Studies on chemical evolution using carbon suboxide

It was learned that when carbon suboxide polymers react with hydroxylamine in modified sea water the amino acids glycine and lysine are produced and that they react with urea to produce nucleic acid-like substances. These results lead to the supposition that it is possible that carbon suboxide polymers may have accumulated in the primeval sea some three or more billion years ago and were transformed into the procursors of living molecules

Can correlations drive a band insulator metallic?

We analyze the effects of the on-site Coulomb repulsion U on a band insulator using dynamical mean field theory (DMFT). We find the surprising result that the gap is suppressed to zero at a critical Uc1 and remains zero within a metallic phase. At a larger Uc2 there is a second transition from the metal to a Mott insulator, in which the gap increases with increasing U. These results are qualitatively different from Hartree-Fock theory which gives a monotonically decreasing but non-zero insulating gap for all finite U.Comment: 4 pages, 5 figure

A Large Mass of H_2 in the Brightest Cluster Galaxy in Zwicky 3146

We present the Spitzer/IRS mid-infrared spectrum of the infrared-luminous (L_(IR) = 4 × 10^(11) L_☉) brightest cluster galaxy (BCG) in the X-ray-luminous cluster Zwicky 3146 (Z3146; z = 0.29). The spectrum shows strong aromatic emission features, indicating that the dominant source of the infrared luminosity is star formation. The most striking feature of the spectrum, however, is the exceptionally strong molecular hydrogen (H_2) emission lines, which seem to be shock-excited. The line luminosities and inferred warm H_2 gas mass (~10^(10) M_☉) are 6 times larger than those of NGC 6240, the most H_2-luminous galaxy at z ≲ 0.05. Together with the large amount of cold H_2 detected previously (~10^(11) M_☉), this indicates that the Z3146 BCG contains disproportionately large amounts of both warm and cold H_2 gas for its infrared luminosity, which may be related to the intracluster gas cooling process in the cluster core

Direct observation of the formation of polar nanoregions in Pb(Mg1/3_{1/3}Nb2/3_{2/3})O3_3 using neutron pair distribution function analysis

Using neutron pair distribution function (PDF) analysis over the temperature range from 1000 K to 15 K, we demonstrate the existence of local polarization and the formation of medium-range, polar nanoregions (PNRs) with local rhombohedral order in a prototypical relaxor ferroelectric Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$. We estimate the volume fraction of the PNRs as a function of temperature and show that this fraction steadily increases from 0 % to a maximum of $\sim$ 30% as the temperature decreases from 650 K to 15 K. Below T$\sim$200 K the PNRs start to overlap as their volume fraction reaches the percolation threshold. We propose that percolating PNRs and their concomitant overlap play a significant role in the relaxor behavior of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$.Comment: 4 pages, 3 figure

A Herschel Study of 24 micron-Selected AGNs and Their Host Galaxies

We present a sample of 290 24-micron-selected active galactic nuclei (AGNs) mostly at z ~ 0.3 -- 2.5, within 5.2 square degrees distributed as 25' X 25' fields around each of 30 galaxy clusters in the Local Cluster Substructure Survey (LoCuSS). The sample is nearly complete to 1 mJy at 24 microns, and has a rich multi-wavelength set of ancillary data; 162 are detected by Herschel. We use spectral templates for AGNs, stellar populations, and infrared emission by star forming galaxies to decompose the spectral energy distributions (SEDs) of these AGNs and their host galaxies, and estimate their star formation rates (SFRs), AGN luminosities, and host galaxy stellar masses. The set of templates is relatively simple: a standard Type-1 quasar template; another for the photospheric output of the stellar population; and a far infrared star-forming template. For the Type-2 AGN SEDs, we substitute templates including internal obscuration, and some Type-1 objects require a warm component (T > 50 K). The individually Herschel- detected Type-1 AGNs and a subset of 17 Type-2 ones typically have luminosities > 10^{45} ergs/s, and supermassive black holes of ~ 3 X 10^8 Msun emitting at ~ 10% of the Eddington rate. We find them in about twice the numbers of AGN identified in SDSS data in the same fields, i.e., they represent typical high luminosity AGN, not an infrared-selected minority. These AGNs and their host galaxies are studied further in an accompanying paper

PhoSim-NIRCam: Photon-by-photon image simulations of the James Webb Space Telescope's Near-Infrared Camera

Recent instrumentation projects have allocated resources to develop codes for simulating astronomical images. Novel physics-based models are essential for understanding telescope, instrument, and environmental systematics in observations. A deep understanding of these systematics is especially important in the context of weak gravitational lensing, galaxy morphology, and other sensitive measurements. In this work, we present an adaptation of a physics-based ab initio image simulator: The Photon Simulator (PhoSim). We modify PhoSim for use with the Near-Infrared Camera (NIRCam) -- the primary imaging instrument aboard the James Webb Space Telescope (JWST). This photon Monte Carlo code replicates the observational catalog, telescope and camera optics, detector physics, and readout modes/electronics. Importantly, PhoSim-NIRCam simulates both geometric aberration and diffraction across the field of view. Full field- and wavelength-dependent point spread functions are presented. Simulated images of an extragalactic field are presented. Extensive validation is planned during in-orbit commissioning

Macroscopic Quantum Dynamics of a Free Domain Wall in a Ferromagnet

We study macroscopic quantum dynamics of a free domain wall in a quasi-one-dimensional ferromagnet by use of the spin-coherent-state path integral in {\it discrete-time} formalism. Transition amplitudes between typical states are quantitatively discussed by use of {\it stationary-action approximation} with respect to collective degrees of freedom representing the center position and the chirality of the domain wall. It is shown that the chirality may be loosely said to be canonically conjugate to the center position; the latter moves with a speed depending on the former. It is clarified under what condition the center position can be regarded as an effective free-particle position, which exhibits the phenomenon of wave-packet spreading. We demonstrate, however, that in some case the non-linear character of the spin leads to such a dramatic phenomenon of a non-spreading wave packet as to completely invalidate the free-particle analogy. In the course of the discussion, we also point out various difficulties associated with the continuous-time formalism.Comment: 23 pages, REVTEX, 4 figures, submitted to Phys. Rev.

Local atomic structure and discommensurations in the charge density wave of CeTe3

The local structure of CeTe3 in the incommensurate charge density wave (IC-CDW) state has been obtained using atomic pair distribution function (PDF) analysis of x-ray diffraction data. Local atomic distortions in the Te-nets due to the CDW are larger than observed crystallographically, resulting in distinct short and long Te-Te bonds. Observation of different distortion amplitudes in the local and average structures are explained by the discommensurated nature of the CDW since the PDF is sensitive to the local displacements within the commensurate regions whereas the crystallographic result averages over many discommensurated domains. The result is supported by STM data. This is the first quantitative local structural study within the commensurate domains in an IC-CDW system.Comment: 4 pages, 4 figure

Macroscopic Quantum Tunneling of Ferromagnetic Domain Walls

Quantum tunneling of domain walls out of an impurity potential in a mesoscopic ferromagnetic sample is investigated. Using improved expressions for the domain wall mass and for the pinning potential, we find that the cross-over temperature between thermal activation and quantum tunneling is of a different functional form than found previously. In materials like Ni or YIG, the crossover temperatures are around 5 mK. We also find that the WKB exponent is typically two orders of magnitude larger than current estimates. The sources for these discrepancies are discussed, and precise estimates for the transition from three-dimensional to one-dimensional magnetic behavior of a wire are given. The cross-over temperatures from thermal to quantum transitions and tunneling rates are calculated for various materials and sample sizes.Comment: 10 pages, 2 postscript figures, REVTe