Metal-Insulator Transition in a Generalized Hubbard Model with Correlated Hopping at Half-Filling

In the present paper metal-insulator transition is studied in a generalized Hubbard model with correlated hopping at half-filling and zero temperature. Single-particle Green function and energy spectrum of electron system are calculated. The expressions for energy gap width and the concentration of polar states (holes or doublons) are obtained. The conditions for metallic and insulating states are found.Comment: 11 pages, 2 eps figures, Latex 2.09, submitted to Phys. Stat. Sol. (B

Differences in the QBO response to stratospheric aerosol modification depending on injection strategy and species

A known adverse side effect of stratospheric aerosol modification (SAM) is the modification of the quasi-biennial oscillation (QBO), which is caused by the stratospheric heating associated with an artificial aerosol layer. Multiple studies found the QBO to slow down or even completely vanish for point-like injections of SO2 at the equator. The cause for this was found to be a modification of the thermal wind balance and a stronger tropical upwelling. For other injection strategies, different responses of the QBO have been observed. It has not yet been presented a theory which is able to explain those differences in a comprehensive manner, which is further complicated by the fact that the simulated QBO response is highly sensitive to the used model even under identical boundary conditions. Therefore, within this study we investigate the response of the QBO to SAM for three different injection strategies (point-like injection at the equator, point-like injection at 30° N and 30° S simultaneously, and areal injection into a 60° wide belt along the equator). Our simulations confirm that the QBO response significantly depends on the injection location. Based on the thermal wind balance, we demonstrate that this dependency is explained by differences in the meridional structure of the aerosol-induced stratospheric warming, i.e. the location and meridional extension of the maximum warming. Additionally, we also tested two different injection species (SO2 and H2SO4). The QBO response is qualitatively similar for both investigated injection species. Comparing the results to corresponding results of a second model, we further demonstrate the generality of our theory as well as the importance of an interactive treatment of stratospheric ozone for the simulated QBO response

Dependency of the impacts of geoengineering on the stratospheric sulfur injection strategy - Part 1: Intercomparison of modal and sectional aerosol modules

Injecting sulfur dioxide into the stratosphere with the intent to create an artificial reflective aerosol layer is one of the most studied options for solar radiation management. Previous modelling studies have shown that stratospheric sulfur injections have the potential to compensate for the greenhouse-gas-induced warming at the global scale. However, there is significant diversity in the modelled radiative forcing from stratospheric aerosols depending on the model and on which strategy is used to inject sulfur into the stratosphere. Until now, it has not been clear how the evolution of the aerosols and their resulting radiative forcing depends on the aerosol microphysical scheme used - that is, if aerosols are represented by a modal or sectional distribution. Here, we have studied different spatio-temporal injection strategies with different injection magnitudes using the aerosolclimate model ECHAM-HAMMOZ with two aerosol microphysical modules: the sectional module SALSA (Sectional Aerosol module for Large Scale Applications) and the modal module M7. We found significant differences in the model responses depending on the aerosol microphysical module used. In a case where SO2 was injected continuously in the equatorial stratosphere, simulations with SALSA produced an 88 %-154% higher all-sky net radiative forcing than simulations with M7 for injection rates from 1 to 100 Tg(S) yr(-1). These large differences are identified to be caused by two main factors. First, the competition between nucleation and condensation: while injected sulfur tends to produce new particles at the expense of gaseous sulfuric acid condensing on pre-existing particles in the SALSA module, most of the gaseous sulfuric acid partitions to particles via condensation at the expense of new particle formation in the M7 module. Thus, the effective radii of stratospheric aerosols were 10 %-52% larger in M7 than in SALSA, depending on the injection rate and strategy. Second, the treatment of the modal size distribution in M7 limits the growth of the accumulation mode which results in a local minimum in the aerosol number size distribution between the accumulation and coarse modes. This local minimum is in the size range where the scattering of solar radiation is most efficient. We also found that different spatial-temporal injection strategies have a significant impact on the magnitude and zonal distribution of radiative forcing. Based on simulations with various injection rates using SALSA, the most efficient studied injection strategy produced a 33 %-42% radiative forcing compared with the least efficient strategy, whereas simulations with M7 showed an even larger difference of 48 %-116 %. Differences in zonal mean radiative forcing were even larger than that. We also show that a consequent stratospheric heating and its impact on the quasi-biennial oscillation depend on both the injection strategy and the aerosol microphysical model. Overall, these results highlight the crucial impact of aerosol microphysics on the physical properties of stratospheric aerosol which, in turn, causes significant uncertainties in estimating the climate impacts of stratospheric sulfur injections

