Mechanisms of multiyear variations of Northern Australia wet-season rainfall

Northern Australia wet season (November–April) rainfall exhibits strong variability on multiyear timescales. In order to reveal the underlying mechanisms of this variability, we investigate observational records for the period 1900–2017. At multiyear timescales, the rainfall varies coherently across north-western Australia (NW) and north-eastern Australia (NE), but the variability in these two regions is largely independent. The variability in the NE appears to be primarily controlled by the remote influence of low frequency variations of El Niño-Southern Oscillation (ENSO). In contrast, multiyear variations in the NW appear to be largely driven locally and stem from a combination of rainfall-wind-evaporation feedback, whereby enhanced land-based rainfall is associated with westerly wind anomalies to the west that enhance local evaporation over the ocean to feed the enhanced land based rainfall, and soil moisture-rainfall feedback. Soil-moisture and associated evapotranspiration over northern Australia appear to act as sources of memory for sustaining multiyear wet and dry conditions in the NW. Our results imply that predictability of multiyear rainfall variations over the NW may derive from the initial soil moisture state and its memory, while predictability in the NE will be limited by the predictability of the low frequency variations of ENSO

Electronic chemical potentials of porous metal-organic frameworks

The binding energy of an electron in a material is a fundamental characteristic, which determines a wealth of important chemical and physical properties. For metal-organic frameworks this quantity is hitherto unknown. We present a general approach for determining the vacuum level of porous metal-organic frameworks and apply it to obtain the first ionisation energy for six prototype materials including zeolitic, covalent and ionic frameworks. This approach for valence band alignment can explain observations relating to the electrochemical, optical and electrical properties of porous frameworks

Chemical strategies to mitigate electrostatic charging during coffee grinding

The process of grinding coffee generates particles with high levels of electrostatic charge, causing a number of detrimental effects including clumping, particle dispersal, and spark discharge. At the brewing level, electrostatic aggregation between particles affects liquid-solid accessibility, leading to variable extraction quality. In this study, we quantify the effectiveness of four charge mitigation strategies. Our data suggests that adding small amounts of water to whole beans pre-grinding, or bombarding the grounds with ions produced from a high-voltage ionizer, are capable of de-electrifying the granular flows. While these techniques helped reduce visible mess, only the static reduction through water inclusion was found to impact the brewing parameters in espresso format coffee. There, wetting coffee with less than 0.05 mL / g resulted in a marked shift in particle size distribution, in part due to preventing clump formation and also liberating fine particles from sticking to the grinder. With all other variables kept constant, this shift resulted in at least 15% higher coffee concentration for espresso extracts prepared from darker roasts. These findings pose financial and sustainability implications, and encourage the widespread implementation of water use to de-electrify coffee during grinding.Comment: 13 pages, 5 figure

Sensitivity of the Southern Hemisphere Wintertime Teleconnection to the Location of ENSO Heating

The Southern Hemisphere extratropical atmospheric circulation response to anomalous convection in the tropical western and eastern Pacific Ocean is distinctly different. The response to westward-located heating has a meridional dipole in the South Pacific with large zonal scale and appears unable to be interpreted simply as a stationary Rossby wave train that disperses poleward and eastward from a tropical source like the meridionally arched response to eastward-located heating. This study investigates the cause of this asymmetry by examining the daily evolution of the response to suddenly switching on steady diabatic heating over a western and central/eastern equatorial Pacific location using large-ensemble integrations from the Community Atmosphere Model version 5. We focus on the austral winter months when the subtropical jet supports the development of an effective Rossby wave source in the subtropical westerlies and acts as a waveguide. We show that the subtropical jet strongly influences the height response to the western tropical Pacific heating, promoting prominent zonal circumglobal propagation. Development of a transient eddy feedback in the extratropical storm track after approximately 10 days appears to play a primary role in establishing the time-mean response, which we test through comparison with similar experiments conducted using a simplified linear model. Conversely, the height anomalies for eastern tropical Pacific heating, farther away from the subtropical jet core, have larger meridional propagation, dispersing in a typical Hoskins–Karoly manner into the Southern Hemisphere extratropics, while the transient eddy feedback plays a secondary role for the establishment of the steady response

Spatio-Temporal Distribution of Larval Gobiosoma Bosc in Waters Adjacent to Natural and Altered Marsh-Edge Habitats of Mississippi Coastal Waters

Larval naked gobies, Gobiosoma bose, were collected monthly from October 1995 to September 1997 by beam plankton trawl from waters adjacent to natural Juncus/Spartina marsh-edge, natural sandy beach and altered Juncus/Spartina marsh-edge habitats in Mississippi coastal waters. Altered marsh habitats consisted of two bulkheaded stations and one stretch of riprap. Abundances were significantly higher in waters adjacent to natural marsh-edge habitats than in those adjacent to altered habitats in year one (P = 0.011), suggesting that the physical nature of alteration may have caused reduced habitat suitability. Abundances also varied seasonally, with summer conditions of high water temperature, increasing tide height, intermediate depth, low dissolved oxygen, and clear skies being significantly related to high abundance of postflexion G, bose in each year (r(2) = 0.481 and 0.276, respectively). Year two abundances were lower than those of year one and not significantly different among habitats. There was also a noticeable shift in the reproductive strategy of G. bose from a bimodal pattern in year one to a single reproductive peak in year two. This study illustrates the importance of natural Juncus/Spartina marsh-edge habitat to G. bose reproduction/recruitment and by extension to the community structure of the Back Bay/Davis Bayou estuarine ecosystem

Strategies to Mitigate Electrostatic Charging During Coffee Grinding

Summary: Coffee grinding generates electrostatically charged particles, causing clumping, spark discharge, and beyond. When brewing, the particle aggregates affect liquid-solid surface accessibility, leading to variable extraction quality. Here, we study four charge mitigation strategies. De-electrification is readily achieved by adding small amounts of water to whole beans or by bombarding the grounds with ions produced from a high-voltage ionizer. While these techniques helped reduce visible mess, only water inclusion was found to impact coffee extracts prepared as espresso. Wetting whole beans with less than 0.05 mL/g resulted in a marked shift in particle size distribution, by preventing clump formation and preventing fine particles from sticking to the grinder. This particle size shift results in at least a 15% higher coffee concentration for espresso extracts prepared from darker roasts. These findings encourage the widespread implementation of water use to de-electrify coffee during grinding with the benefit of increased coffee extraction efficiency

Absorbate-Induced Piezochromism in a Porous Molecular Crystal

Atmospherically stable porous frameworks and materials are interesting for heterogeneous solid–gas applications. One motivation is the direct and selective uptake of pollutant/hazardous gases, where the material produces a measurable response in the presence of the analyte. In this report, we present a combined experimental and theoretical rationalization for the piezochromic response of a robust and porous molecular crystal built from an extensively fluorinated trispyrazole. The electronic response of the material is directly determined by analyte uptake, which provokes a subtle lattice contraction and an observable bathochromic shift in the optical absorption onset. Selectivity for fluorinated absorbates is demonstrated, and toluene is also found to crystallize within the pore. Furthermore, we demonstrate the application of electronic structure calculations to predict a physicochemical response, providing the foundations for the design of electronically tunable porous solids with the chemical properties required for development of novel gas-uptake media