85 research outputs found
Confined colloidal crystals in and out of equilibrium
Recent studies on confined crystals of charged colloidal particles are
reviewed, both in equilibrium and out of equilibrium. We focus in particular on
direct comparisons of experiments (light scattering and microscopy) with
lattice sum calculations and computer simulations. In equilibrium we address
buckling and crystalline multilayering of charged systems in hard and soft slit
confinement. We discuss also recent crystalline structures obtained for charged
mixtures. Moreover, we put forward possibilities to apply external
perturbations, in order to drive the system out of equilibrium. These include
electrolyte gradients as well as the application of shear and electric fields.Comment: Review article, 18 pages, 5 figure
Non-equilibrium melting of colloidal crystals in confinement
We report on a novel and flexible experiment to investigate the
non-equilibrium melting behaviour of model crystals made from charged colloidal
spheres. In a slit geometry polycrystalline material formed in a low salt
region is driven by hydrostatic pressure up an evolving gradient in salt
concentration and melts at large salt concentration. Depending on particle and
initial salt concentration, driving velocity and the local salt concentration
complex morphologic evolution is observed. Crystal-melt interface positions and
the melting velocity are obtained quantitatively from time resolved Bragg- and
polarization microscopic measurements. A simple theoretical model predicts the
interface to first advance, then for balanced drift and melting velocities to
become stationary at a salt concentration larger than the equilibrium melting
concentration. It also describes the relaxation of the interface to its
equilibrium position in a stationary gradient after stopping the drive in
different manners. We further discuss the influence of the gradient strength on
the resulting interface morphology and a shear induced morphologic transition
from polycrystalline to oriented single crystalline material before melting
Crystallization in suspensions of hard spheres: A Monte Carlo and Molecular Dynamics simulation study
The crystallization of a metastable melt is one of the most important non
equilibrium phenomena in condensed matter physics, and hard sphere colloidal
model systems have been used for several decades to investigate this process by
experimental observation and computer simulation. Nevertheless, there is still
an unexplained discrepancy between simulation data and experimental nucleation
rate densities. In this paper we examine the nucleation process in hard spheres
using molecular dynamics and Monte Carlo simulation. We show that the
crystallization process is mediated by precursors of low orientational
bond-order and that our simulation data fairly match the experimental data
sets
Measuring every particle's size from three-dimensional imaging experiments
Often experimentalists study colloidal suspensions that are nominally
monodisperse. In reality these samples have a polydispersity of 4-10%. At the
level of an individual particle, the consequences of this polydispersity are
unknown as it is difficult to measure an individual particle size from
microscopy. We propose a general method to estimate individual particle radii
within a moderately concentrated colloidal suspension observed with confocal
microscopy. We confirm the validity of our method by numerical simulations of
four major systems: random close packing, colloidal gels, nominally
monodisperse dense samples, and nominally binary dense samples. We then apply
our method to experimental data, and demonstrate the utility of this method
with results from four case studies. In the first, we demonstrate that we can
recover the full particle size distribution {\it in situ}. In the second, we
show that accounting for particle size leads to more accurate structural
information in a random close packed sample. In the third, we show that crystal
nucleation occurs in locally monodisperse regions. In the fourth, we show that
particle mobility in a dense sample is correlated to the local volume fraction.Comment: 7 pages, 5 figure
Crystal nuclei and structural correlations in two-dimensional colloidal mixtures: experiment versus simulation
We examine binary mixtures of superparamagnetic colloidal particles confined
to a two-dimensional water-air interface both by real-space experiments and
Monte-Carlo computer simulations at high coupling strength. In the simulations,
the interaction is modelled as a pairwise dipole-dipole repulsion. While the
ratio of magnetic dipole moments is fixed, the interaction strength governed by
the external magnetic field and the relative composition is varied. Excellent
agreement between simulation and experiment is found for the partial pair
distribution functions including the fine structure of the neighbour shells at
high coupling. Furthermore local crystal nuclei in the melt are identified by
bond-orientational order parameters and their contribution to the pair
structure is discussed
Partial clustering prevents global crystallization in a binary 2D colloidal glass former
A mixture of two types of super-paramagnetic colloidal particles with long
range dipolar interaction is confined by gravity to a flat interface of a
hanging water droplet. The particles are observed by video microscopy and the
dipolar interaction strength is controlled via an external magnetic field. The
system is a model system to study the glass transition in 2D, and it exhibits
partial clustering of the small particles. This clustering is strongly
dependent on the relative concentration of big and small particles.
However, changing the interaction strength reveals that the clustering
does not depend on the interaction strength. The partial clustering scenario is
quantified using Minkowski functionals and partial structure factors. Evidence
that partial clustering prevents global crystallization is discussed
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