A Working Lexicon for the Tele-Intensive Care Unit: We Need to Define Tele-Intensive Care Unit to Grow and Understand It

Telemedicine in the intensive care unit (Tele-ICU) has grown exponentially since the first formalized program in 2000. Initially, there was limited product choice, and certain capabilities have been engineered into the process with the implication of necessity. New technology is evolving, and new vendors are entering the market place, which should yield a multitude of technologies from which to select. To date, there has been no organized lexicon designed to facilitate communication, comparison, or evaluation. This article is designed as a starting point to develop a lexicon applicable to all technologies for the Tele-ICU with the goal of facilitating clinical comparisons and administrative choices.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/90470/1/tmj-2E2011-2E0045.pd

Initial fate of fine ash and sulfur from large volcanic eruptions

Large volcanic eruptions emit huge amounts of sulfur and fine ash into the stratosphere. These products cause an impact on radiative processes, temperature and wind patterns. In simulations with a General Circulation Model including detailed aerosol microphysics, the relation between the impact of sulfur and fine ash is determined for different eruption strengths and locations, one in the tropics and one in high Northern latitudes. Fine ash with effective radii between 1 μm and 15 μm has a lifetime of several days only. Nevertheless, the strong absorption of shortwave and long-wave radiation causes additional heating and cooling of ±20 K/day and impacts the evolution of the volcanic cloud. Depending on the location of the volcanic eruption, transport direction changes due to the presence of fine ash, vortices develop and temperature anomalies at ground increase. The results show substantial impact on the local scale but only minor impact on the evolution of sulfate in the stratosphere in the month after the simulated eruptions

Cost benefit analysis of various California renewable portfolio standard targets: is a 33% RPS optimal?

Renewable Portfolio Standards (RPSs') require that a certain fraction of the electricity generated for a given region be produced from renewable resources. California's RPS mandates that by 2020, 33% of the electricity sold in the state must be generated from renewables. Such mandates have important implications for the electricity sector as well as for the whole society. In this paper, we estimate the costs and benefits of varying 2020 California RPS targets on electricity prices, greenhouse gas (GHG) emissions, criteria pollutant emissions, the electricity generation mix, the labor market, renewable investment decisions, and social welfare. We have extended the RPS Calculator model, developed by Energy and Environmental Economics (E3) Inc., to account for distributions of fuel and generation costs, to incorporate demand functions, and to estimate the effects of RPS targets on GHG emissions, criteria pollutant emissions, and employment. The results of our modeling provide the following policy insights: (1) the average 2020 electricity price increases as the RPS target rises, with values ranging between $0.152 and$0.175/kWh (2008 dollars) for the 20% RPS to 50% RPS, respectively; (2) the 33% and 50% RPS targets decrease the GHG emissions by about 17.6 and 35.8 million metric tons of carbon dioxide equivalent (MMTCO2e) relative to the 20% RPS; (3) the GHG emission reduction costs of the RPS options are high ($71 to$94 per ton) relative to results from policy options other than RPS or prices that are common in the carbon markets; and (4) a lower target (e.g., a 27% RPS) provides higher social welfare than the 33% RPS (mandate) under low and moderate CO2 social costs (lower than $35/ton); while a higher RPS target (e.g., 50%) is more beneficial when using high CO2 social costs or with rapid renewable technology diffusion. However, under all studied scenarios, the mandated 33% RPS for California would not provide the best cost/benefit values among the possible targets and would not maximize the net social benefit objective

