6,184 research outputs found
Physisorption of positronium on quartz surfaces
The possibility of having positronium (Ps) physisorbed at a material surface
is of great fundamental interest, since it can lead to new insight regarding
quantum sticking and is a necessary first step to try to obtain a Ps
molecule on a material host. Some experiments in the past have produced
evidence for physisorbed Ps on a quartz surface, but firm theoretical support
for such a conclusion was lacking. We present a first-principles
density-functional calculation of the key parameters determining the
interaction potential between Ps and an -quartz surface. We show that
there is indeed a bound state with an energy of 0.14 eV, a value which agrees
very well with the experimental estimate of eV. Further, a brief
energy analysis invoking the Langmuir-Hinshelwood mechanism for the reaction of
physisorbed atoms shows that the formation and desorption of a Ps molecule
in that picture is consistent with the above results.Comment: 5 pages, 3 figures, submitte
Electron beam chemistry produces high purity metals
Application of radiation chemistry for deposition of metals by irradiation of aqueous solutions with high energy electrons is presented. Design of reaction vessel for irradiation of solution is illustrated. Features of radiochemical technique and procedures followed are described
New type of ellipsometry in infrared spectroscopy: The double-reference method
We have developed a conceptually new type of ellipsometry which allows the
determination of the complex refractive index by simultaneously measuring the
unpolarized normal-incidence reflectivity relative to the vacuum and to another
reference media. From these two quantities the complex optical response can be
directly obtained without Kramers-Kronig transformation. Due to its
transparency and large refractive index over a broad range of the spectrum,
from the far-infrared to the soft ultraviolet region, diamond can be ideally
used as a second reference. The experimental arrangement is rather simple
compared to other ellipsometric techniques.Comment: submitted to Appl. Phys. Let
Laser microscopy of tunneling magnetoresistance in manganite grain-boundary junctions
Using low-temperature scanning laser microscopy we directly image electric
transport in a magnetoresistive element, a manganite thin film intersected by a
grain boundary (GB). Imaging at variable temperature allows reconstruction and
comparison of the local resistance vs temperature for both, the manganite film
and the GB. Imaging at low temperature also shows that the GB switches between
different resistive states due to the formation and growth of magnetic domains
along the GB. We observe different types of domain wall growth; in most cases a
domain wall nucleates at one edge of the bridge and then proceeds towards the
other edge.Comment: 5 pages, 4 figures; submitted to Phys. Rev. Let
Use of radiation in preparative chemistry
A summary and updating of previous work on the use of radiation chemistry for the preparation of pure materials are presented. Work was chiefly concerned with the reduction of metal salts in solution to the free metal using 2 MeV electrons. Metals deposited from aqueous solution are copper, silver, zinc, cadmium, thallium, tin, lead, antimony, iron, nickel, cobalt, and palladium. Dry organic solvents were evaluated for the deposition of metals based on a study involving deposition of antimony from soltions of antimony (III) chloride. The use of organic liquids for the preparation of anhydrous metal halides is also presented. Reaction mechanisms for both organic liquids and aqueous system are discussed
Physical Properties and Baryonic Content of Low-Redshift Intergalactic Ly-alpha and O VI Absorption Systems: The PG1116+215 Sight Line
We present HST and FUSE observations of the intergalactic absorption toward
PG1116+215 in the 900-3000 A spectral region. We detect 25 Ly-alpha absorbers
at rest-frame equivalent widths W_r > 30 mA, yielding (dN/dz)_Ly-alpha =
154+/-18 over an unblocked redshift path of 0.162. Two additional weak Ly-alpha
absorbers with W_r ~ 15-20 mA are also present. Eight of the Ly-alpha absorbers
have large line widths (b > 40 km/sec). The detection of narrow OVI in the
broad Ly-alpha absorber at z=0.06244 supports the idea that the Ly-alpha
profile is thermally broadened in gas with T > 10^5 K. We find dN/dz ~ 50 for
broad Ly-alpha absorbers with W_r > 30 mA and b > 40 km/sec. If the broad
Ly-alpha lines are dominated by thermal broadening in hot gas, the amount of
baryonic material in these absorbers is enormous, perhaps as much as half the
baryonic mass in the low-redshift universe. We detect OVI absorption in several
of the Ly-alpha clouds along the sight line. Two detections at z=0.13847 and
z=0.16548 are confirmed by the presence of other ions at these redshifts, while
the detections at z=0.04125, 0.05895, 0.05928, and 0.06244 are based upon the
Ly-alpha and OVI detections alone. The information available for 13
low-redshift OVI absorbers with W_r > 50 mA along 5 sight lines yields
(dN/dz)_OVI ~ 14 and Omega_b(OVI) > 0.0027/h_75, assuming a metallicity of 0.1
solar and an OVI ionization fraction < 0.2. The properties and prevalence of
low-redshift OVI absorbers suggest that they too may be a substantial baryon
repository, perhaps containing as much mass as stars and gas inside galaxies.
The redshifts of the OVI absorbers are highly correlated with the redshifts of
galaxies along the sight line, though few of the absorbers lie closer than
600/h_75 kpc to any single galaxy. [abbreviated]Comment: 99 pages, 30 figures, aastex format, ApJS in pres
Reliability assessment and criticality analysis for Wave Energy Converters
This paper applies existing
reliability methods, namely Reliability Block diagrams, to a notional wave energy converter configuration. It shows possible source of information and difficulties associated with an omnipresent lack of failure rate data.The reliability of wave energy converters (WECs) is a key issue that has to be addressed in order to make them a viable energy option. At this stage of early
industrial development the reliability assessment of WECs is a challenging task. In this paper existing reliability methods, namely Reliability Block diagrams,
have been applied to a notional configuration. It was found that omnipresent lack of failure rate data makes rather crude adjustments of often generic data necessary which generally lead to rather unfavourable
and highly uncertain results. Reliability data is either not available due to sparse field experience or is kept confidential, within different project developments to
secure competitive advantages and intellectual property.
In order to foster the progress of the marine energy industry, the reliability of devices must be demonstrated and improved. This requires a joint effort between industry stakeholders to collect, share and
disseminate existing failure knowledge and future operational experience.Engineering and Physical
Sciences Research Council (EPSRC) under the
SUPERGEN Marine Doctoral Programm
Testing spontaneous localization theories with matter-wave interferometry
We propose to test the theory of continuous spontaneous localization (CSL) in
an all-optical time-domain Talbot-Lau interferometer for clusters with masses
exceeding 1000000 amu. By assessing the relevant environmental decoherence
mechanisms, as well as the growing size of the particles relative to the
grating fringes, we argue that it will be feasible to test the quantum
superposition principle in a mass range excluded by recent estimates of the CSL
effect.Comment: 4 pages, 3 figures; corresponds to published versio
Is it a showstopper? Reliability assessment and criticality analysis for Wave Energy Converters
The reliability of wave energy converters (WECs) is a key issue that has to be addressed in order to make them a viable energy option. At this stage of early industrial development the reliability assessment of WECs is a challenging task. In this paper existing reliability methods, namely Reliability Block diagrams, have been applied to a notional configuration. It was found that omnipresent lack of failure rate data makes rather crude adjustments of often generic data necessary which generally lead to rather unfavourable and highly uncertain results. Reliability data is either not available due to sparse field experience or is kept confidential, within different project developments to secure competitive advantages and intellectual property. In order to foster the progress of the marine energy industry, the reliability of devices must be demonstrated and improved. This requires a joint effort between industry stakeholders to collect, share and disseminate existing failure knowledge and future operational experience
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