Vacuum field energy and spontaneous emission in anomalously dispersive cavities

Anomalously dispersive cavities, particularly white light cavities, may have larger bandwidth to finesse ratios than their normally dispersive counterparts. Partly for this reason, their use has been proposed for use in LIGO-like gravity wave detectors and in ring-laser gyroscopes. In this paper we analyze the quantum noise associated with anomalously dispersive cavity modes. The vacuum field energy associated with a particular cavity mode is proportional to the cavity-averaged group velocity of that mode. For anomalously dispersive cavities with group index values between 1 and 0, this means that the total vacuum field energy associated with a particular cavity mode must exceed $\hbar \omega/2$. For white light cavities in particular, the group index approaches zero and the vacuum field energy of a particular spatial mode may be significantly enhanced. We predict enhanced spontaneous emission rates into anomalously dispersive cavity modes and broadened laser linewidths when the linewidth of intracavity emitters is broader than the cavity linewidth.Comment: 9 pages, 4 figure

Laser-controlled fluorescence in two-level systems

The ability to modify the character of fluorescent emission by a laser-controlled, optically nonlinear process has recently been shown theoretically feasible, and several possible applications have already been identified. In operation, a pulse of off-resonant probe laser beam, of sufficient intensity, is applied to a system exhibiting fluorescence, during the interval of excited- state decay following the initial excitation. The result is a rate of decay that can be controllably modified, the associated changes in fluorescence behavior affording new, chemically specific information. In this paper, a two-level emission model is employed in the further analysis of this all-optical process; the results should prove especially relevant to the analysis and imaging of physical systems employing fluorescent markers, these ranging from quantum dots to green fluorescence protein. Expressions are presented for the laser-controlled fluorescence anisotropy exhibited by samples in which the fluorophores are randomly oriented. It is also shown that, in systems with suitably configured electronic levels and symmetry properties, fluorescence emission can be produced from energy levels that would normally decay nonradiatively. © 2010 American Chemical Society

Alligator Feeding Habits: New Data and a Review

Nutria (Myocastor coypus) and muskrats (Ondatra zibethicus) are the predominant food items of alligators over 1.5 min length in southeastern Louisiana. Our data and a review of the literature on alligator diets indicate that the mammals are apparently major components of the diet of large alligators over much of their range, with fishes and crustaceans being more important to smaller alligators

Optimising regionalisation techniques: identifying centres of endemism in the extraordinarily endemic-rich Cape Floristic Region

We used a very large dataset (>40% of all species) from the endemic-rich Cape Floristic Region (CFR) to explore the impact of different weighting techniques, coefficients to calculate similarity among the cells, and clustering approaches on biogeographical regionalisation. The results were used to revise the biogeographical subdivision of the CFR. We show that weighted data (down-weighting widespread species), similarity calculated using Kulczinsky's second measure, and clustering using UPGMA resulted in the optimal classification. This maximized the number of endemic species, the number of centres recognized, and operational geographic units assigned to centres of endemism (CoEs). We developed a dendrogram branch order cut-off (BOC) method to locate the optimal cut-off points on the dendrogram to define candidate clusters. Kulczinsky's second measure dendrograms were combined using consensus, identifying areas of conflict which could be due to biotic element overlap or transitional areas. Post-clustering GIS manipulation substantially enhanced the endemic composition and geographic size of candidate CoEs. Although there was broad spatial congruence with previous phytogeographic studies, our techniques allowed for the recovery of additional phytogeographic detail not previously described for the CFR

Adsorbate site determination with the scanning tunneling microscope: C₂H₄ on Cu{110}

Scanning tunneling microscopy at T=4 K has been used to determine directly the binding site of a molecule chemisorbed on a metal surface, namely, ethene on Cu〈110〉, by simultaneous imaging of the adsorbate and the underlying lattice. The molecule is found to bond in the short bridge site on the close-packed rows with its C-C axis oriented in the 〈110〉 direction

Tip‐induced lifting of the Au{100} (hex)‐phase reconstruction in a low temperature ultrahigh vacuum scanning tunneling microscope

