Analysis of Organophosphorus Compounds. 1. Application of Iodine-Azide Reaction for Detection of Thiophosphoorganic Compounds in Thin-Layer Chromatography

Wydrukowano z dostarczonych Wydawnictwu UŁ gotowych materiałówZadanie pt. Digitalizacja i udostępnienie w Cyfrowym Repozytorium Uniwersytetu Łódzkiego kolekcji czasopism naukowych wydawanych przez Uniwersytet Łódzki nr 885/P-DUN/2014 zostało dofinansowane ze środków MNiSW w ramach działalności upowszechniającej naukę

Draft genome sequence of MCPA-degrading <i>Sphingomonas </i>sp. strain ERG5, isolated from a groundwater aquifer in Denmark

Sphingomonas sp. strain ERG5 was isolated from a bacterial community, originating from a groundwater aquifer polluted with low pesticide concentrations. This bacterium degrades 2-methyl-4-chlorophenoxyacetic acid (MCPA) in a wide spectrum of concentrations and has been shown to function in bioaugmented sand filters. Genes associated with MCPA degradation are situated on a putative conjugative plasmid

Ultra high purity, dimensionally stable INVAR 36

An INVAR 36 material having long-term dimensional stability is produced by sintering a blend of powders of nickel and iron under pressure in an inert atmosphere to form an alloy containing less than 0.01 parts of carbon and less than 0.1 part aggregate and preferably 0.01 part individually of Mn, Si, P, S and Al impurities. The sintered alloy is heat treated and slowly and uniformly cooled to form a material having a coefficient of thermal expansion of less than 1 ppm/C and a temporal stability of less than 1 ppm/year

Lipid-induced changes in the secondary structure of snake venom cardiotoxins.

The secondary structures of three snake venom cardiotoxins (from Hemachatus hemachatus, Naja naja atra, and Naja naja naja), in aqueous solution and in a lipid-bound form, were investigated by Fourier-transform infrared spectroscopy. The conformation-sensitive protein infrared bands in the amide I region were analyzed using deconvolution and band-fitting procedures. The spectra of the three cardiotoxins in aqueous buffer are very similar; they indicate a high content of both antiparallel beta-sheet structure and unordered conformation. Moreover, component bands characteristic of turns can also be identified. The binding of cardiotoxins to bilayers of dimyristoylphosphatidyl-glycerol results in an increased content of a beta-structure at the expense of the nonordered conformation. It is suggested that lipid-induced conformational transitions to a beta-structure, similar to that observed with cardiotoxins, may be operative also in membrane interaction of other proteins and peptides, particularly with those which have a small tendency to form alpha-helices

Morphological control of heteroleptic cis- and trans-Pd2L2Lʹ2 cages

Control over the integrative self-sorting of metallo-supramolecular assemblies has recently generated significant interest as it opens up possibilities of introducing increased complexity and function into a single self-assembled architecture. Here, the relationship between the geometry of three ligand components and morphology of three self-sorted heteroleptic [Pd2L2Lʹ2]4+ cages is examined. Pd-mediated assembly of two bis-monodentate pyridyl ligands with native bite angles of 75° and 120° affords a cis-[Pd2L2Lʹ2]4+ cage while the same reaction with two ligands bearing bite angles of 75° and 60° forces an anti-conformation for latter ligand, leading to an unprecedented, self-penetrating structural motif; a trans-[Pd2(anti-L)2Lʹ2]4+ heteroleptic cage bearing a “doubly-bridged figure-eight” topology. Each heteroleptic assembly can be accessed through cage-to-cage conversion of their homoleptic precursors, and notably, morphological control of [Pd2L2Lʹ2] cages is achieved through selective ligand displacement transformations in a system of three ligands and at least six possible cage products

Draft Genome Sequence of Se(IV)-Reducing Bacterium Pseudomonas migulae ES3-33

Pseudomonas migulae ES3-33 is a Gram-negative strain that strongly reduces Se(IV) and was isolated from a selenium mining area in Enshi, southwest China. Here we present the draft genome of this strain containing potential genes involved in selenite reduction and a large number of genes encoding resistances to copper and antibiotics

Towards the Secondary Bar: Gas Morphology and Dynamics in NGC 4303

The bulk of the molecular line emission in the double barred galaxy NGC4303 as observed in its CO(1-0) line with the OVRO mm-interferometer comes from two straight gas lanes which run north-south along the leading sides of the large-scale primary bar. Inside a radius of ~ 400 pc the molecular gas forms a spiral pattern which, for the northern arm, can be traced to the nucleus. Comparison of the OVRO and archival HST data with dynamical models of gas flow in the inner kiloparsec of single- and double-barred galaxies shows that the observed global properties of the molecular gas are in agreement with models for the gas flow in a strong, large-scale bar, and the two-arm spiral structure seen in CO in the inner kiloparsec can already be explained by a density wave initiated by the potential of that bar. Only a weak correlation between the molecular gas distribution and the extinction seen in the HST V-H map is found in the inner 400 pc of NGC4303: The innermost part of one arm of the nuclear CO spiral correlates with a weak dust filament in the color map, while the overall dust distribution follows a ring or single-arm spiral pattern well correlated with the UV continuum. This complicated nuclear geometry of the stellar and gaseous components allows for two scenarios: (A) A self-gravitating m=1 mode is present forming the spiral structure seen in the UV continuum. In this case the gas kinematics would be unaffected by the small (~ 4'') inner bar. (B) The UV continuum traces a complete ring which is heavily extincted north of the nucleus. Such a ring forms in hydrodynamic models of double bars, but the models cannot account for the UV emission observed on the leading side of the inner bar. (abridged)Comment: 47 pages, 14 figures, accepted for publication in Ap