121 research outputs found
Electronic structure of AuMg and AgMg ( = Eu, Gd, Yb)
We have investigated the electronic structure of the equiatomic EuAuMg,
GdAuMg, YbAuMg and GdAgMg intermetallics using x-ray photoelectron
spectroscopy. The spectra revealed that the Yb and Eu are divalent while the Gd
is trivalent. The spectral weight in the vicinity of the Fermi level is
dominated by the mix of Mg , Au/Ag and bands, and not by the
. We also found that the Au and Ag bands are extraordinarily
narrow, as if the noble metal atoms were impurities submerged in a low density
metal host. The experimental results were compared with band structure
calculations, and we found good agreement provided that the spin-orbit
interaction in the Au an Ag bands is included and correlation effects in an
open shell are accounted for using the local density approximation +
Hubbard scheme. Nevertheless, limitations of such a mean-field scheme to
explain excitation spectra are also evident.Comment: 4 pages, 3 figures, Brief Repor
An Automated Visual Inspection System for the Classification of the Phases of Ti-6Al-4V Titanium Alloy
Metallography is the science of studying the physical properties of metal microstructures, by means of microscopes. While traditional approaches involve the direct observation of the acquired images by human experts, Com-puter Vision techniques may help experts in the analysis of the inspected mate-rials. In this paper we present an automated system to classify the phases of a Titanium alloy, Ti-6Al-4V. Our system has been tested to analyze the final products of a Friction Stir Welding process, to study the states of the micro-structures of the welded material
Electronic structure of SrPt_4Ge_{12}: a combined photoelectron spectroscopy and band structure study
We present a combined study of the electronic structure of the
superconducting skutterudite derivative SrPt4Ge12 by means of X-ray
photoelectron spectroscopy and full potential band structure calculations
including an analysis of the chemical bonding. We establish that the states at
the Fermi level originate predominantly from the Ge 4p electrons and that the
Pt 5d shell is effectively full. We find excellent agreement between the
measured and the calculated valence band spectra, thereby validating that band
structure calculations in combination with photoelectron spectroscopy can
provide a solid basis for the modeling of superconductivity in the compounds
MPt4Ge12 (M = Sr, Ba, La, Pr) series
Phosphorylation Alters the Interaction of the Arabidopsis Phosphotransfer Protein AHP1 with Its Sensor Kinase ETR1
The ethylene receptor ethylene response 1 (ETR1) and the Arabidopsis histidine-containing phosphotransfer protein 1 (AHP1) form a tight complex in vitro. According to our current model ETR1 and AHP1 together with a response regulator form a phosphorelay system controlling the gene expression response to the plant hormone ethylene, similar to the two-component signaling in bacteria. The model implies that ETR1 functions as a sensor kinase and is autophosphorylated in the absence of ethylene. The phosphoryl group is then transferred onto a histidine at the canonical phosphorylation site in AHP1. For phosphoryl group transfer both binding partners need to form a tight complex. After ethylene binding the receptor is switched to the non-phosphorylated state. This switch is accompanied by a conformational change that decreases the affinity to the phosphorylated AHP1. To test this model we used fluorescence polarization and examined how the phosphorylation status of the proteins affects formation of the suggested ETR1−AHP1 signaling complex. We have employed various mutants of ETR1 and AHP1 mimicking permanent phosphorylation or preventing phosphorylation, respectively. Our results show that phosphorylation plays an important role in complex formation as affinity is dramatically reduced when the signaling partners are either both in their non-phosphorylated form or both in their phosphorylated form. On the other hand, affinity is greatly enhanced when either protein is in the phosphorylated state and the corresponding partner in its non-phosphorylated form. Our results indicate that interaction of ETR1 and AHP1 requires that ETR1 is a dimer, as in its functional state as receptor in planta
Initiation of sub-surface micro-cracks and white etching areas from debonding at non-metallic inclusions in wind turbine gearbox bearing
In this study, a failed planetary bearing from a wind turbine gearbox was destructively examined to investigate the initiation of micro-cracks and butterflies at non-metallic inclusions, and the effect of debonding between these inclusions and the steel matrix. The butterflies were scanned using Atomic Force Microscopy (AFM) to show the topography that could not be assessed by using other microscopy techniques. Nano-indentation was conducted across a butterfly wing and a non-metallic inclusion to measure the hardness at the interface with the steel matrix. It was found that the White Etching Areas (WEA) in the region of the butterfly wing was a damaged material that showed tearing at the debonding gap between the inclusion and steel matrix. This study highlighted the effect of debonding on the initiation of micro-cracks, WEA and inclusion cracking. A direct relationship was found between the size of inclusions and the total length of inclusions and micro-cracks or butterfly wings. The depth of the observed sub-surface damage was correlated with the sub-surface stress distribution and these results suggested that surface traction could be an important contributing factor to the subsurface damage initiation
Invasion success of a widespread invasive predator may be explained by a high predatory efficacy but may be influenced by pathogen infection
Invasive alien species (IAS) can drive community change through ecological interactions. Parasites and pathogens can play an important role in community function including mitigating or enhancing IAS impacts. Despite this, the degree to which pathogen pressure influences IAS impacts remains poorly understood. We quantified the predatory behaviour of the highly invasive alien harlequin ladybird (Harmonia axyridis) and two UK native species, the 7-spot (Coccinella septempunctata) and 2-spot (Adalia bipunctata) ladybirds, using comparative functional response experiments. We investigated the impacts of pathogen infection on the predatory ability of the ladybirds by exposing individuals to Beauveria bassiana, a widespread entomopathogen. Invasive H. axyridis was a more efficient predator than both the native A. bipunctata and C. septempunctata, often having higher attack and/or lower prey handling time coefficients, whereas native A. bipunctata were the least efficient predators. These differences were found in both adult and larval life-stages. Beauveria bassiana infection significantly altered the predatory efficiency of adult and larval ladybird predators. The effects of pathogenic infection differed between species and life-stage but in many cases infection resulted in a reduced predatory ability. We suggest that the interactions between IAS and pathogens are integral to determining invasion success and impact
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