The clean Au{100} surface is known to be reconstructed, forming a pseudohexagonal (5×27) outermost layer. This structure is observed both in ultrahigh vacuum (UHV) and in the electrochemical environment at potentials corresponding to small negative surface electronic charges. Using a UHV scanning tunneling microscope (STM) at 77 K we have observed that the reconstruction can be lifted at large positive sample biases. The 20% less dense bulk‐terminated surface is produced and the excess material appears as irregularly shaped gold clusters. Over a period of a few minutes, however, the surface relaxes back to the pseudo‐hexagonal phase, a process that can also be followed with the STM

Interparticle interactions:Energy potentials, energy transfer, and nanoscale mechanical motion in response to optical radiation

In the interactions between particles of material with slightly different electronic levels, unusually large shifts in the pair potential can result from photoexcitation, and on subsequent electronic excitation transfer. To elicit these phenomena, it is necessary to understand the fundamental differences between a variety of optical properties deriving from dispersion interactions, and processes such as resonance energy transfer that occur under laser irradiance. This helps dispel some confusion in the recent literature. By developing and interpreting the theory at a deeper level, one can anticipate that in suitable systems, light absorption and energy transfer will be accompanied by significant displacements in interparticle separation, leading to nanoscale mechanical motion

Laser-modified one- and two-photon absorption:Expanding the scope of optical nonlinearity

It is shown that conventional one-photon and two-photon absorption processes can be made subject to nonlinear optical control, in each case significantly modifying the efficiency of absorption, through the effect of a secondary, off-resonant stimulus laser beam. The mechanistic origin of these laser-modified absorption processes, in which the stimulus beam emerges unchanged, is traced to higher-order terms in standard perturbation treatments. These normally insignificant terms become unusually prominent when the secondary optical stimulus is moderately intense. Employing a quantum formulation, the effects of the stimulus beam on one-photon and two-photon absorption are analyzed, and calculations are performed to determine the degree of absorption enhancement, and the form of spectral manifestation, under various laser intensities. The implications of differences in selection rules are also considered and exemplified, leading to the identification of dark states that can be populated as a result of laser-modified absorption. Attention is also drawn to the possibility of quantum nondemolition measurements, based on such a form of optical nonlinearity

Quantifying the Benefits of Using Flue Gas Desulfurization Gypsum in Sustainable Wallboard Production

Electric utilities produce more than 11.2 Mt of flue gas desulfurization (FGD) gypsum annually. Approximately 7.5 Mt is used in wallboard production. This article examines the environmental and cost benefits associated with replacement of natural gypsum in wallboard with FGD gypsum. A life-cycle analysis program was used to quantify the benefits of using FGD gypsum from electric power production in wallboard construction. Comparisons were made between energy consumption, water use, and greenhouse gas (GHG) emissions associated with obtaining and processing virgin gypsum material and those with FGD gypsum. The added impact of disposing of the unused FGD gypsum in landfills was also considered using life-cycle inventory for data generated from construction, operation, and maintenance costs for Subtitle D (nonhazardous municipal solid waste) landfills. Based on 2007 consumption data, the use of FGD gypsum in wallboard manufacture and concomitant avoided landfilling of unused FGD gypsum reduced energy consumption by 1200 TJ, water consumption by 18 GL, GHG emissions by 83 kt CO2e, and had a cost savings of $49 to$64 million dollars. The 2007 reduction in energy consumption from using FGD gypsum in wallboard is commensurate with the annual energy use of 11,800 homes, 58% of the annual domestic water use in Nevada, and the removal of 11,400 automobiles from the roadway

Identifying the development in phase and amplitude of dipole and multipole radiation

The spatial variation in phase and the propagating wave-front of plane wave electromagnetic radiation are widely familiar text-book territory. In contrast, the developing amplitude and phase of radiation emitted by a dipole or multipole source generally receive less attention, despite the prevalence of these systems. There is additional complexity in such cases where, in consequence of retardation, the character and features significantly and progressively change as radiation propagates onwards, from the near-field and out towards the wave-zone. Readily developed analytical representations of the electric field, cast as a function of distance from the source, provide illuminating insights into the most prominent and distinctive properties of radiant electromagnetic emission. Graphical implementations and animations of the results prove particularly instructive in revealing the spatial form and temporal evolution of the emergent electromagnetic fields