Radiative return at NLO and the measurement of the hadronic cross-section in electron-positron annihilation

Electron-positron annihilation into hadrons plus an energetic photon from initial state radiation allows the hadronic cross-section to be measured over a wide range of energies. The full next-to-leading order QED corrections for the cross-section for e^+ e^- annihilation into a real tagged photon and a virtual photon converting into hadrons are calculated where the tagged photon is radiated off the initial electron or positron. This includes virtual and soft photon corrections to the process e^+ e^- \to \gamma +\gamma^* and the emission of two real hard photons: e^+ e^- \to \gamma + \gamma + \gamma^*. A Monte Carlo generator has been constructed, which incorporates these corrections and simulates the production of two charged pions or muons plus one or two photons. Predictions are presented for centre-of-mass energies between 1 and 10 GeV, corresponding to the energies of DAPHNE, CLEO-C and B-meson factories.Comment: 13 pages, 15 figure

Two-photon contributions to the Rosenbluth cross-section in the Skyrme model

We study two-photon contributions to the elastic electron nucleon scattering within the Skyrme model. In particular we focus on the role of the anomaly that enters via the Wess-Zumino term and explain how this induces an axial current interaction.Comment: 19pages, 10 figures, revtex4, version to be published in Eur. Phys. J.

Nonproductive Events in Ring-Closing Metathesis Using Ruthenium Catalysts

The relative TONs of productive and nonproductive metathesis reactions of diethyl diallylmalonate are compared for eight different ruthenium-based catalysts. Nonproductive cross metathesis is proposed to involve a chain-carrying ruthenium methylidene. A second more-challenging substrate (dimethyl allylmethylallylmalonate) that forms a trisubstituted olefin product is used to further delineate the effect of catalyst structure on the relative efficiencies of these processes. A steric model is proposed to explain the observed trends

Electroweak Sudakov Logarithms and Real Gauge-Boson Radiation in the TeV Region

Electroweak radiative corrections give rise to large negative, double-logarithmically enhanced corrections in the TeV region. These are partly compensated by real radiation and, moreover, affected by selecting isospin-noninvariant external states. We investigate the impact of real gauge boson radiation more quantitatively by considering different restricted final state configurations. We consider successively a massive abelian gauge theory, a spontaneously broken SU(2) theory and the electroweak Standard Model. We find that details of the choice of the phase space cuts, in particular whether a fraction of collinear and soft radiation is included, have a strong impact on the relative amount of real and virtual corrections.Comment: 20 pages, 4 figure

Hypoconstrained Jammed Packings of Nonspherical Hard Particles: Ellipses and Ellipsoids

Continuing on recent computational and experimental work on jammed packings of hard ellipsoids [Donev et al., Science, vol. 303, 990-993] we consider jamming in packings of smooth strictly convex nonspherical hard particles. We explain why the isocounting conjecture, which states that for large disordered jammed packings the average contact number per particle is twice the number of degrees of freedom per particle (\bar{Z}=2d_{f}), does not apply to nonspherical particles. We develop first- and second-order conditions for jamming, and demonstrate that packings of nonspherical particles can be jammed even though they are hypoconstrained (\bar{Z}<2d_{f}). We apply an algorithm using these conditions to computer-generated hypoconstrained ellipsoid and ellipse packings and demonstrate that our algorithm does produce jammed packings, even close to the sphere point. We also consider packings that are nearly jammed and draw connections to packings of deformable (but stiff) particles. Finally, we consider the jamming conditions for nearly spherical particles and explain quantitatively the behavior we observe in the vicinity of the sphere point.Comment: 33 pages, third revisio

Tripartite Graph Clustering for Dynamic Sentiment Analysis on Social Media

The growing popularity of social media (e.g, Twitter) allows users to easily share information with each other and influence others by expressing their own sentiments on various subjects. In this work, we propose an unsupervised \emph{tri-clustering} framework, which analyzes both user-level and tweet-level sentiments through co-clustering of a tripartite graph. A compelling feature of the proposed framework is that the quality of sentiment clustering of tweets, users, and features can be mutually improved by joint clustering. We further investigate the evolution of user-level sentiments and latent feature vectors in an online framework and devise an efficient online algorithm to sequentially update the clustering of tweets, users and features with newly arrived data. The online framework not only provides better quality of both dynamic user-level and tweet-level sentiment analysis, but also improves the computational and storage efficiency. We verified the effectiveness and efficiency of the proposed approaches on the November 2012 California ballot Twitter data.Comment: A short version is in Proceeding of the 2014 ACM SIGMOD International Conference on Management of dat

A Facile Preparation of Imidazolinium Chlorides

A process for the preparation of symmetric and unsymmetric imidazolinium chlorides that involves reaction of a formamidine with dichloroethane and a base (a) is described. This method makes it possible to obtain numerous imidazolinium chlorides under solvent-free reaction conditions and in excellent yields with purification by simple filtration. Alternatively, symmetric imidazolinium chlorides can be prepared directly in moderate yields from substituted anilines by utilizing half of the formamidine intermediate as sacrificial base (b)

Chandra Spectroscopy Of The Hot Star β Crucis And The Discovery Of A Pre-Main-Sequence Companion

In order to test the O star wind-shock scenario for X-ray production in less luminous stars with weaker winds, we made a pointed 74-ks observation of the nearby early B giant, beta Crucis (beta Cru; B0.5 III), with the Chandra High Energy Transmission Grating Spectrometer. We find that the X-ray spectrum is quite soft, with a dominant thermal component near 3 million K, and that the emission lines are resolved but quite narrow, with half widths of 150 km s(-1). The forbidden-to-intercombination line ratios of Ne IX and Mg XI indicate that the hot plasma is distributed in the wind, rather than confined near the photosphere. It is difficult to understand the X-ray data in the context of the standard wind-shock paradigm for OB stars, primarily because of the narrow lines, but also because of the high X-ray production efficiency. A scenario in which the bulk of the outer wind is shock heated is broadly consistent with the data, but not very well motivated theoretically. It is possible that magnetic channelling could explain the X-ray properties, although no field has been detected on beta Cru. We detected periodic variability in the hard (h nu \u3e 1 keV) X-rays, modulated on the known optical period of 4.58 h, which is the period of the primary beta Cephei pulsation mode for this star. We also have detected, for the first time, an apparent companion to beta Cru at a projected separation of 4 arcsec. This companion was likely never seen in optical images because of the presumed very high contrast between it and beta Cru in the optical. However, the brightness contrast in the X-ray is only 3:1, which is consistent with the companion being an X-ray active low-mass pre-main-sequence star. The companion\u27s X-ray spectrum is relatively hard and variable, as would be expected from a post-T Tauri star. The age of the beta Cru system (between 8 and 10 Myr) is consistent with this interpretation which, if correct, would add beta Cru to the roster of Lindroos binaries - B stars with low-mass pre-main-sequence companions

Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis

series of ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene (NHC) ligands with varying degrees of backbone and N-aryl substitution have been prepared. These complexes show greater resistance to decomposition through C−H activation of the N-aryl group, resulting in increased catalyst lifetimes. This work has utilized robotic technology to examine the activity and stability of each catalyst in metathesis, providing insights into the relationship between ligand architecture and enhanced efficiency. The development of this robotic methodology has also shown that, under optimized conditions, catalyst loadings as low as 25 ppm can lead to 100% conversion in the ring-closing metathesis of diethyl diallylmalonate