An interactive stratospheric aerosol model intercomparison of solar geoengineering by stratospheric injection of SO2 or accumulation-mode sulfuric acid aerosols

Studies of stratospheric solar geoengineering have tended to focus on modification of the sulfuric acid aerosol layer, and almost all climate model experiments that mechanistically increase the sulfuric acid aerosol burden assume injection of SO2. A key finding from these model studies is that the radiative forcing would increase sublinearly with increasing SO2 injection because most of the added sulfur increases the mass of existing particles, resulting in shorter aerosol residence times and aerosols that are above the optimal size for scattering. Injection of SO3 or H2SO4 from an aircraft in stratospheric flight is expected to produce particles predominantly in the accumulation-mode size range following microphysical processing within an expanding plume, and such injection may result in a smaller average stratospheric particle size, allowing a given injection of sulfur to produce more radiative forcing. We report the first multi-model intercomparison to evaluate this approach, which we label AM-H2SO4 injection. A coordinated multi-model experiment designed to represent this SO3- or H2SO4-driven geoengineering scenario was carried out with three interactive stratospheric aerosol microphysics models: the National Center for Atmospheric Research (NCAR) Community Earth System Model (CESM2) with the Whole Atmosphere Community Climate Model (WACCM) atmospheric configuration, the Max-Planck Institute's middle atmosphere version of ECHAM5 with the HAM microphysical module (MAECHAM5-HAM) and ETH's SOlar Climate Ozone Links with AER microphysics (SOCOL-AER) coordinated as a test-bed experiment within the Geoengineering Model Intercomparison Project (GeoMIP). The intercomparison explores how the injection of new accumulation-mode particles changes the large-scale particle size distribution and thus the overall radiative and dynamical response to stratospheric sulfur injection. Each model used the same injection scenarios testing AM-H2SO4 and SO2 injections at 5 and 25 Tg(S) yr-1 to test linearity and climate response sensitivity. All three models find that AM-H2SO4 injection increases the radiative efficacy, defined as the radiative forcing per unit of sulfur injected, relative to SO2 injection. Increased radiative efficacy means that when compared to the use of SO2 to produce the same radiative forcing, AM-H2SO4 emissions would reduce side effects of sulfuric acid aerosol geoengineering that are proportional to mass burden. The model studies were carried out with two different idealized geographical distributions of injection mass representing deployment scenarios with different objectives, one designed to force mainly the midlatitudes by injecting into two grid points at 30° N and 30° S, and the other designed to maximize aerosol residence time by injecting uniformly in the region between 30° S and 30° N. Analysis of aerosol size distributions in the perturbed stratosphere of the models shows that particle sizes evolve differently in response to concentrated versus dispersed injections depending on the form of the injected sulfur (SO2 gas or AM-H2SO4 particulate) and suggests that prior model results for concentrated injection of SO2 may be strongly dependent on model resolution. Differences among models arise from differences in aerosol formulation and differences in model dynamics, factors whose interplay cannot be easily untangled by this intercomparison. Copyright © 2022 Debra K. Weisenstein et al

A new Geoengineering Model Intercomparison Project (GeoMIP) experiment designed for climate and chemistry models

A new Geoengineering Model Intercomparison Project (GeoMIP) experiment "G4 specified stratospheric aerosols" (short name: G4SSA) is proposed to investigate the impact of stratospheric aerosol geoengineering on atmosphere, chemistry, dynamics, climate, and the environment. In contrast to the earlier G4 GeoMIP experiment, which requires an emission of sulfur dioxide (SO2) into the model, a prescribed aerosol forcing file is provided to the community, to be consistently applied to future model experiments between 2020 and 2100. This stratospheric aerosol distribution, with a total burden of about 2 Tg S has been derived using the ECHAM5-HAM microphysical model, based on a continuous annual tropical emission of 8 Tg SO2 yr−1. A ramp-up of geoengineering in 2020 and a ramp-down in 2070 over a period of 2 years are included in the distribution, while a background aerosol burden should be used for the last 3 decades of the experiment. The performance of this experiment using climate and chemistry models in a multi-model comparison framework will allow us to better understand the impact of geoengineering and its abrupt termination after 50 years in a changing environment. The zonal and monthly mean stratospheric aerosol input data set is available at https://www2.acd.ucar.edu/gcm/geomip-g4-specified-stratospheric-aerosol-data-set

