present uncertainties in the experimental phase shifts prevent the use of N$\alpha$ scattering to discriminate the existing models for the NN interaction.Comment: 19 pages, 6 PostScript figures, RevTeX, to be appear in Phys. Rev.