50 research outputs found
Exotic magnetism on the quasi-FCC lattices of the double perovskites LaNaBO (B Ru, Os)
We find evidence for long-range and short-range ( 70 \AA~at 4 K)
incommensurate magnetic order on the quasi-face-centered-cubic (FCC) lattices
of the monoclinic double perovskites LaNaRuO and LaNaOsO
respectively. Incommensurate magnetic order on the FCC lattice has not been
predicted by mean field theory, but may arise via a delicate balance of
inequivalent nearest neighbour and next nearest neighbour exchange
interactions. In the Ru system with long-range order, inelastic neutron
scattering also reveals a spin gap 2.75 meV. Magnetic
anisotropy is generally minimized in the more familiar octahedrally-coordinated
systems, so the large gap observed for LaNaRuO may result from
the significantly enhanced value of spin-orbit coupling in this
material.Comment: 5 pages, 4 figure
Three unique coordination geometries involving 1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene
Reaction of the new ligand 1,2-dimethoxy-4,5-bis(2-pyridylethynyl) benzene with different metal centers under similar reaction conditions led to three distinct structure formation processes: molecular ring closure, dimerization, and polymer formation
Inhomogeneous magnetism in single crystalline SrCuIrO: Implications to phase-separation concepts
The single crystalline form of an insulator, SrCuIrO, is
shown to exhibit unexpectedly more than one magnetic transition (at 5 and 19 K)
with spin-glass-like magnetic susceptibility behaviour. On the basis of this
finding, viz., inhomogeneous magnetism in a chemically homogeneous material, we
propose that the idea of "phase- separation" described for manganites [1] is
more widespread in different ways. The observed experimental features enable us
to make a comparison with the predictions of a recent toy model [2] on {\it
magnetic} phase separation in an insulating environment.Comment: 4 pages, 4 figure