PCBs and other organochlorines in BCR reference candidate fish oils

A Report to The Vrije Universiteit, lnstituut voor Milieuvraagstukken Amsterda

Kjemisk analyse av utvalgte aromatiske oljehydrokarboner (NPD) og polyklorerte bifenyler (PCB) i sjøvannsinntaket i Akvariet i Bergen

Prøver for analyse av utvalgte oljehydrokarboner og polyklorerte bifenyler ble tappet fra sjøvannsinntaket til Akvariet i Bergen. Analyse er foretatt ved hjelp av et datastyrt gasskromatograf /massespektrometer system. Analysen viser at det meget små konsentrasjoner av disse komponentene i sjøvannet fra denne lokaliteten. Kvaliteten på vannet må ansees som god

Structural, Mechanical, Electronic and Thermodynamic Analysis of Calcium Aluminum Silicate Crystalline Phases in Stone Wool Insulation Materials: A first-principles study

Stone wool materials have gained considerable attention due to their effectiveness as thermal and acoustic insulation solutions. The comprehension of crystal structure properties is pivotal in determining the overall performance of these materials, as it enables us to optimize their composition for enhanced insulating capabilities. Crucial factors such as structural, mechanical, and thermodynamic characteristics of crystalline phases within stone wool are vital for evaluating its thermal and acoustic insulation properties. This study investigates the properties of calcium aluminum silicate crystal phases commonly present in stone wool, including anorthite, svyatoslavite, scolecite, and dehydrated scolecite using density functional theory (DFT) calculations. In comparison to previous works, this study provides a more comprehensive analysis using advanced DFT calculations. Our analysis reveals the complex interplay between the crystal structures and mechanical behavior of these phases. The calculated bulk modulus of the phases varies significantly, ranging from 38 to 83 GPa. We have compared the calculated elastic properties with available experimental data and found excellent agreement, confirming the accuracy of the computational approach. Moreover, we find that polymorphism has a significant impact on the mechanical strength, with anorthite exhibiting higher strength compared to svyatoslavite. Furthermore, dehydration is found to cause a reduction in unit volume and mechanical strength. The thermodynamic properties of dehydrated scolecite, including entropy and heat capacity, are significantly lower due to the absence of water molecules. These findings highlight the importance of understanding the structural and mechanical characteristics of calcium aluminum silicate phases in stone wool materials. Additionally, our findings have broader implications in various industries requiring effective insulation solutions such as to develop new materials or to enhance the energy efficiency of existing insulating products. © 2023 The Author(s)publishedVersio