1,543 research outputs found

    Absolute differential cross sections for electron-impact excitation of CO near threshold: II. The Rydberg states of CO

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    Absolute differential cross sections for electron-impact excitation of Rydberg states of CO have been measured from threshold to 3.7 eV above threshold and for scattering angles between 20° and 140°. Measured excitation functions for the b 3Σ+, B 1Σ+ and E 1π states are compared with cross sections calculated by the Schwinger multichannel method. The behaviour of the excitation functions for these states and for the j 3Σ+ and C 1Σ+ states is analysed in terms of negative-ion states. One of these resonances has not been previously reported

    The spin state transition in LaCoO3_{3}; revising a revision

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    Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-L2,3L_{2,3} edge we reveal that the spin state transition in LaCoO3_{3} can be well described by a low-spin ground state and a triply-degenerate high-spin first excited state. From the temperature dependence of the spectral lineshapes we find that LaCoO3_{3} at finite temperatures is an inhomogeneous mixed-spin-state system. Crucial is that the magnetic circular dichroism signal in the paramagnetic state carries a large orbital momentum. This directly shows that the currently accepted low-/intermediate-spin picture is at variance. Parameters derived from these spectroscopies fully explain existing magnetic susceptibility, electron spin resonance and inelastic neutron data

    Thermal Conductivity, Thermopower, and Figure of Merit of La_{1-x}Sr_xCoO_3

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    We present a study of the thermal conductivity k and the thermopower S of single crystals of La_{1-x}Sr_xCoO_3 with 0<= x <= 0.3. For all Sr concentrations La_{1-x}Sr_xCoO_3 has rather low k values, whereas S strongly changes as a function of x. We discuss the influence of the temperature- and the doping-induced spin-state transitions of the Co ions on both, S and k. From S, k, and the electrical resistivity rho we derive the thermoelectric figure of merit Z=S^2/(k*rho). For intermediate Sr concentrations we find notably large values of Z indicating that Co-based materials could be promising candidates for thermoelectric cooling.Comment: 7 pages, 5 figures included, submitted to Phys. Rev.

    Spin-State Transition and Metal-Insulator Transition in La1−x_{1-x}Eux_xCoO3_3}

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    We present a study of the structure, the electric resistivity, the magnetic susceptibility, and the thermal expansion of La1−x_{1-x}Eux_xCoO3_3. LaCoO3_3 shows a temperature-induced spin-state transition around 100 K and a metal-insulator transition around 500 K. Partial substitution of La3+^{3+} by the smaller Eu3+^{3+} causes chemical pressure and leads to a drastic increase of the spin gap from about 190 K in LaCoO3_3 to about 2000 K in EuCoO3_3, so that the spin-state transition is shifted to much higher temperatures. A combined analysis of thermal expansion and susceptibility gives evidence that the spin-state transition has to be attributed to a population of an intermediate-spin state with orbital order for x<0.5x<0.5 and without orbital order for larger xx. In contrast to the spin-state transition, the metal-insulator transition is shifted only moderately to higher temperatures with increasing Eu content, showing that the metal-insulator transition occurs independently from the spin-state distribution of the Co3+^{3+} ions. Around the metal-insulator transition the magnetic susceptibility shows a similar increase for all xx and approaches a doping-independent value around 1000 K indicating that well above the metal-insulator transition the same spin state is approached for all xx.Comment: 10 pages, 6 figure

    Probabilistic retrieval of OCR degraded text using N-grams

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    Worldwide evidence of a unimodal relationship between productivity and plant species richness

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    The search for predictions of species diversity across environmental gradients has challenged ecologists for decades. The humped-back model (HBM) suggests that plant diversity peaks at intermediate productivity; at low productivity few species can tolerate the environmental stresses, and at high productivity a few highly competitive species dominate. Over time the HBM has become increasingly controversial, and recent studies claim to have refuted it. Here, by using data from coordinated surveys conducted throughout grasslands worldwide and comprising a wide range of site productivities, we provide evidence in support of the HBM pattern at both global and regional extents. The relationships described here provide a foundation for further research into the local, landscape, and historical factors that maintain biodiversity
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