Fair chances and hard work? Families making sense of inequality and opportunity in 21st-century Britain

© London School of Economics and Political Science 2018. In British social mobility discourse, the rhetoric of fair access can obscure wider issues of social justice. While socio-economic inequalities continue to shape young people's lives, sociological work on class dis-identification suggests social class is less obviously meaningful as a source of individual and collective identity. This paper considers subjective understandings of the post-16 education and employment landscape in this context, drawing on qualitative research exploring the aspirations of young men and women as they completed compulsory education in north-west England, and the hopes their parents had for their future. It shows how unequal access to resources shaped the older generation's expectations for their children, although this was rarely articulated using the explicit language of class. Their children recognized they faced a difficult job market but embraced the idea that success was possible through hard work. Both generations drew moral boundaries and made judgments based on implicit classed discourses about undeserving others, while at the same time disavowing class identities. There was a more explicit recognition of gender inequality among the parents framed with reference to hopes for greater freedom for their daughters. Opportunities and inequalities were thus understood in complex and sometimes contradictory ways

Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes to their fully halogenated species. The results reveal a stepwise mechanism with time scales varying from hundreds of picoseconds to nanoseconds. The dynamics are significantly faster when the structure is retained but becomes rate-limited when the octahedral-to-tetrahedral structural change bottlenecks the transformation. Evidence is presented, from bimolecular kinetics and energetics (enthalpic and entropic), for a reaction in which the ligand assists the displacement of water molecules, with the retention of the entering ligand in the activated state. The reaction time scale deviates by one to two orders of magnitude from that of ionic diffusion, suggesting the involvement of a collisional barrier between the ion and the much larger complex

Making Ethical Decisions in an Online context: Reflections on using blogs to explore narratives of experience

Internet research methods can present some challenging ethical dilemmas. Although they are subject to the same guiding principles as ‘offline’ research, it can be difficult to apply these online given the blurring of boundaries presented by digitally-mediated environments. This paper considers a study that utilised personal blogs as primary data to outline two common ethical tensions in internet research: whether online communications can be considered public or private, and whether the people who produce them can be considered subjects or authors. The study examined the narratives of young people who took gap years overseas as represented in their travel blogs. While the blogs were technically public, they contained personal information, and individual perceptions or expectations of privacy can be different. The paper also explores how to establish if human subjects are involved in internet research, including the difficulties of protecting identity and the case for recognising authorship when appropriate. In line with contemporary scholarship on internet research ethics, this paper highlights the need for a contextual approach that recognises the specificities of the communications studied, the methods employed to generate and analyse data, and how the research is disseminated. The decisions made in the gap year study are critically evaluated, and alternative options presented, including a focus on ensuring that data are not linked to individuals without consent. The article aims to contribute to dialogue and debate in online research ethics through offering some reflections on the course of action taken

Framing the Other: cosmopolitanism and the representation of difference in overseas gap year narratives

This paper engages with debates surrounding contemporary cosmopolitanism and the outcomes of cultural encounters. It considers if overseas gap years, often put forward in the UK as a way of becoming a global citizen, enable young Britons to ‘broaden their mind’. I explore representations of the people and places encountered during these periods of time out through an analysis of young people’s travel blogs. Four key themes are highlighted in these narratives: the exotic place; feeling ‘out of place’; the importance and outcomes of local interaction; and the historical legacies that are implicated in constructing places as ‘different’. Gappers display a willingness to interact with and gain knowledge about their host communities. Yet as gap years are designed to be distinct from the normal course of things, they also demonstrate the ‘difference’ of places. This can often result in the reproduction of established ways of representing the Other in order to frame them as meaningful. There is a tension in the narratives between ‘globally reflexive’ and ‘globally reproductive’ representations of difference, and I suggest that we might question the development of cosmopolitan attitudes and competencies through undertaking a gap year

Taking the next step: class, resources and educational choice across the generations

Most young people in the UK now stay on in education or training when they finish school. Numbers will continue to increase following the implementation of raising the participation age. Despite an upward trend in further education participation, young people's pathways continue to be shaped by class and gender. This paper explores the choices and decisions made by young people in their final year of compulsory schooling and describes how these class and gender inequalities are reproduced. We also spoke to parents about their own trajectories and their involvement in guiding their children's next steps. Our concern is with young people in ‘the middle’: not most at risk of social exclusion, but certainly not the most privileged. The decisions at this key transitional point are socially embedded. Processes of class reproduction and class mobility are dependent upon both structural context and access to advantageous resources. The opportunity structures for our participants were very different for the two generations. We note the wider role that social resources play at this moment, and the classed differences between the children of parents who had experienced some upward mobility and those who had remained in working-class positions

What e-patients want from the doctor-patient relationship: content analysis of posts on discussion boards.

People with long-term conditions are encouraged to take control and ownership of managing their condition. Interactions between health care staff and patients become partnerships with sharing of expertise. This has changed the doctor-patient relationship and the division of roles and responsibilities that traditionally existed, but what each party expects from the other may not always be clear. Information that people with long-term conditions share on Internet discussion boards can provide useful insights into their expectations of health care staff. This paper reports on a small study about the expectations that people with a long-term condition (diabetes) have of their doctors using information gleaned from Internet discussion boards

Recent experience in the fabrication and brazing of ceramic beam tubes for kicker magnets at FNAL

Ceramic beam tubes are utilized in numerous kicker magnets in different accelerator rings at Fermi National Accelerator Laboratory. Kovar flanges are brazed onto each beam tube end, since kovar and high alumina ceramic have similar expansion curves. The tube, kovar flange, end piece, and braze foil (titanium/incusil) alloy brazing material are stacked in the furnace and then brazed in the furnace at 1000 C. The ceramic specified is 99.8% Alumina, Al{sub 2}O{sub 3}, a strong recrystallized high-alumina fabricated by slip casting. Recent experience at Fermilab with the fabrication and brazing of these tubes has brought to light numerous problems including tube breakage and cracking and also the difficulty of brazing the tube to produce a leak-tight joint. These problems may be due to the ceramic quality, voids in the ceramic, thinness of the wall, and micro-cracks in the ends which make it difficult to braze because it cannot fill tiny surface cracks which are caused by grain pullout during the cutting process. Solutions which are being investigated include lapping the ends of the tubes before brazing to eliminate the micro-cracks and also metallization of the tubes

Femtosecond infrared studies of ligand rearrangement reactions: silyl hydride products from Group 6 carbonyls

Abstract The ultrafast dynamics of the Si H bond activation reaction by the Group 6 d 6 organometallic compounds M(CO) 5 (M=Cr, Mo, and W) have been studied in neat tri-substituted silanes under ambient conditions. The ultrafast spectral evolutions of the CO stretching bands were monitored following UV photolysis using femtosecond pump -probe spectroscopic methods. It was found that the coordinatively unsaturated species, which is formed following CO photolysis from the parent molecule, is quickly solvated ( B 2 ps) via the C H bonds of the solvent. These species then rearranged to the silyl hydride product on a timescale of a few nanoseconds. These results were augmented by rearrangement studies in neat ethanol, propanol and hexanol solutions in which the initially formed metal C H complex rearranged to the metal hydroxyl complex. The mechanism of this rearrangement was discussed by comparison of the data with various models in the literature. It was found that a mechanism that is primarily dissociative in nature provided the best description of the experimental data

A Tentative Modeling Study of the Effect of Wall Reactions on Oxidation Phenomena

This paper gives details of a tentative modeling study that investigates the inhibiting effect of internal reactor walls treated with acid..