The preparation, identification and properties of chlorophyll derivatives

In the investigation of 10-hydroxy chlorophylls a and b novel techniques included modification of chromatography and the use of fully-deuterated compounds isolated from fully-deuterated autotropic algae to determine the molecular structure of the chlorophylls

Qualitative and quantitative analysis of mixtures of compounds containing both hydrogen and deuterium

Method allows qualitative and quantitative analysis of mixtures of partially deuterated compounds. Nuclear magnetic resonance spectroscopy determines location and amount of deuterium in organic compounds but not fully deuterated compounds. Mass spectroscopy can detect fully deuterated species but not the location

On the mass of a Kerr-anti-de Sitter spacetime in D dimensions

We show how to compute the mass of a Kerr-anti-de Sitter spacetime with respect to the anti-de Sitter background in any dimension, using a superpotential which has been derived from standard Noether identities. The calculation takes no account of the source of the curvature and confirms results obtained for black holes via the first law of thermodynamics.Comment: minor changes; accepted by CQ

The spectral-curvature parameter: an alternative tool for the analysis of synchrotron spectra

The so-called Spectral Curvature Parameter(SCP), when plotted versus the high-frequency spectral index ($alpha_{high}$) of synchrotron sources, provides crucial parameters on the continuum spectrum of synchrotron radiation without the more complex modeling of spectral ageing scenarios. An important merit of the SCP-$alpha$ diagram is the enhanced reliability of extracting multiple injection spectra, $alpha_{inj}$. Different from the colour-colour diagram, tracks of different $alpha_{inj}$s, especially when the synchrotron particles are young, exhibit less overlap and less smearing in the SCP-$alpha$ diagram. Three giant radio galaxies(GRGs) and a sample of Compact steep spectrum(CSS) souces are presented. GRGs exhibit asymmetries of their injection spectral indices $alpha_{inj}$ in the SCP-$alpha_{high}$ diagram. The obtained $alpha_{inj}$s and the trends in the sources are cross-checked with the literature and show remarkable confidence. Besides the spectral steepening, spectral flattening is prominent in the radio lobes. The spectral flattening is a clue to efficient re-acceleration processes in the lobes. It implies interaction with the surrounding intergalactic or intra-cluster medium is an important characteristic of GRGs. In the SW lobe of DA240, there is a clear sign of CI and KP/JP bifurcation at the source extremity. This indicates a highly relativistic energy transportation from the core or in situ acceleration in this typical FR I lobe. Our analysis proves, if exists, KP spectra imply the existence of strong $B_{sync}$ field with $B_{sync} > B_{CMB}$. In the CSS sources, our result confirms the CI model and $B_{sync} >> B_{CMB}$. The synchrotron self-absorption is significant in the CSS sample.Comment: to be published in A&

A Comment on Junction and Energy Conditions in Thin Shells

This comment contains a suggestion for a slight modification of Israel's covariant formulation of junction conditions between two spacetimes, placing both sides on equal footing with normals having uniquely defined orientations. The signs of mass energy densities in thin shells at the junction depend not only on the orientations of the normals and it is useful therefore to discuss the sign separately. Calculations gain in clarity by not choosing the orientations in advance. Simple examples illustrate our point and complete previous classifications of spherical thin shells in spherically symmetric spacetimes relevant to cosmology.Comment: (Tex file + PS file with a figure) Tex errors were correcte

Surface critical behavior of driven diffusive systems with open boundaries

Using field theoretic renormalization group methods we study the critical behavior of a driven diffusive system near a boundary perpendicular to the driving force. The boundary acts as a particle reservoir which is necessary to maintain the critical particle density in the bulk. The scaling behavior of correlation and response functions is governed by a new exponent eta_1 which is related to the anomalous scaling dimension of the chemical potential of the boundary. The new exponent and a universal amplitude ratio for the density profile are calculated at first order in epsilon = 5-d. Some of our results are checked by computer simulations.Comment: 10 pages ReVTeX, 6 figures include

Glacial cycles drive variations in the production of oceanic crust

Glacial cycles redistribute water between oceans and continents causing pressure changes in the upper mantle, with consequences for melting of Earth's interior. Using Plio-Pleistocene sea-level variations as a forcing function, theoretical models of mid-ocean ridge dynamics that include melt transport predict temporal variations in crustal thickness of hundreds of meters. New bathymetry from the Australian-Antarctic ridge shows significant spectral energy near the Milankovitch periods of 23, 41, and 100 ky, consistent with model predictions. These results suggest that abyssal hills, one of the most common bathymetric features on Earth, record the magmatic response to changes in sea level. The models and data support a link between glacial cycles at the surface and mantle melting at depth, recorded in the bathymetric fabric of the sea floor.Comment: 30 pages, 6 figures (including supplementary information). Resubmitted to Science on 12 December 201

Mass and angular momenta of Kerr anti-de Sitter spacetimes in Einstein-Gauss-Bonnet theory

We compute the mass and angular momenta of rotating anti-de Sitter spacetimes in Einstein-Gauss-Bonnet theory of gravity using a superpotential derived from standard Noether identities. The calculation relies on the fact that the Einstein and Einstein-Gauss-Bonnet vacuum equations are the same when linearized on maximally symmetric backgrounds and uses the recently discovered D-dimensional Kerr-anti-de Sitter solutions to Einstein's equations

Gravitational energy

Observers at rest in a stationary spacetime flat at infinity can measure small amounts of rest-mass+internal energies+kinetic energies+pressure energy in a small volume of fluid attached to a local inertial frame. The sum of these small amounts is the total "matter energy" for those observers. The total mass-energy minus the matter energy is the binding gravitational energy. Misner, Thorne and Wheeler evaluated the gravitational energy of a spherically symmetric static spacetime. Here we show how to calculate gravitational energy in any static and stationary spacetime for isolated sources with a set of observers at rest. The result of MTW is recovered and we find that electromagnetic and gravitational 3-covariant energy densities in conformastatic spacetimes are of opposite signs. Various examples suggest that gravitational energy is negative in spacetimes with special symmetries or when the energy-momentum tensor satisfies usual energy conditions.Comment: 12 pages. Accepted for publication in Class. Quantum Gra