Dependency of the impacts of geoengineering on the stratospheric sulfur injection strategy – Part 2: How changes in the hydrological cycle depend on the injection rate and model used

This is the second of two papers in which we study the dependency of the impacts of stratospheric sulfur injections on the model and injection strategy used. Here, aerosol optical properties from simulated stratospheric aerosol injections using two aerosol models (modal scheme M7 and sectional scheme SALSA), as described in Part 1 (Laakso et al., 2022), are implemented consistently into the EC-Earth, MPI-ESM and CESM Earth system models (ESMs) to simulate the climate impacts of different injection rates ranging from 2 to 100 Tg(S) yr−1. Two sets of simulations were run with the three ESMs: (1) regression simulations, in which an abrupt change in CO2 concentration or stratospheric aerosols over pre-industrial conditions was applied to quantify global mean fast temperature-independent climate responses and quasi-linear dependence on temperature, and (2) equilibrium simulations, in which radiative forcing of aerosol injections with various magnitudes compensated for the corresponding radiative forcing of CO2 enhancement to study the dependence of precipitation on the injection magnitude. The latter also allow one to explore the regional climatic responses. Large differences in SALSA- and M7-simulated radiative forcing in Part 1 translated into large differences in the estimated surface temperature and precipitation changes in ESM simulations; for example, an injection rate of 20 Tg(S) yr−1 in CESM using M7-simulated aerosols led to only 2.2 K global mean cooling, while EC-Earth–SALSA combination produced a 5.2 K change. In equilibrium simulations, where aerosol injections were utilized to offset the radiative forcing caused by an atmospheric CO2 concentration of 500 ppm, the decrease in global mean precipitation varied among models, ranging from −0.7 % to −2.4 % compared with the pre-industrial climate. These precipitation changes can be explained by the fast precipitation response due to radiation changes caused by the stratospheric aerosols and CO2, as the global mean fast precipitation response is shown to be negatively correlated with global mean atmospheric absorption. Our study shows that estimating the impact of stratospheric aerosol injection on climate is not straightforward. This is because the simulated capability of the sulfate layer to reflect solar radiation and absorb long-wave radiation is sensitive to the injection rate as well as the aerosol model used to simulate the aerosol field. These findings emphasize the necessity for precise simulation of aerosol microphysics to accurately estimate the climate impacts of stratospheric sulfur intervention. This study also reveals gaps in our understanding and uncertainties that still exist related to these controversial techniques.</p

Untying a nanoscale knotted polymer structure to linear chains for efficient gene delivery in vitro and to the brain

The purpose of this study was to develop a platform transfection technology, for applications in the brain, which could transfect astrocytes without requiring cell specific functionalization and without the common cause of toxicity through high charge density. Here we show that a simple and scalable preparation technique can be used to produce a “knot” structured cationic polymer, where single growing chains can crosslink together via disulphide intramolecular crosslinks (internal cyclizations). This well-defined knot structure can thus “untie” under reducing conditions, showing a more favorable transfection profile for astrocytes compared to 25 kDa-PEI (48-fold), SuperFect® (39-fold) and Lipofectamine®2000 (18-fold) whilst maintaining neural cell viability at over 80% after four days of culture. The high transfection/lack of toxicity of this knot structured polymer in vitro, combined with its ability to mediate luciferase transgene expression in the adult rat brain, demonstrates its use as a platform transfection technology which should be investigated further for neurodegenerative disease therapies