204 research outputs found
Electron spin resonance study of thermal instability reactions in jet fuels
Free radicals were studied by electron spin resonance (ESR) using model compounds that are representative of constituents of jet fuels. Radical formation was initiated with peroxides and hydroperoxides by using UV photolysis at and near room temperature and thermal initiation at higher temperatures. Both oxygen free and air saturated systems were studied. N-Dodecane was frequently used as a solvent, and a mixture of n-dodecyl radicals was made with a peroxide initiator in n-dodecane (free of oxygen) thermally at 212 C and photolytically at room temperature. Hydrogen abstraction from the 3,4,5 and 6-positions gives radicals that are sufficiently alike that their spectra are essentially superimposed. The radical formed by abstract of hydrogen from the 2-position gives a different spectrum. ESR parameters for these radicals were measured. The radical formed by abstraction of a primary hydrogen was not observed. Similar radicals are formed from n-decane. A variety of exploratory experiments were carried out with systems that give free radical spectra to which was added small amounts of 2,5-dimethylpyrrole
Proton drip-line nuclei in relativistic mean-field theory
The position of the two-proton drip line has been calculated for even-even
nuclei with in the framework of the relativistic mean-field
(RMF) theory. The current model uses the NL3 effective interaction in the
mean-field Lagrangian and describes pairing correlations in the
Bardeen-Cooper-Schrieffer (BCS) formalism. The predictions of the RMF theory
are compared with those of the Hartree-Fock+BCS approach (with effective force
Skyrme SIII) and the finite-range droplet model (FRDM) and with the available
experimental information.Comment: 18 pages, RevTeX, 2 p.s figures, to appear in Phys. Rev.
PRIVATE SAVINGS IN TRANSITION ECONOMIES: ARE THERE TERMS OF TRADE SHOCKS?
The paper examines the impact of terms of trade shocks on private savings in the transition economies after accounting for the effect of other determinants. Economic agents in the transition economies are subject to tight credit constraints which are more pronounced during bad state of nature. Thus, adverse shocks to commodity prices in the world market can force them to reduce savings by a larger amount than they would otherwise have. Empirical analysis using a dynamic panel model and data from twenty one transition economies confirm that most of the determinants of savings identified in the literature also apply to the transition economies. Favorable movements in both the permanent and transitory components of the terms of trade have a significant positive impact on private savings with transitory movements having a larger impact than the permanent component. This reflects the lack of access to foreign borrowing that many of the transition economies have faced during the last decade. Although the impact of terms of trade shocks are found to be asymmetric, the magnitude of the impact appears to be small. The results are robust for alternative estimators, determinants, and country groupings.http://deepblue.lib.umich.edu/bitstream/2027.42/39958/3/wp572.pd
An Algebraic Pairing Model with Sp(4) Symmetry and its Deformation
A fermion realization of the compact symplectic sp(4) algebra provides a
natural framework for studying isovector pairing correlations in nuclei. While
these correlations manifest themselves most clearly in the binding energies of
0^+ ground states, they also have a large effect on the energies of excited
states, including especially excited 0^+ states. In this article we consider
non-deformed as well as deformed algebraic descriptions of pairing through the
reductions of sp_{(q)}(4) to different realizations of u_{(q)}(2) for single-j
and multi-j orbitals. The model yields a classification scheme for completely
paired 0^{+} states of even-even and odd-odd nuclei in the 1d_{3/2}, 1f_{7/2},
and 1f_{5/2}2p_{1/2}2p_{3/2}1g_{9/2} shells. Phenomenological non-deformed and
deformed isospin-breaking Hamiltonians are expressed in terms of the generators
of the dynamical symmetry groups Sp(4) and Sp_{q}(4). These Hamiltonians are
related to the most general microscopic pairing problem, including isovector
pairing and isoscalar proton-neutron interaction along with non-linear
interaction in the deformed extension. In both the non-deformed and deformed
cases the eigenvalues of the Hamiltonian are fit to the relevant Coulomb
corrected experimental 0^{+} energies and this, in turn, allows us to estimate
the interaction strength parameters, to investigate isovector-pairing
properties and symmetries breaking, and to predict the corresponding energies.
While the non-deformed theory yields results that are comparable to other
theories for light nuclei, the deformed extension, which takes into account
higher-order interactions between the particles, gives a better fit to the
data. The multi-shell applications of the model provide for reasonable
predictions of energies of exotic nuclei.Comment: 19 pages, 5 figures minor changes; improvements to achieve a better
and clearer presentation of our messages and idea
Experimental evidence for 56Ni-core breaking from the low-spin structure of the N=Z nucleus 58Cu
Low-spin states in the odd-odd N=Z nucleus 58Cu were investigated with the
58Ni(p,n gamma)58Cu fusion evaporation reaction at the FN-tandem accelerator in
Cologne. Seventeen low spin states below 3.6 MeV and 17 new transitions were
observed. Ten multipole mixing ratios and 17 gamma-branching ratios were
determined for the first time. New detailed spectroscopic information on the
2+,2 state, the Isobaric Analogue State (IAS) of the 2+,1,T=1 state of 58Ni,
makes 58Cu the heaviest odd-odd N=Z nucleus with known B(E2;2+,T=1 --> 0+,T=1)
value. The 4^+ state at 2.751 MeV, observed here for the first time, is
identified as the IAS of the 4+,1,T=1 state in 58Ni. The new data are compared
to full pf-shell model calculations with the novel GXPF1 residual interaction
and to calculations within a pf5/2 configurational space with a residual
surface delta interaction. The role of the 56Ni core excitations for the
low-spin structure in 58Cu is discussed.Comment: 15 pages, 7 figures, submitted to Phys. Rev.
Pairing in nuclear systems: from neutron stars to finite nuclei
We discuss several pairing-related phenomena in nuclear systems, ranging from
superfluidity in neutron stars to the gradual breaking of pairs in finite
nuclei. We focus on the links between many-body pairing as it evolves from the
underlying nucleon-nucleon interaction and the eventual experimental and
theoretical manifestations of superfluidity in infinite nuclear matter and of
pairing in finite nuclei. We analyse the nature of pair correlations in nuclei
and their potential impact on nuclear structure experiments. We also describe
recent experimental evidence that points to a relation between pairing and
phase transitions (or transformations) in finite nuclear systems. Finally, we
discuss recent investigations of ground-state properties of random two-body
interactions where pairing plays little role although the interactions yield
interesting nuclear properties such as 0+ ground states in even-even nuclei.Comment: 74 pages, 33 figs, uses revtex4. Submitted to Reviews of Modern
Physic
Paying to Save: Tax Withholding and Asset Allocation among Low- and Moderate-Income Taxpayers
Estimating the Effect of Student Aid on College Enrollment: Evidence from a Government Grant Policy Reform
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